ABSTRACT

New devices built from hybrid materials composed of organic and

inorganic components are being researched as replacements to

conventional inorganic semiconductors [1]. These devices exploit

the transport properties of hybrid materials that emerge due to

the juxtaposition of organic molecules with discrete states and

inorganic semiconductors with continuous band structures. An

exciting prospect for hybrid materials is their use in thermoelectric

energy conversion creating an electric current by applying a

temperature gradient in a material, thus converting heat directly

into electricity. In this chapter, wewill discuss the details of this phe-

nomenon in molecular junctions and provide models to elucidate its

behavior.