PVT DATA OF COPOLYMERS AND SOLUTIONS

P/MPa T/K 393.7 413.7 433.5 453.6 473.1 493.1 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8968 0.9092 0.9219 0.9349 0.9489 0.9632 10 0.8918 0.9037 0.9158 0.9282 0.9416 0.9547 20 0.8872 0.8983 0.9100 0.9219 0.9348 0.9467 50 0.8744 0.8848 0.8950 0.9053 0.9171 0.9271 100 0.8572 0.8665 0.8751 0.8841 0.8946 0.9029 150 0.8431 0.8512 0.8592 0.8671 0.8764 0.8839 200 0.8310 0.8381 0.8457 0.8526 0.8612 0.8679 _______________________________________________________________________________ Tait equation parameter functions:

Range of data: T/K = 393-493, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 _______________________________________________________________________________

V(0,T/K)/cm3g1 B(T/K)/MPa 0.6775 exp(7.110 104 T) 903.5 exp(4.441 103 T) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-butene) 2007SAT Characterization: Mn/g.mol1 = 53000, Mw/g.mol1 = 110000, 10 mol% 1-butene, 12 wt% crystallinity, unspecified industrial source

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T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

373.8 1.236 1.226 1.217 1.194 1.165 393.9 1.254 1.243 1.233 1.208 1.176 1.152 1.131 414.0 1.271 1.260 1.248 1.222 1.188 1.162 1.140 433.9 1.289 1.276 1.264 1.235 1.199 1.172 1.149 453.7 1.307 1.293 1.280 1.249 1.210 1.181 1.158 473.6 1.326 1.310 1.296 1.262 1.221 1.191 1.166 493.5 1.345 1.328 1.312 1.275 1.232 1.200 1.175 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-butene) 2000CAP Characterization: Mn/g.mol1 = 24900, Mw/g.mol1 = 120000, 3.80 mol% 1-butene, ρ = 0.9190 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.141 exp(7.39 104  ) 199.8 exp(5.01 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-butene) 2000CAP Characterization: Mn/g.mol1 = 24200, Mw/g.mol1 = 98700, 4.03 mol% 1-butene, ρ = 0.9194 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.137 exp(7.46 104  ) 194.4 exp(4.93 103  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2007SAT Characterization: Mn/g.mol1 = 28000, Mw/g.mol1 = 63000, 3.5 mol% 1-hexene, 51 wt% crystallinity, unspecified industrial source

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T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

414.0 1.274 1.263 1.252 1.226 433.9 1.293 1.280 1.270 1.240 1.204 1.177 453.8 1.311 1.297 1.284 1.253 1.215 1.186 1.163 473.7 1.329 1.314 1.300 1.266 1.226 1.196 1.171 493.6 1.349 1.331 1.315 1.279 1.236 1.205 1.179 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2000CAP Characterization: Mn/g.mol1 = 43000, Mw/g.mol1 = 94000, 2.56 mol% 1-hexene, ρ = 0.9194 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.138 exp(7.44 104  ) 196.3 exp(4.99 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2000CAP Characterization: Mn/g.mol1 = 44000, Mw/g.mol1 = 98000, 3.08 mol% 1-hexene, ρ = 0.9192 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.138 exp(7.42 104  ) 199.5 exp(5.08 103  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2000CAP Characterization: Mn/g.mol1 = 36000, Mw/g.mol1 = 111300, 3.77 mol% 1-hexene, ρ = 0.9234 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.134 exp(7.54 104  ) 198.7 exp(5.08 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2000CAP Characterization: Mn/g.mol1 = 30000, Mw/g.mol1 = 111000, 3.94 mol% 1-hexene, ρ = 0.9208 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.136 exp(7.52 104  ) 194.5 exp(4.99 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-norbornene) 2006BLO Characterization: Mn/g.mol1 = 56000, Mw/g.mol1 = 101000, Tg/K = 415, 51.8 mol% norbornene, commercial sample

Tait equation parameter functions: Range of data: T/K = 415-550, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.927 + 5.5 104  − 3.0 108  2 238.0 exp(0.3 102  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2007SAT Characterization: Mn/g.mol1 = 106000, Mw/g.mol1 = 196000, 8.9 mol% 1-octene, 17.6 wt% crystallinity, unspecified industrial source

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T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

373.9 1.238 1.228 1.219 394.0 1.258 1.247 1.237 1.212 1.180 414.1 1.275 1.265 1.253 1.226 1.191 1.165 1.143 434.0 1.293 1.281 1.269 1.240 1.203 1.175 1.152 453.8 1.311 1.298 1.285 1.253 1.214 1.185 1.161 473.6 1.330 1.316 1.302 1.267 1.226 1.195 1.170 493.4 1.349 1.333 1.318 1.281 1.237 1.204 1.178 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2000CAP Characterization: Mn/g.mol1 = 25900, Mw/g.mol1 = 114000, 2.80 mol% 1-octene, ρ = 0.9212 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.140 exp(7.56 104  ) 203.7 exp(5.21 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2000CAP Characterization: Mn/g.mol1 = 38000, Mw/g.mol1 = 70000, 3.20 mol% 1-octene, ρ = 0.9180 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.144 exp(7.35 104  ) 195.2 exp(4.91 103  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2000CAP Characterization: Mn/g.mol1 = 17000, Mw/g.mol1 = 106000, 3.20 mol% 1-octene, ρ = 0.9200 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]} with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.145 exp(7.55 104  ) 198.3 exp(5.04 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2000CAP Characterization: Mn/g.mol1 = 22000, Mw/g.mol1 = 53000, 5.00 mol% 1-octene, ρ = 0.9070 g/cm3, Nova Chemicals, Calgary, Canada

Tait equation parameter functions: Range of data: T/K = 453-513, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]} with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 1.148 exp(7.26 104  ) 194.1 exp(4.91 103  ) _______________________________________________________________________________ Polymer (B): poly(ethylene-co-propylene) 2007SAT Characterization: Mn/g.mol1 = 87000, Mw/g.mol1 = 190000, 19 mol% propene, 10 wt% crystallinity, unspecified industrial source _______________________________________________________________________________

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

333.7 1.200 1.192 1.184 1.165 353.8 1.217 1.209 1.200 1.179 1.151 1.130 1.111 374.0 1.234 1.225 1.215 1.192 1.163 1.140 1.120 394.0 1.252 1.241 1.230 1.206 1.174 1.150 1.129 414.2 1.269 1.257 1.246 1.219 1.185 1.159 1.138 434.1 1.287 1.274 1.262 1.232 1.196 1.169 1.147 454.0 1.306 1.291 1.278 1.246 1.207 1.179 1.155 473.9 1.324 1.308 1.294 1.259 1.218 1.188 1.164 493.8 1.343 1.326 1.309 1.273 1.229 1.197 1.172 _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-propylene) 2000TOM Characterization: Mn/g.mol1 = 71000, Mw/g.mol1 = 141000, 22.0 wt% propene, random copolymer,ρ = 0.88 g/cm3, Exxelor PE805, Exxon Chemical Company

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P/MPa = 0.1 40.0 80.0 120.0 160.0

T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 _______________________________________________________________________________

432.40 1.2876 433.81 1.2441 434.80 1.2143 435.38 1.1906 435.85 1.1705 442.35 1.2972 443.54 1.2512 444.67 1.2204 445.52 1.1964 446.10 1.1760 452.65 1.3076 454.25 1.2587 455.14 1.2264 455.81 1.2012 456.06 1.1804 462.52 1.3170 463.94 1.2657 464.90 1.2324 465.68 1.2069 466.30 1.1857 472.70 1.3269 474.33 1.2733 475.20 1.2387 476.09 1.2125 476.64 1.1908 482.85 1.3368 484.50 1.2812 485.35 1.2448 486.10 1.2175 486.48 1.1952 492.17 1.3460 493.92 1.2882 494.86 1.2509 495.70 1.2229 496.38 1.2002 502.09 1.3564 503.82 1.2953 504.95 1.2569 505.77 1.2282 506.52 1.2052 512.71 1.3673 514.46 1.3033 515.61 1.2633 516.45 1.2339 517.13 1.2099 522.36 1.3776 524.17 1.3101 525.25 1.2695 526.15 1.2389 527.06 1.2146 532.48 1.3884 534.28 1.3173 535.25 1.2752 536.09 1.2438 536.93 1.2189 542.04 1.3996 544.15 1.3250 545.32 1.2816 546.26 1.2495 547.13 1.2239 552.07 1.4109 554.08 1.3321 555.28 1.2875 556.17 1.2550 556.91 1.2284 561.96 1.4227 563.88 1.3396 565.02 1.2930 565.86 1.2596 566.70 1.2325 571.55 1.4340 573.90 1.3475 575.15 1.2997 576.04 1.2654 576.93 1.2378 _______________________________________________________________________________ Polymer (B): poly[(ethylene-alt-propylene)-co-carbon monoxide] 2001PRI Characterization: Mw/g.mol1 = 192000, 50 wt% carbon monoxide, synthesized in the laboratory

Tait equation parameter functions: Range of data: T/K = 293-423, P/MPa = 30-100

V(P/MPa,  /°C)/V(0,  /°C) = 1  0.0894 ln{1 + (P/MPa)/[92.5 exp(3.38 103  )]} Polymer (B): poly[(ethylene-alt-propylene)-co-carbon monoxide] 2001PRI Characterization: Mw/g.mol1 = 397000, 40 wt% carbon monoxide, synthesized in the laboratory

Tait equation parameter functions: Range of data: T/K = 293-423, P/MPa = 30-100

V(P/MPa,  /°C)/V(0,  /°C) = 1  0.0894 ln{1 + (P/MPa)/[104.2 exp(1.93 103  )]}

________________________________________________________________________ Polymer (B): poly[(ethylene-alt-propylene)-co-carbon monoxide] 2001PRI Characterization: Mw/g.mol1 = 343000, 30 wt% carbon monoxide, synthesized in the laboratory

Tait equation parameter functions: Range of data: T/K = 293-423, P/MPa = 30-100

V(P/MPa,  /°C)/V(0,  /°C) = 1  0.0894 ln{1 + (P/MPa)/[120.8 exp(3.08 103  )]} Polymer (B): poly(ethylene-co-propylene-co-ethylidene norbornene) 2000TOM Characterization: Mn/g.mol1 = 117000, Mw/g.mol1 = 304000, 41.4 wt% propene, 50.2 wt% ethene, 8.7 wt% ethylidene norbornene, random terpolymer, ρ = 0.85 g/cm3, Royaltuf 490, Uniroyal Chemical

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P/MPa = 0.1 40.0 80.0 120.0 160.0

T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 T/K Vspec/cm3g1 _______________________________________________________________________________

