HIGH-PRESSURE FLUID PHASE EQUILIBRIUM (HPPE) DATA OF POLYMER SOLUTIONS

ABSTRACT

T/K 293.45 299.25 303.85 308.75 313.95 318.55 23.55 328.25 333.65 P/bar 98.3 120.0 136.9 157.4 172.2 187.9 203.3 219.1 234.1 /(g/cm3) 0.8520 0.8378 0.8273 0.8203 0.8056 0.7967 0.7860 0.7783 0.7669

T/K 337.65 P/bar 248.4 /(g/cm3) 0.7627 Polymer (B): poly(acetoacetoxyethyl methacrylate-b-1,1,2,2-tetrahydroperfluorodecyl acrylate) 2011RIB Characterization: Mn/g.mol1 = 86500, 26.2 mol% acetoacetoxyethyl methacrylate, synthesized in the laboratory Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.040 was kept constant

T/K 293.65 298.85 303.85 309.45 314.85 318.75 323.75 328.85 333.95 P/bar 103.8 132.0 148.0 181.8 207.0 227.3 246.7 263.4 277.0 /(g/cm3) 0.8573 0.8545 0.8405 0.8425 0.8374 0.8359 0.8286 0.8192 0.8079 Polymer (B): poly(acetoacetoxyethyl methacrylate-co-1,1,2,2-tetrahydroperfluorodecyl acrylate) 2011RIB Characterization: Mn/g.mol1 = 63200, 10.8 mol% acetoacetoxyethyl methacrylate, gradient copolymer, synthesized in the laboratory Solvent (A): carbon dioxide CO2 124-38-9

continued

_______________________________________________________________________________

continued

Type of data: cloud points

wB 0.040 was kept constant

T/K 292.55 298.45 303.25 308.05 312.75 317.55 322.65 327.15 331.95 P/bar 71.4 92.9 111.5 127.5 143.8 160.4 176.6 188.8 203.3 /(g/cm3) 0.8177 0.8025 0.7940 0.7822 0.7731 0.7650 0.7552 0.7444 0.7362

T/K 336.85 P/bar 216.7 /(g/cm3) 0.7267 Polymer (B): poly(acetoacetoxyethyl methacrylate-co-1,1,2,2-tetrahydroperfluorodecyl acrylate) 2011RIB Characterization: Mn/g.mol1 = 89200, 26.8 mol% acetoacetoxyethyl methacrylate, gradient copolymer, synthesized in the laboratory Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.040 was kept constant

T/K 293.65 298.05 303.35 307.95 312.95 317.75 322.45 327.25 332.35 P/bar 105.5 123.6 143.6 164.6 179.5 197.2 213.5 230.3 246.0 /(g/cm3) 0.8593 0.8504 0.8387 0.8335 0.8201 0.8119 0.8035 0.7959 0.7864

T/K 337.55 P/bar 262.7 /(g/cm3) 0.7782 Polymer (B): poly[4,4’-bis(trifluorovinyloxy)biphenyl] 2005SHE Characterization: Mn/g.mol1 = 37500, Mw/g.mol1 = 78800, Tg/K = 417, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.030 was kept constant

T/K 295.35 311.85 314.55 317.15 326.65 343.15 357.65 382.55 404.15 P/bar 5.5 9.0 9.7 15.2 58.8 119.3 173.7 252.4 311.0 /(g/cm3) 0.673 0.654 0.656 0.658 0.655 0.641 0.638 0.625 0.613 VLE VLE VLE LLE LLE LLE LLE LLE LLE

T/K 315.85 326.75 360.45 384.15 401.95 P/bar 9.7 12.8 25.9 39.7 53.8 /(g/cm3) 0.546 0.556 0.505 0.489 0.355 VLLE VLLE VLLE VLLE VLLE

_______________________________________________________________________________ Polymer (B): poly{1,1-bis[4-(trifluorovinyloxy)phenyl]- hexafluoroisopropylidene} 2005SHE Characterization: Mn/g.mol1 = 31300, Mw/g.mol1 = 62600, Tg/K = 386, Tm/K = 392, synthesized in the laboratory Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.028 was kept constant

T/K 307.95 320.85 327.95 336.05 344.55 364.55 384.05 P/bar 870.0 839.7 828.3 824.1 826.9 840.0 859.3 /(g/cm3) 1.110 1.088 1.065 1.055 1.032 0.998 0.967 Polymer (B): poly{1,1-bis[4-(trifluorovinyloxy)phenyl]- hexafluoroisopropylidene} 2005SHE Characterization: Mn/g.mol1 = 31300, Mw/g.mol1 = 62600, Tg/K = 386, Tm/K = 392, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.051 was kept constant

