ABSTRACT

Wavelengths of Emission Lines Used for the Detection and Determination of Some Common Elements: Preferred Flames Used and the Detection Limits

Element

Wavelength (nm)

Type of flame

Detection limits (ppm)

Aluminum

396.2

OA

0.1

484.0

OA

0.5

Antimony

252.8

OA

1.0

Arsenic

235.0

OA

2.2

Barium

455.5

OH

3

553.6

OH

1

Bismuth

223.1

OA

6.4

Boron

249.8

OA

7

518.0

OA

3

Cadmium

326.1

AH

0.5

Calcium

422.7

OA

0.07

554.0

OA

0.16

662.0

OA

0.6

Cesium

455.5

OH

2.0

852.0

OH

0.5

Chromium

425.4

OA

5.0

Cobalt

242.5

OA

1.7

353.0

OA

4.0

Copper

324.7

OA

0.6

Gallium

417.2

OA

0.5

Gold

267.6

OA

2.0

Indium

451.1

OH

0.01

Iron

372.0

OA

2.5

386.0

OA

2.7

550.0

OA

0.5

Lanthanum

442.0

OA

0.1

741.0

OA

4.5

Lead

405.8

OA

1.0

Lithium

670.8

OA

0.007

Magnesium

285.2

OA

0.8

383.0

OA

1.6

Manganese

403.3

OA

0.01

Mercury

253.6

OA

2.5

Molybdenum

379.8

OA

0.5

Neodymium

555.0

OH

0.2

702.0

OH

1.0

Nickel

352.4

OA

0.1

Niobium

405.9

OA

12

Palladium

363.5

OH

0.1

Phosphorus

253.0

OH

1.0

Platinum

265.9

OA

10

Potassium

404.4

OH

1.0

767.0

OH

0.01

Rhenium

346.1

OA

0.3

Rhodium

369.2

OH

0.1

Rubidium

780.0

OH

0.3

Ruthenium

372.8

OA

0.3

Scandium

604.0

OH

0.012

473Silicon

251.6

OH

4.0

Silver

328.0

OH

0.1

338.3

OH

0.6

Sodium

590.0

OH

0.001

Strontium

460.7

OA

0.01

Tellurium

238.6

OA

2.0

Thallium

377.6

OH

0.6

Tin

243.0

OA

0.5

Titanium

399.9

OA

1.0

Vanadium

437.9

OA

1.0

Yttrium

597.0

OA

0.3

Zinc

213.9

OA

77

Note: AH, air-hydrogen flame; OA, oxygen-acetylene flame; OH, oxygen-hydrogen flame.