431.71 1.2543 433.06 1.2140 434.22 1.1860 435.01 1.1639 435.63 1.1436 441.84 1.2631 443.20 1.2210 444.39 1.1918 445.12 1.1690 445.77 1.1499 451.89 1.2724 453.27 1.2278 454.37 1.1975 455.06 1.1740 455.66 1.1545 461.86 1.2814 463.25 1.2346 464.41 1.2035 465.25 1.1794 465.88 1.1593 472.12 1.2913 473.65 1.2420 474.74 1.2098 475.60 1.1848 476.36 1.1642 482.15 1.3018 483.90 1.2494 485.02 1.2160 485.86 1.1905 486.58 1.1693 491.92 1.3110 493.73 1.2564 494.94 1.2217 495.86 1.1955 496.56 1.1739 501.87 1.3204 503.55 1.2628 504.73 1.2268 505.49 1.1999 506.36 1.1779 511.72 1.3299 513.70 1.2703 514.76 1.2325 515.66 1.2048 516.38 1.1822 522.49 1.3412 524.16 1.2778 525.02 1.2382 525.86 1.2095 526.70 1.1865 532.19 1.3513 534.00 1.2850 535.07 1.2444 536.04 1.2150 536.89 1.1917 542.23 1.3629 544.16 1.2931 545.38 1.2511 546.10 1.2208 547.02 1.1964 552.11 1.3753 554.15 1.3017 555.23 1.2589 556.14 1.2272 557.03 1.2022 562.12 1.3896 564.26 1.3111 565.62 1.2667 566.52 1.2340 567.31 1.2084 571.26 1.4048 573.62 1.3214 575.08 1.2753 575.92 1.2414 576.86 1.2151 _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 15 mol% ethene, ρ(293.15 K) = 1.2522 g/cm3, Tg/K = 341, Tm/K = 484, Kuraray Specialities, Japan

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P/MPa T/K 483.55 493.80 503.38 514.05 523.80 534.11 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8783 0.8852 0.8908 0.8964 0.9034 0.9133 10 0.8744 0.8810 0.8863 0.8918 0.8987 0.9083 20 0.8706 0.8769 0.8818 0.8874 0.8940 0.9036 30 0.8671 0.8734 0.8783 0.8837 0.8901 0.8994 40 0.8640 0.8701 0.8749 0.8801 0.8865 0.8958 50 0.8609 0.8670 0.8718 0.8768 0.8831 0.8921 60 0.8581 0.8642 0.8686 0.8736 0.8799 0.8887 70 0.8551 0.8614 0.8659 0.8707 0.8768 0.8854 80 0.8523 0.8587 0.8629 0.8679 0.8738 0.8823 90 0.8492 0.8562 0.8604 0.8651 0.8709 0.8795 100 0.8463 0.8536 0.8577 0.8624 0.8681 0.8765 110 0.8433 0.8512 0.8552 0.8600 0.8655 0.8740 120 0.8404 0.8488 0.8528 0.8574 0.8628 0.8712 130 0.8374 0.8464 0.8505 0.8550 0.8604 0.8687 140 0.8341 0.8443 0.8482 0.8526 0.8581 0.8661 150 0.8313 0.8421 0.8461 0.8505 0.8556 0.8638 160 0.8284 0.8400 0.8439 0.8483 0.8534 0.8615 170 0.8258 0.8379 0.8418 0.8461 0.8513 0.8593 180 0.8234 0.8358 0.8398 0.8440 0.8491 0.8572 190 0.8208 0.8337 0.8379 0.8419 0.8470 0.8550 200 0.8185 0.8316 0.8360 0.8400 0.8451 0.8531 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 27 mol% ethene, ρ(293.15 K) = 1.1959 g/cm3, Tg/K = 339, Tm/K = 466, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 466.52 477.39 487.28 497.68 508.00 518.11 528.90 539.09 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9234 0.9290 0.9340 0.9392 0.9453 0.9576 0.9702 0.9821 10 0.9189 0.9243 0.9292 0.9341 0.9402 0.9522 0.9641 0.9754 20 0.9146 0.9196 0.9244 0.9292 0.9352 0.9469 0.9584 0.9691 30 0.9109 0.9158 0.9204 0.9250 0.9309 0.9425 0.9534 0.9638 40 0.9075 0.9121 0.9167 0.9212 0.9271 0.9385 0.9488 0.9589 50 0.9042 0.9088 0.9132 0.9175 0.9235 0.9346 0.9445 0.9543 continued

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continued

60 0.9010 0.9055 0.9098 0.9141 0.9200 0.9309 0.9405 0.9500 70 0.8981 0.9024 0.9066 0.9107 0.9167 0.9273 0.9366 0.9458 80 0.8951 0.8994 0.9035 0.9075 0.9136 0.9239 0.9330 0.9419 90 0.8924 0.8965 0.9006 0.9045 0.9105 0.9208 0.9295 0.9382 100 0.8897 0.8938 0.8977 0.9016 0.9076 0.9175 0.9260 0.9346 110 0.8872 0.8910 0.8949 0.8987 0.9048 0.9146 0.9228 0.9311 120 0.8846 0.8885 0.8923 0.8960 0.9020 0.9117 0.9197 0.9278 130 0.8821 0.8860 0.8897 0.8934 0.8994 0.9088 0.9166 0.9246 140 0.8798 0.8835 0.8871 0.8909 0.8968 0.9060 0.9137 0.9215 150 0.8772 0.8812 0.8847 0.8883 0.8944 0.9033 0.9109 0.9186 160 0.8746 0.8789 0.8824 0.8858 0.8919 0.9008 0.9081 0.9156 170 0.8717 0.8766 0.8801 0.8835 0.8895 0.8982 0.9055 0.9129 180 0.8685 0.8745 0.8779 0.8813 0.8873 0.8958 0.9028 0.9101 190 0.8650 0.8724 0.8757 0.8790 0.8850 0.8933 0.9003 0.9075 200 0.8616 0.8703 0.8736 0.8769 0.8828 0.8910 0.8978 0.9049 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 32 mol% ethene, ρ(293.15 K) = 1.1810 g/cm3, Tg/K = 335, Tm/K = 457, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 467.46 477.59 488.37 498.75 508.97 519.72 529.57 539.30 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9363 0.9420 0.9479 0.9536 0.9599 0.9673 0.9753 0.9841 10 0.9318 0.9372 0.9428 0.9483 0.9543 0.9613 0.9691 0.9775 20 0.9273 0.9325 0.9378 0.9432 0.9488 0.9555 0.9632 0.9712 30 0.9235 0.9286 0.9335 0.9388 0.9444 0.9507 0.9582 0.9660 40 0.9200 0.9249 0.9297 0.9348 0.9401 0.9464 0.9536 0.9612 50 0.9164 0.9213 0.9260 0.9308 0.9361 0.9423 0.9493 0.9566 60 0.9132 0.9179 0.9225 0.9272 0.9323 0.9383 0.9451 0.9524 70 0.9100 0.9147 0.9190 0.9238 0.9287 0.9347 0.9413 0.9483 80 0.9070 0.9115 0.9159 0.9204 0.9253 0.9311 0.9375 0.9445 90 0.9042 0.9086 0.9128 0.9173 0.9220 0.9277 0.9340 0.9407 100 0.9014 0.9057 0.9098 0.9142 0.9190 0.9245 0.9306 0.9371 110 0.8988 0.9028 0.9069 0.9112 0.9158 0.9213 0.9274 0.9337 120 0.8962 0.9002 0.9042 0.9084 0.9129 0.9183 0.9242 0.9304 130 0.8936 0.8976 0.9015 0.9057 0.9100 0.9153 0.9212 0.9273 140 0.8911 0.8951 0.8989 0.9031 0.9073 0.9125 0.9182 0.9243 150 0.8888 0.8926 0.8964 0.9005 0.9047 0.9097 0.9154 0.9213 160 0.8866 0.8903 0.8940 0.8980 0.9021 0.9071 0.9126 0.9184 170 0.8842 0.8880 0.8916 0.8955 0.8996 0.9045 0.9099 0.9157 180 0.8820 0.8856 0.8893 0.8931 0.8972 0.9020 0.9073 0.9130 190 0.8799 0.8835 0.8871 0.8907 0.8947 0.8996 0.9047 0.9103 200 0.8778 0.8813 0.8849 0.8885 0.8925 0.8972 0.9023 0.9079 _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 38 mol% ethene, ρ(293.15 K) = 1.1690 g/cm3, Tg/K = 332, Tm/K = 450, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 467.82 477.75 488.37 499.04 509.02 519.75 529.66 539.20 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9530 0.9585 0.9643 0.9705 0.9769 0.9858 0.9963 1.0071 10 0.9482 0.9535 0.9590 0.9649 0.9711 0.9798 0.9899 1.0002 20 0.9434 0.9486 0.9539 0.9595 0.9656 0.9740 0.9837 0.9936 30 0.9394 0.9444 0.9495 0.9549 0.9608 0.9690 0.9784 0.9880 40 0.9355 0.9403 0.9452 0.9505 0.9563 0.9642 0.9733 0.9828 50 0.9318 0.9365 0.9413 0.9464 0.9521 0.9598 0.9686 0.9777 60 0.9283 0.9329 0.9376 0.9425 0.9481 0.9556 0.9642 0.9730 70 0.9250 0.9294 0.9339 0.9388 0.9443 0.9515 0.9600 0.9686 80 0.9218 0.9261 0.9305 0.9353 0.9406 0.9477 0.9560 0.9644 90 0.9187 0.9229 0.9272 0.9318 0.9372 0.9441 0.9521 0.9603 100 0.9156 0.9199 0.9241 0.9286 0.9337 0.9407 0.9485 0.9565 110 0.9128 0.9170 0.9211 0.9253 0.9306 0.9373 0.9449 0.9528 120 0.9100 0.9139 0.9181 0.9224 0.9275 0.9341 0.9416 0.9492 130 0.9073 0.9112 0.9152 0.9194 0.9244 0.9310 0.9383 0.9458 140 0.9047 0.9086 0.9125 0.9167 0.9216 0.9280 0.9353 0.9425 150 0.9021 0.9060 0.9099 0.9138 0.9188 0.9251 0.9322 0.9394 160 0.8998 0.9034 0.9073 0.9112 0.9160 0.9223 0.9292 0.9363 170 0.8974 0.9010 0.9047 0.9086 0.9133 0.9196 0.9263 0.9333 180 0.8951 0.8986 0.9023 0.9062 0.9108 0.9170 0.9236 0.9303 190 0.8927 0.8963 0.8999 0.9037 0.9083 0.9144 0.9209 0.9276 200 0.8906 0.8941 0.8977 0.9013 0.9058 0.9118 0.9183 0.9248 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 44 mol% ethene, ρ(293.15 K) = 1.1359 g/cm3, Tg/K = 327, Tm/K = 439, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 450.10 460.43 471.16 481.64 492.41 502.47 512.67 523.20 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9751 0.9813 0.9879 0.9945 1.0012 1.0075 1.0141 1.0214 10 0.9702 0.9762 0.9825 0.9888 0.9952 1.0013 1.0077 1.0145 20 0.9655 0.9713 0.9774 0.9834 0.9895 0.9954 1.0015 1.0081 30 0.9613 0.9669 0.9727 0.9787 0.9845 0.9901 0.9961 1.0024 40 0.9574 0.9627 0.9684 0.9742 0.9798 0.9853 0.9910 0.9971 50 0.9535 0.9587 0.9643 0.9700 0.9752 0.9807 0.9863 0.9921 continued