T/K 327.25 340.15 356.55 363.65 366.25 369.05 372.95 375.25 385.85 P/bar 13.6 18.1 25.2 28.6 30.0 35.5 49.9 53.1 83.4 /(g/cm3) 0.649 0.629 0.591 0.574 0.568 0.571 0.568 0.568 0.560 VLE VLE VLE VLE LLE LLE LLE LLE LLE

T/K 299.65 406.95 369.85 376.85 383.85 393.35 401.75 P/bar 113.6 129.3 32.8 36.2 41.7 48.6 55.2 /(g/cm3) 0.555 0.553 0.519 0.503 0.501 0.428 0.354 LLE LLE VLLE VLLE VLLE VLLE VLLE Polymer (B): poly{1,1-bis[4-(trifluorovinyloxy)phenyl]- hexafluoroisopropylidene} 2005SHE Characterization: Mn/g.mol1 = 31300, Mw/g.mol1 = 62600, Tg/K = 386, Tm/K = 392, synthesized in the laboratory Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.036 was kept constant

T/K 377.75 380.35 386.25 399.55 409.25 P/bar 1291.8 1220.3 1096.3 849.2 759.9 /(g/cm3) 0.624 0.617 0.606 0.577 0.562

_______________________________________________________________________________ Polymer (B): polybutadiene 2010MIL Characterization: Mn/g.mol1 = 15800, Mw/g.mol1 = 16600, 15% 1,2-vinyl content, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.019 0.019 0.019 0.019 0.019 0.019 0.019 0.019 0.019 T/K 308.15 323.15 333.15 342.15 353.15 361.15 371.15 380.15 394.15 P/bar 34 62 87 106 128 147 167 186 202

wB 0.019 0.019 0.028 0.028 0.028 0.028 0.028 0.028 0.028 T/K 401.15 411.15 322.15 332.15 343.15 353.15 363.15 371.15 381.15 P/bar 220 237 92 111 134 154 171 190 208

wB 0.028 0.028 0.028 0.028 0.046 0.046 0.046 0.046 0.046 T/K 390.15 401.15 411.15 419.15 313.15 323.15 334.15 343.15 353.15 P/bar 226 245 263 276 79 102 122 135 163

wB 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.046 T/K 363.15 370.15 380.15 394.15 401.15 321.15 333.15 341.15 351.15 P/bar 184 196 208 223 232 99 122 138 156

wB 0.046 0.046 0.046 0.046 0.046 0.046 0.046 T/K 361.15 371.15 383.15 391.15 401.15 410.15 420.15 P/bar 175 194 213 228 245 260 277 Polymer (B): polybutadiene 2012MIL Characterization: Mn/g.mol1 = 15800, Mw/g.mol1 = 16600, 15% 1,2-vinyl content, synthesized in the laboratory Solvent (A): n-pentane C5H12 109-66-0

Type of data: cloud points

wB 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011 T/K 396.15 400.15 406.15 409.15 414.15 418.15 422.15 427.15 431.15 P/bar 19 28 36 43 48 53 62 69 72

wB 0.011 0.011 0.011 0.011 0.033 0.033 0.033 0.033 0.033 T/K 438.15 441.15 446.15 451.15 384.15 389.15 395.15 398.15 401.15 P/bar 77 83 89 96 26 35 44 50 55

wB 0.033 0.033 0.033 0.033 0.033 0.033 0.033 0.033 0.033 T/K 405.15 411.15 417.15 420.15 425.15 431.15 436.15 443.15 447.15 P/bar 63 72 82 87 93 101 109 118 122

wB 0.033 0.033 0.036 0.036 0.036 0.036 0.036 0.036 0.036 T/K 451.15 457.15 391.15 399.15 411.15 419.15 428.15 438.15 447.15 P/bar 126 134 25 39 55 68 79 94 108

