ABSTRACT

This is first achieved by directing the ions into the interface region. The interface consists of two metallic cones with very small orifices, which are maintained at a vacuum of ~1-2 Torr with a mechanical roughing pump. After the ions are generated in the plasma, they pass into the first cone, known as the sampler cone, which has an orifice of 0.8-1.2 mm i.d. From there, they travel a short distance to the skimmer cone, which is generally smaller and more pointed than the sampler cone. The skimmer also has a much smaller orifice (typically 0.4-0.8 mm i.d.) than the sampler cone. Both cones are usually made of nickel but can be made of other materials such as platinum, which are far more tolerant to corrosive liquids. To reduce the effects of the high temperature plasma on the cones, the interface housing is water-cooled and made from a material that dissipates heat easily, such as copper or aluminum. The ions then emerge from the skimmer cone, where

FIGURE 5.1 Schematic of ICP-MS, showing proximity of the interface region.