________________________________________________________________________

continued

60 0.9499 0.9550 0.9603 0.9659 0.9711 0.9764 0.9817 0.9875 70 0.9465 0.9515 0.9566 0.9620 0.9671 0.9722 0.9774 0.9830 80 0.9431 0.9479 0.9530 0.9582 0.9632 0.9682 0.9733 0.9788 90 0.9400 0.9446 0.9497 0.9546 0.9596 0.9644 0.9694 0.9748 100 0.9369 0.9415 0.9464 0.9513 0.9560 0.9608 0.9656 0.9709 110 0.9339 0.9385 0.9432 0.9480 0.9526 0.9573 0.9621 0.9671 120 0.9310 0.9354 0.9401 0.9449 0.9493 0.9539 0.9585 0.9636 130 0.9282 0.9327 0.9373 0.9418 0.9462 0.9508 0.9553 0.9601 140 0.9256 0.9300 0.9344 0.9389 0.9433 0.9477 0.9521 0.9569 150 0.9231 0.9272 0.9316 0.9361 0.9403 0.9447 0.9489 0.9537 160 0.9204 0.9247 0.9290 0.9334 0.9375 0.9418 0.9459 0.9507 170 0.9180 0.9221 0.9264 0.9307 0.9347 0.9389 0.9432 0.9476 180 0.9155 0.9197 0.9238 0.9281 0.9321 0.9362 0.9403 0.9449 190 0.9128 0.9173 0.9215 0.9257 0.9295 0.9335 0.9376 0.9420 200 0.9096 0.9150 0.9191 0.9231 0.9269 0.9309 0.9349 0.9392 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 533.89 543.95 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0293 1.0378 10 1.0220 1.0301 20 1.0153 1.0230 30 1.0093 1.0166 40 1.0037 1.0108 50 0.9985 1.0054 60 0.9937 1.0003 70 0.9891 0.9954 80 0.9846 0.9909 90 0.9804 0.9866 100 0.9764 0.9825 110 0.9726 0.9785 120 0.9689 0.9747 130 0.9654 0.9710 140 0.9620 0.9675 150 0.9588 0.9641 160 0.9556 0.9608 170 0.9525 0.9578 180 0.9495 0.9547 190 0.9467 0.9517 200 0.9438 0.9488 _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 48 mol% ethene, ρ(293.15 K) = 1.1243 g/cm3, Tg/K = 321, Tm/K = 436, Kuraray Specialities, Japan

_______________________________________________________________________________

P/MPa T/K 447.09 456.99 467.74 478.12 488.02 493.16 503.16 519.30 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9886 0.9947 1.0010 1.0072 1.0135 1.0199 1.0264 1.0336 10 0.9833 0.9891 0.9951 1.0011 1.0071 1.0132 1.0193 1.0260 20 0.9781 0.9838 0.9895 0.9954 1.0010 1.0067 1.0127 1.0188 30 0.9736 0.9791 0.9845 0.9902 0.9957 1.0013 1.0069 1.0128 40 0.9694 0.9748 0.9800 0.9854 0.9906 0.9961 1.0014 1.0070 50 0.9654 0.9704 0.9757 0.9809 0.9860 0.9912 0.9964 1.0018 60 0.9616 0.9665 0.9715 0.9767 0.9816 0.9866 0.9916 0.9969 70 0.9579 0.9628 0.9676 0.9726 0.9773 0.9824 0.9873 0.9922 80 0.9545 0.9592 0.9638 0.9687 0.9733 0.9781 0.9829 0.9877 90 0.9511 0.9556 0.9602 0.9649 0.9695 0.9742 0.9788 0.9836 100 0.9479 0.9522 0.9568 0.9615 0.9658 0.9705 0.9749 0.9796 110 0.9447 0.9491 0.9535 0.9580 0.9623 0.9667 0.9711 0.9757 120 0.9417 0.9460 0.9504 0.9547 0.9588 0.9632 0.9676 0.9721 130 0.9388 0.9429 0.9473 0.9516 0.9556 0.9599 0.9641 0.9685 140 0.9361 0.9402 0.9443 0.9485 0.9524 0.9567 0.9608 0.9651 150 0.9333 0.9373 0.9414 0.9456 0.9494 0.9535 0.9575 0.9618 160 0.9307 0.9346 0.9386 0.9427 0.9466 0.9505 0.9545 0.9586 170 0.9281 0.9321 0.9359 0.9399 0.9437 0.9476 0.9516 0.9556 180 0.9257 0.9295 0.9334 0.9373 0.9408 0.9448 0.9486 0.9525 190 0.9232 0.9270 0.9308 0.9346 0.9382 0.9421 0.9458 0.9498 200 0.9209 0.9246 0.9282 0.9322 0.9355 0.9394 0.9431 0.9468 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 528.86 539.38 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0406 1.0491 10 1.0328 1.0408 20 1.0254 1.0330 30 1.0191 1.0264 40 1.0134 1.0202 50 1.0078 1.0146 60 1.0029 1.0093 70 0.9979 1.0042 continued

________________________________________________________________________

continued

80 0.9935 0.9996 90 0.9891 0.9951 100 0.9849 0.9909 110 0.9810 0.9867 120 0.9772 0.9827 130 0.9735 0.9790 140 0.9700 0.9754 150 0.9666 0.9719 160 0.9633 0.9685 170 0.9601 0.9653 180 0.9571 0.9621 190 0.9541 0.9590 200 0.9512 0.9562 _______________________________________________________________________________ Polymer (B): poly[propylene-b-(ethylene-co-propylene)] 2000SA2 Characterization: Mw/g.mol1 = 240000, 90% isotactic, 58.1 wt% crystallinity, 4.9 wt% ethene, Mitsubishi Chemical, Kurashiki, Japan

_______________________________________________________________________________

P/MPa T/K 453.8 473.7 493.6 513.5 533.6 553.6 573.4 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.3139 1.3326 1.3515 1.3708 1.3943 1.4145 1.4361 10.0 1.2976 1.3145 1.3315 1.3487 1.3691 1.3866 1.4053 20.0 1.2830 1.2983 1.3138 1.3296 1.3480 1.3640 1.3805 50.0 1.2488 1.2617 1.2743 1.2871 1.3009 1.3134 1.3267 100.0 1.2092 1.2191 1.2294 1.2395 1.2498 1.2601 1.2703 150.0 1.1792 1.1883 1.1970 1.2056 1.2142 1.2232 1.2320 200.0 1.1550 1.1636 1.1712 1.1789 1.1864 1.1944 1.2023 _______________________________________________________________________________ Polymer (B): poly(styrene-co-acrylonitrile) 2005BRI Characterization: Mw/g.mol1 = 80000, 33 wt% acrylonitrile

Tait equation parameter functions: Range of data: T/K = 380-460, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.8892 + 5.23 104  − 3.0 108  2 294.0 exp(3.86 103  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 46000, Mw/g.mol1 = 89000, 11.8 mol% maleic anhydride, Tg/K = 391, Dylark 232, Acro Chemicals _______________________________________________________________________________

P/MPa T/K 429.93 439.99 450.33 460.55 470.95 481.28 491.35 501.55 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9734 0.9789 0.9846 0.9902 0.9959 1.0015 1.0072 1.0128 10 0.9668 0.9720 0.9774 0.9826 0.9879 0.9933 0.9985 1.0038 20 0.9606 0.9656 0.9706 0.9756 0.9806 0.9857 0.9906 0.9955 30 0.9551 0.9598 0.9644 0.9693 0.9741 0.9789 0.9836 0.9882 40 0.9498 0.9543 0.9589 0.9635 0.9680 0.9728 0.9771 0.9815 50 0.9450 0.9493 0.9537 0.9581 0.9625 0.9670 0.9713 0.9754 60 0.9405 0.9447 0.9488 0.9531 0.9573 0.9617 0.9658 0.9697 70 0.9361 0.9402 0.9442 0.9484 0.9525 0.9567 0.9606 0.9645 80 0.9320 0.9360 0.9400 0.9440 0.9479 0.9520 0.9558 0.9595 90 0.9282 0.9320 0.9359 0.9397 0.9436 0.9475 0.9511 0.9548 100 0.9245 0.9283 0.9320 0.9357 0.9395 0.9433 0.9469 0.9503 110 0.9210 0.9246 0.9283 0.9319 0.9356 0.9392 0.9428 0.9461 120 0.9176 0.9211 0.9247 0.9282 0.9318 0.9355 0.9388 0.9421 130 0.9144 0.9178 0.9213 0.9247 0.9283 0.9318 0.9350 0.9382 140 0.9114 0.9145 0.9180 0.9213 0.9248 0.9283 0.9314 0.9345 150 0.9086 0.9114 0.9148 0.9180 0.9215 0.9249 0.9279 0.9310 160 0.9059 0.9085 0.9118 0.9149 0.9183 0.9215 0.9246 0.9275 170 0.9034 0.9057 0.9087 0.9119 0.9152 0.9184 0.9213 0.9242 180 0.9011 0.9029 0.9058 0.9089 0.9121 0.9153 0.9181 0.9209 190 0.8989 0.9003 0.9030 0.9060 0.9092 0.9122 0.9151 0.9179 200 0.8967 0.8978 0.9002 0.9032 0.9063 0.9093 0.9120 0.9147 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 38000, Mw/g.mol1 = 73000, 14.5 mol% maleic anhydride, Tg/K = 403, Dylark 332, Acro Chemicals _______________________________________________________________________________

P/MPa T/K 438.23 453.03 468.23 483.07 497.88 512.98 527.76 543.63 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.95312 0.96159 0.97020 0.97900 0.98749 0.99685 1.00636 1.01598 10 0.94661 0.95461 0.96278 0.97117 0.97948 0.98793 0.99676 1.00574 20 0.94047 0.94803 0.95577 0.96382 0.97192 0.97952 0.98791 0.99625 30 0.93511 0.94234 0.94975 0.95748 0.96543 0.97267 0.98049 0.98853 40 0.93010 0.93709 0.94426 0.95172 0.95932 0.96613 0.97361 0.98087 50 0.92552 0.93227 0.93920 0.94633 0.95360 0.96026 0.96731 0.97434 continued

________________________________________________________________________

continued

60 0.92108 0.92769 0.93438 0.94137 0.94835 0.95479 0.96157 0.96835 70 0.91696 0.92343 0.92993 0.93663 0.94346 0.94965 0.95619 0.96272 80 0.91317 0.91930 0.92561 0.93221 0.93881 0.94477 0.95114 0.95738 90 0.90939 0.91538 0.92155 0.92801 0.93436 0.94026 0.94640 0.95243 100 0.90588 0.91173 0.91776 0.92398 0.93019 0.93594 0.94183 0.94766 110 0.90270 0.90821 0.91401 0.92017 0.92614 0.93175 0.93749 0.94317 120 0.89964 0.90468 0.91046 0.91646 0.92221 0.92786 0.93336 0.93898 130 0.89684 0.90147 0.90698 0.91297 0.91855 0.92405 0.92940 0.93488 140 0.89423 0.89822 0.90368 0.90952 0.91502 0.92029 0.92574 0.93086 150 0.89170 0.89524 0.90047 0.90623 0.91165 0.91686 0.92204 0.92717 160 0.88941 0.89232 0.89749 0.90306 0.90838 0.91345 0.91864 0.92349 170 0.88715 0.88970 0.89444 0.89995 0.90514 0.91016 0.91521 0.92001 180 0.88503 0.88713 0.89162 0.89714 0.90203 0.90713 0.91202 0.91675 190 0.88301 0.88478 0.88883 0.89424 0.89914 0.90410 0.90891 0.91352 200 0.88108 0.88259 0.88618 0.89154 0.89639 0.90118 0.90599 0.91042 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 27000, Mw/g.mol1 = 52000, 25.3 mol% maleic anhydride, Tg/K = 426, DSM Research, The Netherlands _______________________________________________________________________________