wB 0.036 T/K 456.15 P/bar 117

_______________________________________________________________________________ Polymer (B): 1,4-cis-polybutadiene 2007TAN Characterization: Mn/g.mol1 = 1750, Mw/Mn = 1.1, Polymer Source, Inc., Quebec, Canada Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant T/K 353.0 373.0 393.2 413.1 433.0 P/bar 34.9 67.1 94.9 116.8 135.7 Polymer (B): 1,4-cis-polybutadiene 2007TAN Characterization: Mn/g.mol1 = 5300, Mw/Mn = 1.04, Polymer Source, Inc., Quebec, Canada Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant T/K 293.1 303.2 313.2 333.1 353.2 373.2 393.0 413.1 433.2 P/bar 98.5 112.7 126.3 153.6 180.4 205.7 229.4 250.0 267.2 Polymer (B): 1,4-cis-polybutadiene 2007TAN Characterization: Mn/g.mol1 = 8800, Mw/Mn = 1.04, Polymer Source, Inc., Quebec, Canada Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant T/K 293.1 303.2 313.2 333.3 353.2 373.2 393.1 413.1 433.2 P/bar 267.9 265.2 266.3 275.7 289.3 304.3 320.5 335.3 348.8 Polymer (B): polybutadiene 2010MIL Characterization: Mn/g.mol1 = 14200, Mw/g.mol1 = 14800, 22% 1,2-vinyl content, synthesized in the laboratory Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.022 0.022 0.022 0.022 0.022 0.022 0.022 0.034 0.034 T/K 332.15 343.15 356.15 368.15 386.15 394.15 401.15 316.15 326.15 P/bar 518 515 514 516 520 520 517 558 542

wB 0.034 0.034 0.034 0.034 0.034 0.034 0.034 0.034 0.043 T/K 337.15 347.15 357.15 370.15 381.15 392.15 403.15 415.15 329.15 P/bar 540 540 538 537 534 533 537 537 536

wB 0.043 0.043 0.043 0.043 0.043 0.043 0.043 T/K 341.15 353.15 356.15 371.15 374.15 390.15 400.15 P/bar 522 515 507 500 502 500 500

_______________________________________________________________________________ Polymer (B): 1,4-cis-polybutadiene 2007TAN Characterization: Mn/g.mol1 = 18000, Mw/Mn = 1.04, Polymer Source, Inc., Quebec, Canada Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant

T/K 293.1 303.2 313.2 333.2 353.1 373.2 393.3 413.2 433.2 P/bar 495.1 470.2 453.1 435.3 427.9 428.8 434.1 440.9 447.6 Polymer (B): 1,4-cis-polybutadiene 2007TAN Characterization: Mn/g.mol1 = 58000, Mw/Mn = 1.05, Polymer Source, Inc., Quebec, Canada Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant

T/K 293.4 313.3 353.2 393.2 433.0 452.9 P/bar 872.1 753.6 641.3 598.1 585.3 579.7 Polymer (B): polybutadiene 2009WI2 Characterization: Mn/g.mol1 = 38200, Mw/Mn = 1.05, synthesized in the laboratory Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant

T/K 293.15 293.15 313.15 313.25 353.05 352.85 393.25 393.25 433.25 P/bar 675 674 600 601 537 537 522 522 522

T/K 433.15 453.25 453.15 P/bar 522 555 551 Polymer (B): polybutadiene (deuterated) 2009WI1 Characterization: Mn/g.mol1 = 38300, Mw/g.mol1 = 39800, synthesized in the laboratory Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant

T/K 293.25 313.25 323.05 393.15 433.15 453.25 P/bar 496 460 440 448 463 485

_______________________________________________________________________________ Polymer (B): polybutadiene (hydrogenated) 2009WI2 Characterization: Mn/g.mol1 = 39600, Mw/Mn = 1.05, synthesized in the laboratory Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.005 was kept constant

T/K 353.25 353.15 373.15 373.15 393.15 393.15 413.15 413.15 453.15 P/bar 462 462 460 460 461 462 466 467 457

T/K 453.15 P/bar 455 Polymer (B): polybutadiene 2009WI2 Characterization: Mn/g.mol1 = 38200, Mw/Mn = 1.05, synthesized in the laboratory Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.005 was kept constant

T/K 293.35 293.35 314.85 314.65 333.35 333.45 352.85 352.95 373.05 P/bar 343 343 365 365 385 385 405 406 428

T/K 372.95 392.55 393.25 413.35 413.55 433.25 433.35 453.15 453.25 P/bar 428 447 448 466 466 480 480 493 493 Polymer (B): polybutadiene (hydrogenated) 2009WI2 Characterization: Mn/g.mol1 = 39600, Mw/Mn = 1.05, synthesized in the laboratory Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.005 was kept constant

T/K 372.85 373.15 393.25 393.25 413.15 413.15 433.15 433.15 453.15 P/bar 489 489 488 488 492 492 497 497 502

T/K 453.15 P/bar 503 Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points continued

