Performance of a biotrickling filter for anaerobic utilization of gas-phase methanol coupled to thiosulphate reduction and resource recovery through volatile fatty acids production

62The anaerobic removal of continuously fed gas-phase methanol (2.5–30 g/m³.h) and the reduction of step-fed thiosulphate (1000 mg/L) was investigated in a biotrickling filter (BTF) operated for 123 d at an empty bed residence time (EBRT) of 4.6 and 2.3 min. The BTF performance during steady step feed and special operational phases like intermittent liquid trickling in 6 and 24 h cycles and operation without pH regulation were evaluated. Performance of the BTF was not affected and nearly 100% removal of gas-phase methanol was achieved with an EC_max of 21 g/m³.h. Besides, > 99% thiosulphate reduction was achieved, in all the phases of operation. The production of sulphate, H₂S and volatile fatty acids (VFA) was monitored and a maximum of 2500 mg/L of acetate, 200 mg/L of propionate, 150 mg/L of isovalerate, 100 mg/L isobutyrate was produced.