P/MPa T/K 433.38 443.34 453.79 463.81 474.02 484.58 494.50 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.90381 0.90882 0.91386 0.91875 0.92377 0.92873 0.93396 10 0.89850 0.90314 0.90789 0.91255 0.91728 0.92207 0.92699 20 0.89344 0.89774 0.90231 0.90672 0.91115 0.91581 0.92040 30 0.88892 0.89294 0.89719 0.90150 0.90574 0.91025 0.91469 40 0.88492 0.88847 0.89250 0.89665 0.90077 0.90501 0.90940 50 0.88133 0.88425 0.88818 0.89210 0.89614 0.90017 0.90438 60 0.87808 0.88035 0.88407 0.88792 0.89178 0.89574 0.89980 70 0.87505 0.87682 0.88013 0.88393 0.88762 0.89144 0.89543 80 0.87238 0.87359 0.87644 0.88011 0.88372 0.88748 0.89127 90 0.86978 0.87061 0.87307 0.87653 0.88004 0.88366 0.88744 100 0.86734 0.86786 0.86982 0.87307 0.87652 0.87999 0.88366 110 0.86506 0.86533 0.86676 0.86981 0.87317 0.87661 0.88014 120 0.86290 0.86291 0.86403 0.86666 0.86995 0.87326 0.87673 130 0.86076 0.86075 0.86139 0.86362 0.86684 0.87000 0.87352 140 0.85863 0.85853 0.85901 0.86086 0.86381 0.86699 0.87036 150 0.85664 0.85644 0.85671 0.85814 0.86093 0.86403 0.86745 160 0.85467 0.85438 0.85454 0.85567 0.85811 0.86115 0.86448 170 0.85279 0.85244 0.85243 0.85324 0.85543 0.85836 0.86164 180 0.85099 0.85063 0.85046 0.85102 0.85281 0.85562 0.85894 190 0.84910 0.84870 0.84853 0.84888 0.85036 0.85299 0.85618 200 0.84736 0.84696 0.84661 0.84688 0.84798 0.85036 0.85346 _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 28000, Mw/g.mol1 = 54000, 30.9 mol% maleic anhydride, Tg/K = 439, DSM Research, The Netherlands _______________________________________________________________________________

P/MPa T/K 449.64 459.76 470.05 480.33 490.76 501.01 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.88563 0.89054 0.89530 0.90032 0.90511 0.91030 10 0.88037 0.88501 0.88956 0.89428 0.89892 0.90383 20 0.87534 0.87973 0.88410 0.88852 0.89309 0.89770 30 0.87093 0.87511 0.87925 0.88354 0.88787 0.89238 40 0.86679 0.87074 0.87472 0.87881 0.88301 0.88742 50 0.86311 0.86668 0.87057 0.87448 0.87853 0.88271 60 0.85976 0.86287 0.86657 0.87037 0.87427 0.87833 70 0.85681 0.85936 0.86286 0.86660 0.87037 0.87430 80 0.85412 0.85597 0.85938 0.86288 0.86661 0.87041 90 0.85160 0.85304 0.85601 0.85944 0.86303 0.86679 100 0.84933 0.85019 0.85276 0.85614 0.85961 0.86332 110 0.84707 0.84771 0.84979 0.85296 0.85639 0.85997 120 0.84500 0.84528 0.84693 0.84992 0.85330 0.85683 130 0.84297 0.84311 0.84432 0.84701 0.85030 0.85373 140 0.84103 0.84099 0.84186 0.84423 0.84742 0.85078 150 0.83916 0.83900 0.83956 0.84157 0.84463 0.84795 160 0.83728 0.83711 0.83743 0.83909 0.84197 0.84515 170 0.83556 0.83521 0.83539 0.83667 0.83930 0.84247 180 0.83384 0.83341 0.83348 0.83440 0.83681 0.83993 190 0.83210 0.83168 0.83156 0.83229 0.83437 0.83736 200 0.83043 0.82993 0.82977 0.83025 0.83197 0.83483 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 30000, Mw/g.mol1 = 58000, 34.7 mol% maleic anhydride, Tg/K = 449, DSM Research, The Netherlands _______________________________________________________________________________

P/MPa T/K 460.25 470.41 480.76 491.06 501.28 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.87138 0.87623 0.88109 0.88602 0.89124 10 0.86613 0.87072 0.87531 0.87999 0.88490 20 0.86112 0.86542 0.86981 0.87428 0.87890 30 0.85668 0.86087 0.86501 0.86928 0.87372 40 0.85255 0.85653 0.86055 0.86471 0.86895 50 0.84869 0.85252 0.85639 0.86037 0.86454 continued

________________________________________________________________________

continued

60 0.84526 0.84872 0.85248 0.85633 0.86023 70 0.84203 0.84511 0.84879 0.85250 0.85636 80 0.83917 0.84175 0.84526 0.84886 0.85264 90 0.83657 0.83862 0.84191 0.84541 0.84913 100 0.83421 0.83568 0.83877 0.84214 0.84573 110 0.83193 0.83304 0.83571 0.83902 0.84257 120 0.82982 0.83053 0.83280 0.83603 0.83948 130 0.82778 0.82827 0.83012 0.83319 0.83653 140 0.82589 0.82609 0.82758 0.83043 0.83372 150 0.82407 0.82411 0.82520 0.82774 0.83096 160 0.82221 0.82212 0.82299 0.82519 0.82829 170 0.82052 0.82026 0.82087 0.82277 0.82567 180 0.81877 0.81848 0.81893 0.82048 0.82319 190 0.81707 0.81679 0.81704 0.81824 0.82074 200 0.81546 0.81506 0.81521 0.81612 0.81838 _______________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-2,2-bis(trifluoromethyl)- 4,5-difluoro-1,3-dioxole] 2008DLU Characterization: 13 mol% tetrafluoroethylene, Tg/K = 513, Teflon AF2400, Random Technologies, San Francisco _______________________________________________________________________________

T/K P/MPa 0.1 10 20 30 40 50 80 120 Vspec/cm3g1 _______________________________________________________________________________

515.46 0.60962 530.86 0.61813 0.60334 545.85 0.63020 0.60984 0.59384 561.43 0.64216 0.61663 0.59853 0.58673 576.08 0.65486 0.62419 0.60382 0.59045 0.58055 591.38 0.66872 0.63258 0.61011 0.59535 0.58425 0.57576 606.33 0.68364 0.64084 0.61603 0.59990 0.58794 0.57845 0.56060 620.76 0.70048 0.64989 0.62279 0.60520 0.59233 0.58215 0.56155 0.54661 635.12 0.71977 0.65951 0.62983 0.61103 0.59729 0.58644 0.56364 0.54727 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 515-635, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0781 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.6490 − 8.8 104  + 2.97 106  2 978.0 exp(1.45 102  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-2,2-bis(trifluoromethyl)- 4,5-difluoro-1,3-dioxole 2008DLU Characterization: 35 mol% tetrafluoroethylene, Tg/K = 433, Teflon AF1600, Random Technologies, San Francisco _______________________________________________________________________________

T/K P/MPa 0.1 10 20 30 40 50 80 120 Vspec/cm3g1 _______________________________________________________________________________

454.64 0.58246 0.57009 469.94 0.59302 0.57728 0.56497 485.28 0.60202 0.58446 0.57119 0.56091 494.60 0.61134 0.59105 0.57604 0.56521 0.55659 500.69 0.61170 0.59195 0.57741 0.56647 0.55760 515.39 0.62201 0.59985 0.58398 0.57223 0.56280 0.55493 530.90 0.63310 0.60801 0.59068 0.57796 0.56798 0.55979 0.54113 546.16 0.64493 0.61633 0.59731 0.58374 0.57312 0.56451 0.54493 561.62 0.65675 0.62455 0.60397 0.58959 0.57826 0.56910 0.54876 0.53038 576.55 0.66967 0.63313 0.61082 0.59535 0.58353 0.57393 0.55259 0.53351 592.00 0.68299 0.64161 0.61745 0.60112 0.58871 0.57854 0.55629 0.53669 607.04 0.69873 0.65091 0.62464 0.60721 0.59390 0.58332 0.56014 0.53994 621.74 0.71654 0.66043 0.63173 0.61320 0.59920 0.58808 0.56414 0.54318 636.12 0.74124 0.67156 0.63966 0.61976 0.60489 0.59319 0.56818 0.54651 520.34 0.62808 0.60361 0.58650 0.57425 0.56463 0.55659 0.53843 0.52454 494.60 0.61134 0.59105 0.57604 0.56521 0.55659 0.54926 0.53510 0.52399 _______________________________________________________________________________

continued _______________________________________________________________________________

T/K P/MPa 160 200 Vspec/cm3g1 _______________________________________________________________________________

607.04 0.52524 0.51358 621.74 0.52817 0.51602 636.12 0.53105 0.51860 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 435-635, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]} with C = 0.0760 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.5494 − 1.4 104  + 1.80 106  2 256.0 exp(1.13 102  ) _______________________________________________________________________________

________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-perfluoro(methyl vinyl ether)] 2004DLU Characterization: Mw/g.mol1 = 100000, 15-55 mol% perfluoro(methyl vinyl ether), Tg/K = 271, Dyneon Perfluoroelastomer PFE, Dyneon GmbH & Co. KG, Burgkirchen, Germany _______________________________________________________________________________

P/MPa T/K 298.94 299.465 300.77 305.746 310.59 315.415 320.21 324.945 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.48071 0.48126 0.48153 0.48376 0.48600 0.48813 0.49042 0.49279 10 0.47712 0.47765 0.47790 0.47996 0.48204 0.48410 0.48621 0.48841 20 0.47372 0.47426 0.47449 0.47640 0.47832 0.48041 0.48235 0.48437 30 0.47071 0.47124 0.47141 0.47321 0.47505 0.47704 0.47886 0.48080 40 0.46793 0.46837 0.46866 0.47039 0.47208 0.47395 0.47571 0.47748 50 0.46540 0.46582 0.46600 0.46777 0.46943 0.47121 0.47282 0.47452 60 0.46304 0.46345 0.46370 0.46524 0.46684 0.46854 0.47016 0.47184 70 0.46084 0.46125 0.46146 0.46303 0.46453 0.46612 0.46772 0.46928 80 0.45884 0.45916 0.45941 0.46087 0.46232 0.46395 0.46540 0.46697 90 0.45695 0.45726 0.45744 0.45890 0.46032 0.46189 0.46318 0.46477 100 0.45511 0.45545 0.45566 0.45706 0.45840 0.45987 0.46128 0.46266 110 0.45351 0.45376 0.45398 0.45519 0.45661 0.45801 0.45936 0.46071 120 0.45193 0.45224 0.45239 0.45361 0.45484 0.45628 0.45757 0.45887 130 0.45055 0.45078 0.45096 0.45204 0.45321 0.45460 0.45581 0.45721 140 0.44923 0.44943 0.44957 0.45058 0.45170 0.45298 0.45426 0.45552 150 0.44791 0.44820 0.44826 0.44918 0.45019 0.45142 0.45266 0.45394 160 0.44676 0.44695 0.44702 0.44788 0.44882 0.45002 0.45110 0.45241 170 0.44563 0.44582 0.44585 0.44662 0.44742 0.44861 0.44976 0.45084 180 0.44452 0.44470 0.44477 0.44541 0.44627 0.44723 0.44832 0.44954 190 0.44343 0.44361 0.44369 0.44436 0.44506 0.44599 0.44701 0.44816 200 0.44242 0.44258 0.44266 0.44322 0.44392 0.44481 0.44567 0.44676 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 329.77 334.65 364.545 379.32 394.37 409.58 424.67 439.995 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.49520 0.49745 0.51195 0.51929 0.52691 0.53482 0.54252 0.55074 10 0.49061 0.49271 0.50598 0.51266 0.51952 0.52655 0.53330 0.54041 20 0.48639 0.48837 0.50055 0.50673 0.51302 0.51934 0.52541 0.53170 30 0.48264 0.48451 0.49599 0.50175 0.50756 0.51336 0.51890 0.52470 40 0.47945 0.48103 0.49190 0.49731 0.50279 0.50820 0.51337 0.51865 50 0.47626 0.47791 0.48826 0.49338 0.49852 0.50358 0.50850 0.51349 60 0.47346 0.47505 0.48494 0.48979 0.49466 0.49952 0.50412 0.50880 continued