_______________________________________________________________________________

continued

wB 0.050 was kept constant

T/K 333.6 353.5 373.2 393.6 413.3 433.3 453.2 P/MPa 23.62 15.35 13.97 14.31 15.69 17.41 19.14 Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.049 was kept constant

T/K 373.3 393.4 413.8 433.2 453.3 P/MPa 4.14 7.41 10.35 12.93 15.69 Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.050 was kept constant

T/K 363.9 368.7 373.3 393.4 414.3 433.9 454.2 P/MPa 224.31 183.10 163.10 134.83 124.31 117.41 115.17 Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.050 was kept constant

T/K 353.8 373.5 393.7 414.5 433.7 453.7 P/MPa 2.93 8.28 11.90 16.38 18.79 20.86 Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.051 was kept constant

T/K 333.4 353.8 373.7 393.9 413.8 433.8 454.2 P/MPa 56.03 41.88 36.38 34.31 33.97 34.31 34.66

_______________________________________________________________________________ Polymer (B): poly(2-butoxyethyl acrylate) 2014JAN Characterization: Mw/g.mol1 = 80000, Mw/Mn = 1.6 Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.048 was kept constant

T/K 333.6 353.4 373.4 393.5 413.6 433.3 453.6 P/MPa 16.38 19.48 22.93 25.69 28.10 30.17 31.90 Polymer (B): poly(tert-butyl acrylate) 2006BY1 Characterization: Mn/g.mol1 = 72000, Mw/g.mol1 = 250000, Polysciences, Inc., Warrington, PA Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.048 was kept constant

T/K 395.55 401.85 411.35 427.45 442.55 457.65 P/bar 2063.8 1711.4 1427.2 1294.5 1240.7 1215.2 Polymer (B): poly(butyl methacrylate) 2004BEC, 2004LAT Characterization: Mn/g.mol1 = 38100, Mw/g.mol1 = 65500, synthesized in the laboratory Solvent (A): ethene C2H4 74-85-1

Type of data: cloud points

wB 0.05 was kept constant

T/K 373.15 393.15 413.15 433.15 453.15 473.15 488.15 508.15 P/bar 1380 1320 1215 1161 1147 1111 1077 1031 Polymer (B): poly(tert-butyl methacrylate) 2006BY1 Characterization: Mn/g.mol1 = 69800, Mw/g.mol1 = 180000, Polysciences, Inc., Warrington, PA Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.046 was kept constant

T/K 434.95 437.75 444.75 456.15 463.95 P/bar 2575.5 2377.6 2186.6 1933.8 1913.1

_______________________________________________________________________________ Polymer (B): poly(ε-caprolactone) 2006BY2 Characterization: Mw/g.mol1 = 170000, Honam Petrochemical Co., South Korea Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.051 was kept constant

T/K 425.25 430.85 435.15 444.95 455.65 464.15 473.35 484.85 P/bar 1610.3 1734.5 1825.9 1979.3 2298.3 2650.0 2746.6 2836.2 Polymer (B): poly(ε-caprolactone) 2006BY2 Characterization: Mw/g.mol1 = 170000, Honam Petrochemical Co., South Korea Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.040 was kept constant

T/K 458.25 463.05 467.75 476.15 485.65 494.95 502.15 P/bar 2832.8 2781.0 2750.0 2677.6 2622.4 2560.4 2522.4 Polymer (B): poly(ε-caprolactone) 2006PAR Characterization: Mw/g.mol1 = 14000, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): chlorodifluoromethane CHClF2 75-45-6

Type of data: cloud points

wB 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 T/K 322.4 333.6 343.3 354.6 363.2 373.3 383.1 393.8 402.8 P/MPa 1.9 5.9 9.1 12.8 15.4 18.4 21.3 24.4 26.7

wB 0.0299 0.0501 0.0501 0.0501 0.0501 0.0501 0.0501 0.0501 0.0501 T/K 410.3 323.8 336.1 342.9 353.2 365.2 373.3 383.5 394.1 P/MPa 28.8 2.5 6.4 9.0 12.4 16.2 18.6 21.6 24.6

wB 0.0501 0.0501 0.0695 0.0695 0.0695 0.0695 0.0695 0.0695 0.0695 T/K 403.1 411.7 322.4 332.3 344.1 352.3 364.4 373.1 383.7 P/MPa 27.0 29.3 1.5 5.0 8.9 11.6 15.3 17.9 20.9

wB 0.0695 0.0695 0.0695 T/K 393.5 403.2 412.5 P/MPa 23.2 25.9 28.1 Polymer (B): poly(ε-caprolactone) 2006BY2 Characterization: Mw/g.mol1 = 170000, Honam Petrochemical Co., South Korea Solvent (A): chlorodifluoromethane CHClF2 75-45-6