________________________________________________________________________

continued

70 0.47096 0.47246 0.48189 0.48655 0.49125 0.49588 0.50018 0.50469 80 0.46853 0.46997 0.47916 0.48354 0.48807 0.49252 0.49670 0.50088 90 0.46624 0.46773 0.47648 0.48076 0.48512 0.48939 0.49340 0.49743 100 0.46419 0.46555 0.47409 0.47822 0.48244 0.48652 0.49034 0.49431 110 0.46222 0.46357 0.47181 0.47581 0.47989 0.48386 0.48750 0.49127 120 0.46034 0.46153 0.46968 0.47350 0.47752 0.48124 0.48489 0.48853 130 0.45847 0.45977 0.46768 0.47141 0.47524 0.47902 0.48239 0.48589 140 0.45672 0.45802 0.46567 0.46939 0.47313 0.47665 0.48003 0.48346 150 0.45513 0.45636 0.46387 0.46750 0.47107 0.47458 0.47781 0.48110 160 0.45359 0.45478 0.46212 0.46567 0.46918 0.47257 0.47571 0.47888 170 0.45209 0.45318 0.46039 0.46382 0.46733 0.47060 0.47365 0.47682 180 0.45064 0.45179 0.45881 0.46219 0.46550 0.46875 0.47174 0.47473 190 0.44922 0.45039 0.45715 0.46048 0.46379 0.46693 0.46986 0.47291 200 0.44789 0.44897 0.45558 0.45885 0.46211 0.46517 0.46805 0.47099 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 455.57 470.84 486.094 501.76 516.876 532.605 547.58 563.503 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.55918 0.56803 0.57704 0.58677 0.59692 0.60765 0.61919 0.63239 10 0.54763 0.55503 0.56253 0.57050 0.57862 0.58717 0.59594 0.60571 20 0.53807 0.54446 0.55103 0.55784 0.56481 0.57220 0.57940 0.58748 30 0.53042 0.53616 0.54196 0.54819 0.55429 0.56079 0.56720 0.57425 40 0.52403 0.52922 0.53460 0.54012 0.54576 0.55170 0.55735 0.56373 50 0.51842 0.52327 0.52822 0.53327 0.53858 0.54396 0.54926 0.55514 60 0.51345 0.51811 0.52263 0.52743 0.53235 0.53729 0.54220 0.54772 70 0.50910 0.51340 0.51768 0.52218 0.52679 0.53149 0.53613 0.54126 80 0.50509 0.50925 0.51334 0.51764 0.52191 0.52631 0.53066 0.53556 90 0.50142 0.50530 0.50926 0.51334 0.51748 0.52170 0.52591 0.53049 100 0.49808 0.50178 0.50558 0.50952 0.51339 0.51749 0.52140 0.52594 110 0.49496 0.49864 0.50221 0.50600 0.50975 0.51358 0.51737 0.52174 120 0.49211 0.49556 0.49911 0.50260 0.50625 0.51003 0.51358 0.51789 130 0.48939 0.49276 0.49614 0.49960 0.50307 0.50661 0.51018 0.51428 140 0.48683 0.49005 0.49329 0.49668 0.50015 0.50351 0.50701 0.51089 150 0.48440 0.48752 0.49069 0.49400 0.49720 0.50054 0.50394 0.50768 160 0.48209 0.48515 0.48820 0.49137 0.49448 0.49781 0.50102 0.50473 170 0.47982 0.48284 0.48579 0.48898 0.49200 0.49513 0.49831 0.50202 180 0.47771 0.48076 0.48353 0.48662 0.48957 0.49270 0.49574 0.49930 190 0.47574 0.47852 0.48133 0.48431 0.48729 0.49021 0.49331 0.49668 200 0.47374 0.47647 0.47923 0.48212 0.48504 0.48780 0.49075 0.49425 _______________________________________________________________________________

continued

________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 578.20 593.788 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.64774 0.66445 10 0.61667 0.62784 20 0.59638 0.60530 30 0.58195 0.58955 40 0.57068 0.57742 50 0.56140 0.56751 60 0.55359 0.55915 70 0.54677 0.55204 80 0.54072 0.54569 90 0.53548 0.54008 100 0.53064 0.53501 110 0.52626 0.53044 120 0.52224 0.52617 130 0.51841 0.52227 140 0.51490 0.51863 150 0.51161 0.51522 160 0.50851 0.51203 170 0.50566 0.50896 180 0.50287 0.50608 190 0.50014 0.50333 200 0.49764 0.50070 _______________________________________________________________________________ Polymer (B): poly(vinylidene fluoride-co-hexafluoropropylene) 2001MEK Characterization: Mn/g.mol1 = 145000, Mw/g.mol1 = 480000, 3.1 mol% hexafluoropropylene, ATOFINA Chemicals, Philadelphia, PA

_______________________________________________________________________________

P/MPa T/K 433.15 438.15 443.15 448.15 453.15 458.15 463.15 468.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6500 0.6520 0.6546 0.6569 0.6589 0.6615 0.6639 0.6660 20.0 0.6402 0.6422 0.6444 0.6466 0.6485 0.6508 0.6530 0.6549 40.0 0.6304 0.6323 0.6342 0.6362 0.6381 0.6402 0.6420 0.6439 80.0 0.6170 0.6184 0.6200 0.6216 0.6232 0.6247 0.6263 0.6280 120.0 0.6064 0.6079 0.6092 0.6107 0.6120 0.6135 0.6148 0.6163 _______________________________________________________________________________ continued

________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 473.15 478.15 483.15 488.15 493.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6682 0.6707 0.6728 0.6747 0.6771 20.0 0.6567 0.6587 0.6605 0.6625 0.6642 40.0 0.6459 0.6479 0.6498 0.6515 0.6525 80.0 0.6294 0.6316 0.6330 0.6346 0.6361 120.0 0.6176 0.6189 0.6202 0.6216 0.6224 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 433-493, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.587 + 4.138 104  157.7 exp(2.83 103  ) _______________________________________________________________________________ Polymer (B): poly(vinylidene fluoride-co-hexafluoropropylene) 2001MEK Characterization: Mn/g.mol1 = 111000, Mw/g.mol1 = 321000, 10.5 mol% hexafluoropropylene, ATOFINA Chemicals, Philadelphia, PA

_______________________________________________________________________________

P/MPa T/K 433.15 438.15 443.15 448.15 453.15 458.15 463.15 468.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6468 0.6492 0.6512 0.6535 0.6558 0.6577 0.6601 0.6624 20.0 0.6377 0.6399 0.6419 0.6438 0.6459 0.6477 0.6501 0.6520 40.0 0.6282 0.6302 0.6322 0.6338 0.6355 0.6375 0.6396 0.6416 80.0 0.6146 0.6159 0.6175 0.6196 0.6210 0.6221 0.6242 0.6259 120.0 0.6043 0.6057 0.6070 0.6083 0.6098 0.6112 0.6125 0.6138 _______________________________________________________________________________ continued

________________________________________________________________________

continued

_______________________________________________________________________________

P/MPa T/K 473.15 478.15 483.15 488.15 493.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6639 0.6661 0.6681 0.6698 0.6723 20.0 0.6534 0.6558 0.6577 0.6594 0.6612 40.0 0.6435 0.6455 0.6473 0.6491 0.6503 80.0 0.6270 0.6288 0.6304 0.6315 0.6328 120.0 0.6151 0.6164 0.6177 0.6187 0.6196 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 433-493, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.577 + 4.543 104  207.1 exp(4.15 103  ) _______________________________________________________________________________ Polymer (B): poly(vinylidene fluoride-co-hexafluoropropylene) 2001MEK Characterization: Mn/g.mol1 = 143000, Mw/g.mol1 = 471000, 11.1 mol% hexafluoropropylene, ATOFINA Chemicals, Philadelphia, PA

_______________________________________________________________________________

P/MPa T/K 448.15 453.15 458.15 463.15 468.15 473.15 478.15 483.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6589 0.6613 0.6639 0.6657 0.6681 0.6700 0.6718 0.6739 20.0 0.6488 0.6506 0.6532 0.6549 0.6570 0.6587 0.6608 0.6629 40.0 0.6380 0.6401 0.6420 0.6440 0.6461 0.6481 0.6500 0.6520 80.0 0.6233 0.6250 0.6266 0.6282 0.6296 0.6313 0.6329 0.6343 120.0 0.6122 0.6136 0.6151 0.6165 0.6179 0.6192 0.6207 0.6220 _______________________________________________________________________________ continued

________________________________________________________________________

continued

_______________________________________________________________________________

P/MPa T/K 488.15 493.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.6760 0.6776 20.0 0.6648 0.6666 40.0 0.6536 0.6554 80.0 0.6358 0.6370 120.0 0.6230 0.6234 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 448-493, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.580 + 4.201 104  183.15 exp(3.35 103  ) _______________________________________________________________________________ Polymer (B): poly(vinylidene fluoride-co-hexafluoropropylene) 2004DLU Characterization: Mw/g.mol1 = 85000, 22.0 mol% hexafluoropropylene, Tg/K = 255, Fluorel FC-2175, Dyneon GmbH & Co. KG, Burgkirchen, Germany _______________________________________________________________________________

P/MPa T/K 302.885 305.956 310.925 315.605 320.35 325.19 329.995 334.935 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.55660 0.55805 0.56011 0.56223 0.56447 0.56675 0.56887 0.57099 10 0.55358 0.55495 0.55696 0.55897 0.56106 0.56321 0.56523 0.56728 20 0.55065 0.55193 0.55394 0.55582 0.55787 0.55982 0.56176 0.56377 30 0.54808 0.54935 0.55120 0.55309 0.55497 0.55686 0.55872 0.56064 40 0.54569 0.54693 0.54870 0.55053 0.55234 0.55417 0.55590 0.55782 50 0.54343 0.54463 0.54633 0.54810 0.54981 0.55163 0.55342 0.55518 60 0.54133 0.54249 0.54418 0.54591 0.54761 0.54932 0.55098 0.55277 70 0.53940 0.54049 0.54214 0.54378 0.54537 0.54712 0.54876 0.55041 80 0.53749 0.53853 0.54017 0.54178 0.54333 0.54501 0.54663 0.54827 90 0.53565 0.53677 0.53823 0.53991 0.54140 0.54304 0.54450 0.54615 100 0.53396 0.53501 0.53643 0.53804 0.53958 0.54112 0.54264 0.54422 110 0.53221 0.53333 0.53480 0.53631 0.53782 0.53930 0.54073 0.54233

continued

________________________________________________________________________

continued

120 0.53066 0.53170 0.53316 0.53464 0.53609 0.53752 0.53900 0.54051 130 0.52918 0.53019 0.53149 0.53301 0.53444 0.53591 0.53729 0.53880 140 0.52763 0.52869 0.53001 0.53144 0.53282 0.53421 0.53564 0.53712 150 0.52615 0.52720 0.52850 0.52993 0.53128 0.53276 0.53405 0.53545 160 0.52477 0.52572 0.52714 0.52850 0.52984 0.53118 0.53256 0.53389 170 0.52349 0.52441 0.52572 0.52703 0.52845 0.52971 0.53105 0.53239 180 0.52215 0.52302 0.52438 0.52558 0.52699 0.52831 0.52959 0.53093 190 0.52081 0.52176 0.52298 0.52428 0.52562 0.52697 0.52812 0.52944 200 0.51953 0.52041 0.52171 0.52299 0.52421 0.52559 0.52680 0.52805 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 349.80 364.62 379.445 394.216 409.46 424.545 439.605 454.74 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.57769 0.58435 0.59123 0.59827 0.60540 0.61294 0.62032 0.62744 10 0.57356 0.57983 0.58628 0.59284 0.59946 0.60644 0.61322 0.61975 20 0.56971 0.57563 0.58170 0.58779 0.59404 0.60059 0.60689 0.61288 30 0.56623 0.57190 0.57767 0.58355 0.58938 0.59549 0.60147 0.60710 40 0.56319 0.56863 0.57411 0.57969 0.58527 0.59106 0.59665 0.60202 50 0.56033 0.56552 0.57083 0.57611 0.58144 0.58707 0.59231 0.59740 60 0.55765 0.56272 0.56776 0.57286 0.57806 0.58335 0.58840 0.59319 70 0.55520 0.56007 0.56495 0.56984 0.57481 0.57995 0.58475 0.58938 80 0.55282 0.55756 0.56230 0.56702 0.57188 0.57678 0.58137 0.58584 90 0.55069 0.55527 0.55981 0.56448 0.56910 0.57384 0.57824 0.58255 100 0.54855 0.55302 0.55745 0.56186 0.56643 0.57104 0.57530 0.57949 110 0.54655 0.55089 0.55522 0.55956 0.56398 0.56849 0.57259 0.57661 120 0.54460 0.54892 0.55313 0.55738 0.56164 0.56598 0.56997 0.57386 130 0.54282 0.54703 0.55108 0.55524 0.55938 0.56359 0.56745 0.57123 140 0.54103 0.54515 0.54915 0.55318 0.55722 0.56137 0.56509 0.56879 150 0.53936 0.54337 0.54727 0.55125 0.55516 0.55922 0.56282 0.56635 160 0.53775 0.54162 0.54547 0.54937 0.55325 0.55710 0.56065 0.56413 170 0.53621 0.53996 0.54374 0.54756 0.55129 0.55517 0.55859 0.56194 180 0.53461 0.53835 0.54207 0.54574 0.54949 0.55313 0.55655 0.55985 190 0.53311 0.53679 0.54046 0.54401 0.54762 0.55131 0.55461 0.55780 200 0.53163 0.53527 0.53886 0.54236 0.54592 0.54949 0.55268 0.55579 _______________________________________________________________________________ continued

________________________________________________________________________

continued

_______________________________________________________________________________

P/MPa T/K 470.07 485.945 501.34 516.63 531.755 547.27 562.18 576.84 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.63500 0.64298 0.65111 0.65955 0.66830 0.67810 0.68808 0.69928 10 0.62653 0.63368 0.64087 0.64826 0.65593 0.66419 0.67261 0.68196 20 0.61908 0.62559 0.63210 0.63869 0.64560 0.65275 0.66017 0.66837 30 0.61287 0.61886 0.62481 0.63088 0.63724 0.64374 0.65032 0.65774 40 0.60735 0.61294 0.61853 0.62416 0.63006 0.63601 0.64214 0.64887 50 0.60244 0.60776 0.61295 0.61818 0.62378 0.62926 0.63504 0.64125 60 0.59799 0.60304 0.60795 0.61296 0.61811 0.62328 0.62876 0.63461 70 0.59400 0.59874 0.60344 0.60814 0.61309 0.61796 0.62306 0.62870 80 0.59021 0.59479 0.59932 0.60382 0.60845 0.61315 0.61801 0.62331 90 0.58676 0.59116 0.59549 0.59978 0.60422 0.60870 0.61329 0.61844 100 0.58355 0.58779 0.59187 0.59607 0.60036 0.60465 0.60907 0.61389 110 0.58053 0.58454 0.58854 0.59262 0.59671 0.60086 0.60510 0.60977 120 0.57767 0.58160 0.58544 0.58931 0.59331 0.59728 0.60138 0.60594 130 0.57499 0.57878 0.58251 0.58619 0.59014 0.59393 0.59791 0.60227 140 0.57236 0.57607 0.57975 0.58332 0.58714 0.59076 0.59469 0.59890 150 0.56987 0.57353 0.57705 0.58056 0.58423 0.58786 0.59154 0.59570 160 0.56753 0.57107 0.57451 0.57795 0.58148 0.58494 0.58855 0.59262 170 0.56529 0.56868 0.57212 0.57539 0.57888 0.58221 0.58578 0.58972 180 0.56315 0.56646 0.56974 0.57293 0.57632 0.57966 0.58308 0.58694 190 0.56106 0.56421 0.56752 0.57058 0.57389 0.57713 0.58046 0.58424 200 0.55896 0.56207 0.56531 0.56830 0.57162 0.57463 0.57796 0.58170 _______________________________________________________________________________

________________________________________________________________________ 6.2. Excess volumes and/or densities of copolymer solutions Polymer (B): poly(ethylene-co-1-butene) 2000BY2 Characterization: Mn/g.mol1 = 175000, Mw/g.mol1 = 177000, 94 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): dimethyl ether C2H6O 115-10-6

T/K = 383.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.669 0.683 0.701 0.725 0.763 0.793 0.818 0.840 0.860

T/K = 393.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.660 0.675 0.694 0.719 0.759 0.790 0.816 0.839 0.859

T/K = 403.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.643 0.659 0.678 0.705 0.746 0.777 0.803 0.826 0.846

T/K = 423.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.612 0.632 0.655 0.684 0.727 0.760 0.787 0.811 0.831 Polymer (B): poly(ethylene-co-1-butene) 2000BY2 Characterization: Mn/g.mol1 = 230000, Mw/g.mol1 = 232000, 20.2 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): dimethyl ether-d6 C2D6O 17222-37-6

T/K = 383.15 wB 0.05

P/bar 1001.7 1036.2 1105.2 1174.1 1280.6 1381.0 1484.5 1725.9 1932.8 /(g/cm3) 0.850 0.857 0.860 0.868 0.872 0.889 0.898 0.921 0.938

P/bar 2070.7 2312.1 2401.7 /(g/cm3) 0.949 0.969 0.980

T/K = 393.15 wB 0.05

P/bar 760.3 829.3 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.813 0.823 0.848 0.883 0.915 0.945 0.959

T/K = 403.15 wB 0.05

P/bar 650.0 670.7 691.4 829.3 1036.2 1381.0 1725.9 2139.7 2415.5 /(g/cm3) 0.778 0.781 0.785 0.804 0.830 0.866 0.896 0.929 0.959

continued

________________________________________________________________________

continued

T/K = 423.15 wB 0.05

P/bar 622.4 691.4 829.3 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.748 0.760 0.782 0.809 0.846 0.878 0.906 0.933 Polymer (B): poly(ethylene-co-1-butene) 2000BY2 Characterization: Mn/g.mol1 = 175000, Mw/g.mol1 = 177000, 94 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): dimethyl ether-d6 C2D6O 17222-37-6

T/K = 383.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.685 0.698 0.715 0.739 0.776 0.804 0.828 0.849 0.867

T/K = 393.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.676 0.690 0.708 0.733 0.772 0.801 0.826 0.847 0.866

T/K = 403.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.659 0.675 0.694 0.720 0.759 0.789 0.814 0.835 0.854

T/K = 423.15 wB 0.05

P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5 /(g/cm3) 0.630 0.649 0.671 0.699 0.740 0.772 0.798 0.821 0.840 Polymer (B): poly(ethylene-co-1-butene) (deuterated) 2000BY1 Characterization: Mn/g.mol1 = 155000, Mw/g.mol1 = 169000, 3 mol% 1-butene, synthesized from polymerization of deuterated 1,3-butadiene by controlled 1,2-addition, Polymer Source, Inc., Dorval, Quebec Solvent (A): ethane C2H6 74-84-0

T/K = 393.15 wB 0.024

P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9 /(g/cm3) 0.511 0.518 0.523 0.532 0.546 0.554 0.563 0.571 0.580

T/K = 403.15 wB 0.024

P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9 /(g/cm3) 0.506 0.513 0.518 0.528 0.541 0.551 0.561 0.570 0.578

T/K = 423.15 wB 0.024

P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9 /(g/cm3) 0.497 0.503 0.508 0.519 0.533 0.543 0.553 0.562 0.571

________________________________________________________________________ Polymer (B): poly(ethylene-co-1-butene) 2000BY1 Characterization: Mn/g.mol1 = 230000, Mw/g.mol1 = 232000, 20.2 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): ethane C2H6 74-84-0 Solvent (C): n-pentane-d12 C5D12 2031-90-5

T/K = 383.15

wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 P/bar 277.5 312.0 346.5 380.9 415.4 484.3 553.3 691.2 1035.9 /(g/cm3) 0.643 0.650 0.656 0.662 0.667 0.677 0.687 0.702 0.736

wA 0.231 0.231 0.231 0.231 wB 0.049 0.049 0.049 0.049 P/bar 1380.7 1725.4 2070.1 2414.9 /(g/cm3) 0.762 0.785 0.805 0.822

T/K = 403.15

wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 P/bar 277.5 312.0 346.5 380.9 415.4 484.3 553.3 691.2 1035.9 /(g/cm3) 0.622 0.630 0.634 0.645 0.651 0.662 0.672 0.689 0.724

wA 0.231 0.231 0.231 0.231 wB 0.049 0.049 0.049 0.049 P/bar 1380.7 1725.4 2070.1 2414.9 /(g/cm3) 0.752 0.775 0.796 0.814

T/K = 423.15

wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 P/bar 346.5 380.9 415.4 484.3 553.3 691.2 1035.9 1380.7 1725.4 /(g/cm3) 0.619 0.627 0.634 0.646 0.657 0.676 0.712 0.741 0.765

wA 0.231 0.231 wB 0.049 0.049 P/bar 2070.1 2414.9 /(g/cm3) 0.786 0.805 Polymer (B): poly(ethylene-co-1-butene) 2000BY1 Characterization: Mn/g.mol1 = 230000, Mw/g.mol1 = 232000, 20.2 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): n-pentane C5H12 109-66-0

T/K = 383.15 wB 0.053

P/bar 70.7 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7 /(g/cm3) 0.560 0.575 0.586 0.596 0.605 0.623 0.638 0.664 0.685

continued

________________________________________________________________________

continued

P/bar 2070.1 2414.9 /(g/cm3) 0.719 0.733

T/K = 403.15 wB 0.053

P/bar 45.2 70.7 139.6 208.6 277.5 346.5 415.4 484.4 553.3 /(g/cm3) 0.528 0.536 0.555 0.569 0.581 0.591 0.599 0.607 0.614

P/bar 622.2 691.2 760.1 829.1 898.0 967.0 1035.9 1104.9 1173.8 /(g/cm3) 0.621 0.627 0.633 0.639 0.644 0.649 0.654 0.659 0.663

P/bar 1242.8 1311.7 1380.7 1449.6 1518.5 1587.5 1656.4 1725.4 1794.3 /(g/cm3) 0.668 0.672 0.676 0.680 0.684 0.688 0.691 0.695 0.698

P/bar 1863.3 1932.2 2001.2 2070.1 /(g/cm3) 0.702 0.705 0.708 0.712

T/K = 423.15 wB 0.053

P/bar 105.1 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7 /(g/cm3) 0.525 0.535 0.552 0.566 0.577 0.599 0.617 0.645 0.668

P/bar 2070.1 2414.9 /(g/cm3) 0.704 0.720 Polymer (B): poly(ethylene-co-1-butene) 2000BY1 Characterization: Mn/g.mol1 = 230000, Mw/g.mol1 = 232000, 20.2 mol% 1-butene, Exxon Research and Engineering Co. Solvent (A): n-pentane-d12 C5D12 2031-90-5

T/K = 383.15 wB 0.051

P/bar 70.7 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7 /(g/cm3) 0.644 0.662 0.676 0.688 0.699 0.722 0.740 0.771 0.796

P/bar 2070.1 2414.9 /(g/cm3) 0.837 0.855

T/K = 403.15 wB 0.051

P/bar 70.7 77.6 84.5 91.3 105.1 125.8 139.6 174.1 208.6 /(g/cm3) 0.617 0.619 0.621 0.624 0.628 0.634 0.638 0.647 0.655

P/bar 277.5 346.5 518.8 689.5 1034.2 1380.7 2070.1 2414.9 /(g/cm3) 0.669 0.681 0.705 0.725 0.757 0.783 0.826 0.844

T/K = 423.15 wB 0.051

P/bar 108.6 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7 /(g/cm3) 0.605 0.616 0.635 0.651 0.664 0.692 0.714 0.747 0.774

P/bar 2070.1 2414.9 /(g/cm3) 0.818 0.837

________________________________________________________________________ Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2009FRA Characterization: Mn/g.mol1 = 2000, Mw/g.mol1 = 2100, 14 wt% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): dimethylsulfoxide C2H6OS 67-68-5

T/K = 298.15

wB 0.0000 0.0347 0.0671 0.1427 0.2102 0.2927 0.4061 0.4710 /(g/cm3) 1.09532 1.09268 1.09026 1.08463 1.07968 1.07354 1.06518 1.06030 V E/(cm3/g) 0.0 0.00022 0.00045 0.00098 0.00147 0.00194 0.00256 0.00278

wB 0.5717 0.6791 0.7731 0.8617 0.9684 1.0000 /(g/cm3) 1.05262 1.04429 1.03675 1.02943 1.02019 1.01738 V E /(cm3/g) 0.00295 0.00289 0.00249 0.00183 0.00049 0.0

T/K = 313.15

wB 0.0000 0.0347 0.0671 0.1427 0.2102 0.2927 0.4061 0.4710 /(g/cm3) 1.07983 1.07723 1.07493 1.06937 1.06456 1.05861 1.05061 1.04595 V E /(cm3/g) 0.0 0.00015 0.00039 0.00075 0.00117 0.00156 0.00215 0.00237

wB 0.5717 0.6791 0.7731 0.8617 0.9684 1.0000 /(g/cm3) 1.03869 1.03073 1.02359 1.01664 1.00789 1.00522 V E /(cm3/g) 0.00261 0.00256 0.00226 0.00166 0.00046 0.0 Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2009FRA Characterization: Mn/g.mol1 = 1240, Mw/g.mol1 = 1290, 15 wt% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): dimethylsulfoxide C2H6OS 67-68-5

T/K = 298.15

wB 0.0000 0.0248 0.0701 0.1459 0.2142 0.2884 0.4071 0.4902 /(g/cm3) 1.09532 1.09340 1.09006 1.08452 1.07954 1.07417 1.06552 1.05945 V E /(cm3/g) 0.0 0.00016 0.00044 0.00093 0.00135 0.00179 0.00234 0.00264

wB 0.5644 0.6861 0.7805 0.8595 0.9534 1.0000 /(g/cm3) 1.05392 1.04462 1.03724 1.03084 1.02300 1.01899 V E /(cm3/g) 0.00276 0.00263 0.00227 0.00168 0.00066 0.0

T/K = 313.15

wB 0.0000 0.0248 0.0701 0.1459 0.2142 0.2883 0.4071 0.4902 /(g/cm3) 1.07983 1.07794 1.07473 1.06947 1.06468 1.05961 1.05137 1.04560 V E /(cm3/g) 0.0 0.00015 0.00043 0.00095 0.00133 0.00183 0.00242 0.00277

wB 0.5644 0.6861 0.7806 0.8595 0.9534 1.0000 /(g/cm3) 1.04033 1.03147 1.02433 1.01815 1.01051 1.00660 V E /(cm3/g) 0.00291 0.00284 0.00243 0.00182 0.00071 0.0

________________________________________________________________________ Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2009FRA Characterization: Mn/g.mol1 = 2720, Mw/g.mol1 = 2890, 16 wt% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): dimethylsulfoxide C2H6OS 67-68-5

T/K = 298.15

wB 0.0000 0.0404 0.0642 0.1405 0.2113 0.2846 0.4078 0.4914 /(g/cm3) 1.09532 1.09233 1.09055 1.08495 1.07984 1.07453 1.06572 1.05972 V E /(cm3/g) 0.0 0.00016 0.00026 0.00062 0.00099 0.00131 0.00186 0.00213

wB 0.5629 0.6864 0.7715 0.8721 0.9595 1.0000 /(g/cm3) 1.05456 1.04544 1.03899 1.03112 1.02402 1.02065 V E /(cm3/g) 0.00230 0.00227 0.00203 0.00140 0.00052 0.0

T/K = 313.15

wB 0.0000 0.0404 0.0642 0.1405 0.2113 0.2846 0.4078 0.4914 /(g/cm3) 1.07983 1.07661 1.07491 1.06959 1.06475 1.05979 1.05146 1.04584 V E /(cm3/g) 0.0 0.00017 0.00025 0.00062 0.00099 0.00140 0.00199 0.00235

wB 0.5629 0.6864 0.7716 0.8721 0.9595 1.0000 /(g/cm3) 1.04097 1.03226 1.02602 1.01848 1.01158 1.00828 V E /(cm3/g) 0.00256 0.00253 0.00220 0.00156 0.00058 0.0 Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2009FRA Characterization: Mn/g.mol1 = 2110, Mw/g.mol1 = 2210, 51 wt% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): dimethylsulfoxide C2H6OS 67-68-5

T/K = 298.15

wB 0.0000 0.0335 0.0642 0.1462 0.2241 0.3081 0.4759 0.4939 /(g/cm3) 1.09532 1.09440 1.09342 1.09100 1.08870 1.08620 1.08080 1.08014 V E /(cm3/g) 0.0 0.00030 0.00048 0.00112 0.00173 0.00235 0.00322 0.00325

wB 0.5620 0.6804 0.7839 0.8703 0.9390 1.0000 /(g/cm3) 1.07778 1.07320 1.06873 1.06452 1.06101 1.05758 V E /(cm3/g) 0.00344 0.00334 0.00282 0.00194 0.00107 0.0

T/K = 313.15

wB 0.0000 0.0335 0.0642 0.1462 0.2241 0.3081 0.4759 0.4939 /(g/cm3) 1.07983 1.07883 1.07806 1.07583 1.07381 1.07155 1.06667 1.06608 V E /(cm3/g) 0.0 0.00027 0.00056 0.00116 0.00180 0.00242 0.00330 0.00333

wB 0.5620 0.6804 0.7839 0.8703 0.9390 1.0000 /(g/cm3) 1.06387 1.05966 1.05553 1.05163 1.04831 1.04504 V E /(cm3/g) 0.00348 0.00338 0.00287 0.00202 0.00111 0.0

________________________________________________________________________ Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2008COM Characterization: Mn/g.mol1 = 1220, Mw/g.mol1 = 1320, 19 mol% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): 2-methyltetrahydrofuran C5H10O 96-47-9

T/K = 298.15

wB 0.0000 0.0423 0.0938 0.1630 0.2670 0.3525 0.4740 0.5565 /(g/cm3) 0.84800 0.85434 0.86213 0.87276 0.88911 0.90290 0.92300 0.93708 V E /(cm3/g) 0.0 0.0004 0.0008 0.0013 0.0018 0.0021 0.0022 0.0022

wB 0.6247 0.7482 0.8195 0.8942 0.9629 1.0000 /(g/cm3) 0.94890 0.97104 0.98414 0.99813 1.01132 1.01856 V E /(cm3/g) 0.0020 0.0017 0.0013 0.0008 0.0003 0.0

T/K = 313.15

wB 0.0000 0.0423 0.0938 0.1630 0.2670 0.3525 0.4740 0.5565 /(g/cm3) 0.83238 0.83887 0.84690 0.85780 0.87456 0.88875 0.90944 0.92362 V E /(cm3/g) 0.0 0.0005 0.0011 0.0017 0.0024 0.0029 0.0032 0.0032

wB 0.6247 0.7482 0.8195 0.8942 0.9629 1.0000 /(g/cm3) 0.93596 0.95850 0.97183 0.98605 0.99938 1.00667 V E /(cm3/g) 0.0030 0.0024 0.0019 0.0012 0.0005 0.0 Polymer (B): poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) 2008COM Characterization: Mn/g.mol1 = 2280, Mw/g.mol1 = 2510, 59 mol% PEG, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): 2-methyltetrahydrofuran C5H10O 96-47-9

T/K = 298.15

wB 0.0000 0.0456 0.0981 0.1713 0.2670 0.3527 0.4755 0.5663 /(g/cm3) 0.84800 0.85613 0.86559 0.87910 0.89723 0.91397 0.93876 0.95779 V E /(cm3/g) 0.0 0.0006 0.0010 0.0017 0.0023 0.0027 0.0029 0.0029

wB 0.6320 0.7441 0.8145 0.8885 0.9648 1.0000 /(g/cm3) 0.97193 0.99683 1.01296 1.03040 1.04880 1.05747 V E /(cm3/g) 0.0027 0.0022 0.0018 0.0012 0.0004 0.0

T/K = 313.15

wB 0.0000 0.0456 0.0981 0.1713 0.2670 0.3527 0.4755 0.5663 /(g/cm3) 0.83238 0.84071 0.85042 0.86425 0.88276 0.89989 0.92529 0.94467 V E /(cm3/g) 0.0 0.0007 0.0014 0.0023 0.0031 0.0037 0.0041 0.0040

wB 0.6320 0.7441 0.8145 0.8885 0.9648 1.0000 /(g/cm3) 0.95912 0.98444 1.00080 1.01832 1.03697 1.04567 V E /(cm3/g) 0.0039 0.0032 0.0026 0.0016 0.0006 0.0

________________________________________________________________________ Polymer (B): poly(ethylene oxide-b-propylene oxide) 2004TAB Characterization: Mn/g.mol1 = 20700, EO316PO94, 77.1 mol% or 71.8 wt% ethylene oxide, synthesized in the laboratory Solvent (A): water H2O 7732-18-5

T/K = 278.15

cB/(g/L) 1.003 1.505 2.046 2.529 3.024 3.921 5.038 7.458 9.991 /(g/cm3) 1.00013 1.00021 1.00030 1.00038 1.00046 1.00060 1.00078 1.00118 1.00158

cB/(g/L) 12.092 14.991 17.409 19.838 /(g/cm3) 1.00192 1.00238 1.00277 1.00316

T/K = 283.15

cB/(g/L) 1.003 1.505 2.046 2.529 3.024 3.921 5.038 7.458 9.991 /(g/cm3) 0.99986 0.99994 1.00002 1.00010 1.00018 1.00032 1.00049 1.00087 1.00127

cB/(g/L) 12.092 14.991 17.409 19.838 /(g/cm3) 1.00159 1.00204 1.00242 1.00279

T/K = 288.15

cB/(g/L) 1.003 1.505 2.046 2.529 3.024 3.921 5.038 7.458 9.991 /(g/cm3) 0.99925 0.99933 0.99941 0.99948 0.99956 0.99969 0.99986 1.00023 1.00061

cB/(g/L) 12.092 14.991 17.409 19.838 /(g/cm3) 1.00092 1.00135 1.00171 1.00207

T/K = 293.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99835 0.99840 0.99848 0.99856 0.99864 0.99879 0.99897 0.99929 0.99965

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99995 1.00034 1.00067 1.00101

T/K = 298.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99718 0.99723 0.99729 0.99737 0.99744 0.99758 0.99774 0.99804 0.99837

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99864 0.99900 0.99929 0.99960

T/K = 303.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99577 0.99581 0.99588 0.99596 0.99602 0.99615 0.99631 0.99660 0.99692

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99719 0.99753 0.99782 0.99812

continued

________________________________________________________________________

continued

T/K = 308.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99415 0.99419 0.99426 0.99433 0.99440 0.99452 0.99468 0.99495 0.99527

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99553 0.99586 0.99614 0.99644

T/K = 313.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99233 0.99237 0.99244 0.99251 0.99257 0.99269 0.99285 0.99312 0.99342

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99368 0.99400 0.99428 0.99456

T/K = 318.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.99032 0.99037 0.99043 0.99050 0.99056 0.99068 0.99083 0.99109 0.99139

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.99164 0.99196 0.99223 0.99251

T/K = 323.15

cB/(g/L) 0.989 1.322 1.846 2.453 2.995 4.024 5.305 7.581 10.162 /(g/cm3) 0.98814 0.98818 0.98824 0.98831 0.98837 0.98849 0.98864 0.98890 0.98919

cB/(g/L) 12.340 15.132 17.467 19.935 /(g/cm3) 0.98944 0.98975 0.99001 0.99029 Polymer (B): poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) 2006DE1 Characterization: Mn/g.mol1 = 11400, EO103PO39EO103, 15.9 mol% propylene oxide, F88, BASF AG, Germany Solvent (A): water H2O 7732-18-5

T/K = 298.15

cB/(mol/kg) 0.00000 0.00126 0.00208 0.00382 0.00393 0.00489 0.00491 0.00559 /(g/cm3) 0.99705 0.99919 1.00057 1.00339 1.00361 1.00516 1.00515 1.00622

cB/(mol/kg) 0.00668 0.00739 0.00749 0.00831 0.01021 0.01245 0.01376 0.01450 /(g/cm3) 1.00789 1.00900 1.00913 1.01036 1.01314 1.01634 1.01813 1.01921

cB/(mol/kg) 0.01526 0.01667 0.01939 0.02007 0.02126 0.02350 /(g/cm3) 1.02018 1.02201 1.02551 1.02627 1.02757 1.02998

T/K = 308.15

cB/(mol/kg) 0.00000 0.00126 0.00201 0.00208 0.00292 0.00302 0.00382 0.00393 /(g/cm3) 0.99404 0.99609 0.99728 0.99739 0.99870 0.99886 1.00009 1.00027

continued

________________________________________________________________________

continued

cB/(mol/kg) 0.00489 0.00559 0.00611 0.00668 0.00713 0.00749 0.00831 0.01021 /(g/cm3) 1.00175 1.00274 1.00353 1.00428 1.00499 1.00541 1.00653 1.00905

cB/(mol/kg) 0.01140 0.01245 0.01376 0.01450 0.01667 0.01701 0.01939 0.02126 /(g/cm3) 1.01058 1.01183 1.01339 1.01441 1.01687 1.01732 1.02010 1.02212

cB/(mol/kg) 0.02140 0.02342 0.02350 /(g/cm3) 1.02226 1.02443 1.02451 Polymer (B): poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) 2006DE1 Characterization: Mn/g.mol1 = 14600, EO132PO50EO132, 15.9 mol% propylene oxide, F108, BASF AG, Germany Solvent (A): water H2O 7732-18-5

T/K = 298.15

cB/(mol/kg) 0.00000 0.00050 0.00067 0.00113 0.00197 0.00264 0.00335 0.00371 /(g/cm3) 0.99705 0.99816 0.99853 0.99955 1.00136 1.00276 1.00425 1.00498

cB/(mol/kg) 0.00482 0.00545 0.00606 0.00672 0.00769 0.00828 0.00835 0.00941 /(g/cm3) 1.00723 1.00849 1.00965 1.01091 1.01265 1.01370 1.01379 1.01571

cB/(mol/kg) 0.00982 0.01058 0.01127 0.01274 0.01482 0.01636 0.01670 0.01882 /(g/cm3) 1.01630 1.01761 1.01868 1.02105 1.02432 1.02667 1.02721 1.03023

T/K = 308.15

cB/(mol/kg) 0.00067 0.00197 0.00264 0.00335 0.00371 0.00482 0.00606 0.00672 /(g/cm3) 0.99543 0.99803 0.99930 1.00064 1.00133 1.00333 1.00555 1.00675

cB/(mol/kg) 0.00769 0.00828 0.00835 0.00982 0.01090 0.01127 0.01274 0.01482 /(g/cm3) 1.00845 1.00947 1.00958 1.01210 1.01388 1.01446 1.01683 1.02012 Polymer (B): poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) 2006DE1 Characterization: Mn/g.mol1 = 8350, EO76PO29EO76, 16.0 mol% propylene oxide, F68, BASF AG, Germany Solvent (A): water H2O 7732-18-5

T/K = 298.15

cB/(mol/kg) 0.00000 0.00301 0.00524 0.00712 0.00813 0.00994 0.01197 0.01443 /(g/cm3) 0.99705 1.00074 1.00339 1.00559 1.00671 1.00881 1.01096 1.01354

cB/(mol/kg) 0.01647 0.01687 0.01900 0.02007 0.02668 0.03065 0.03905 0.04439 /(g/cm3) 1.01565 1.01607 1.01821 1.01927 1.02547 1.02895 1.03571 1.03944

cB/(mol/kg) 0.04950 0.05235 0.05735 0.06981 0.071515 /(g/cm3) 1.04272 1.04444 1.04732 1.05356 1.05438

continued

________________________________________________________________________

continued

T/K = 308.15

cB/(mol/kg) 0.00000 0.00301 0.00524 0.00712 0.00813 0.00994 0.01197 0.01443 /(g/cm3) 0.99404 0.99755 1.00007 1.00215 1.00322 1.00519 1.00725 1.00967

cB/(mol/kg) 0.01647 0.01687 0.01900 0.02007 0.02129 0.02523 0.02668 0.03065 /(g/cm3) 1.01162 1.01204 1.01403 1.01509 1.01603 1.01930 1.02046 1.02352

cB/(mol/kg) 0.03572 0.03905 0.04439 0.04950 0.05089 0.05235 /(g/cm3) 1.02728 1.02939 1.03289 1.03607 1.03708 1.03772 Polymer (B): poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) 2006DE1 Characterization: Mn/g.mol1 = 1900, EO11PO16EO11, 42.1 mol% propylene oxide, L35, BASF AG, Germany Solvent (A): water H2O 7732-18-5

T/K = 298.15

cB/(mol/kg) 0.01529 0.04002 0.06275 0.07064 0.07566 0.1076 0.1272 0.1417 /(g/cm3) 1.00068 1.00619 1.01098 1.01252 1.01350 1.01942 1.02278 1.02518

cB/(mol/kg) 0.1840 0.2167 0.2503 0.2987 0.3641 0.4400 0.4749 0.5812 /(g/cm3) 1.03143 1.03573 1.03969 1.04440 1.04944 1.05357 1.05507 1.05866

cB/(mol/kg) 0.6848 0.7383 0.7981 0.9084 0.9586 1.3439 1.4572 /(g/cm3) 1.06117 1.06241 1.06316 1.06455 1.06478 1.06722 1.06707

T/K = 305.15

cB/(mol/kg) 0.00000 0.00541 0.00717 0.0153 0.03872 0.06275 0.07409 0.1082 /(g/cm3) 0.99503 0.99629 0.99668 0.99852 1.00357 1.00833 1.01048 1.01651

cB/(mol/kg) 0.1417 0.1943 0.2167 0.2503 0.3641 0.4749 0.5812 0.6167 /(g/cm3) 1.02167 1.02875 1.03134 1.03475 1.04343 0.04878 1.05238 1.05328

cB/(mol/kg) 0.7383 0.9084 1.3439 /(g/cm3) 1.05666 1.05864 1.06144

T/K = 308.15

cB/(mol/kg) 0.00000 0.00517 0.01533 0.04002 0.07064 0.07566 0.1076 0.1272 /(g/cm3) 0.99404 0.99522 0.99748 1.00270 1.00863 1.00954 1.01507 1.01810

cB/(mol/kg) 0.1840 0.2242 0.2355 0.2503 0.2987 0.3683 0.4400 0.4731 /(g/cm3) 1.02589 1.03039 1.03152 1.03349 1.03691 1.04161 1.04500 1.04640

cB/(mol/kg) 0.5801 0.6848 0.7981 0.9586 1.4572 /(g/cm3) 1.04995 1.05256 1.05426 1.05644 1.05900

________________________________________________________________________

pentane, pentane-d12, 25.5 wt% ethane in pentane-d12, 2.4 wt% deuterated poly(ethylene-co-butene) (PEB) in ethane, 5.3 wt% hydrogenated PEB in pentane, 5.1 wt % hydrogenated PEB in pentane-d12, and 4.9 wt % hydrogenated PEB in pentane-d12 + 23.1 wt % ethane, J. Chem. Eng. Data, 45, 810, 2000.