Type of data: cloud points

wB 0.047 was kept constant

continued

_______________________________________________________________________________

continued

T/K 312.75 320.55 333.85 344.25 351.05 360.85 371.05 382.75 393.65 P/bar 43.1 74.1 126.9 168.3 194.1 229.0 262.4 297.6 328.3

T/K 403.35 415.25 423.35 444.15 P/bar 359.7 393.5 422.1 454.8 Polymer (B): poly(ε-caprolactone) 2006PAR Characterization: Mw/g.mol1 = 14000, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 0.0299 T/K 313.7 324.0 333.2 343.7 353.0 363.5 373.9 383.6 394.3 P/MPa 14.0 16.8 18.9 21.6 23.9 26.2 28.3 30.5 32.7

wB 0.0299 0.0299 0.0499 0.0499 0.0499 0.0499 0.0499 0.0499 0.0499 T/K 402.9 411.9 314.0 325.3 334.7 345.0 354.4 363.7 374.2 P/MPa 34.0 35.5 13.3 16.3 18.7 21.2 23.4 25.6 27.8

wB 0.0499 0.0499 0.0499 0.0499 0.0696 0.0696 0.0696 0.0696 0.0696 T/K 383.3 393.6 404.7 413.6 312.5 322.7 332.6 343.2 353.4 P/MPa 29.7 31.7 33.7 35.2 13.1 15.8 18.3 20.8 23.1

wB 0.0696 0.0696 0.0696 0.0696 0.0696 0.0696 T/K 362.8 373.2 384.2 393.8 403.2 413.6 P/MPa 25.3 27.5 29.8 31.7 33.4 35.2 Polymer (B): poly(ε-caprolactone) 2006BY2 Characterization: Mw/g.mol1 = 170000, Honam Petrochemical Co., South Korea Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.050 was kept constant

T/K 328.95 350.15 368.25 389.55 411.05 427.05 444.95 459.85 471.55 P/bar 261.7 311.4 355.2 388.6 434.1 456.9 481.0 494.8 496.6 Polymer (B): poly(ε-caprolactone) 2006BY2 Characterization: Mw/g.mol1 = 170000, Honam Petrochemical Co., South Korea Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.053 was kept constant

T/K 419.25 424.05 427.45 435.95 446.25 456.15 465.45 474.25 P/bar 2767.2 2632.8 2556.9 2360.3 2163.8 2015.5 1887.9 1825.9

_______________________________________________________________________________ Polymer (B): poly(4-chlorostyrene) 2013YA2 Characterization: Mn/g.mol1 = 57000, Mw/g.mol1 = 87000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.046 was kept constant

T/K 446.7 452.2 459.1 467.5 483.5 P/MPa 243.62 227.76 211.55 193.97 168.10 Polymer (B): poly(4-chlorostyrene) 2013YA2 Characterization: Mn/g.mol1 = 57000, Mw/g.mol1 = 87000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.049 was kept constant

T/K 335.1 355.3 375.2 394.4 414.8 435.3 451.8 P/MPa 40.35 47.24 52.76 57.59 61.55 65.00 67.76 Polymer (B): poly(4-chlorostyrene) 2013YA2 Characterization: Mn/g.mol1 = 57000, Mw/g.mol1 = 87000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.046 was kept constant

T/K 477.1 481.5 488.1 494.2 P/MPa 239.14 230.69 220.00 209.83 Polymer (B): poly(cyclohexene oxide-co-carbon dioxide) 2005SCH Characterization: Mw/g.mol1 = 12000, Mw/Mn < 1.2, synthesized in the laboratory Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0051 was kept constant

T/K 455.06 459.66 465.20 475.95 479.33 479.93 P/MPa 335 309 292 257 254 252

_______________________________________________________________________________ Polymer (B): poly(decyl acrylate) 2006BY3 Characterization: Mw/g.mol1 = 130000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points

wB 0.051 was kept constant

T/K 354.55 375.55 394.05 414.05 435.25 454.75 P/bar 19.0 50.0 68.3 102.4 126.6 143.1 Polymer (B): poly(decyl acrylate) 2006BY3 Characterization: Mw/g.mol1 = 130000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.065 was kept constant

T/K 395.05 414.85 435.45 454.85 P/bar 53.5 87.9 119.0 139.7 Polymer (B): poly(decyl acrylate) 2006BY3 Characterization: Mw/g.mol1 = 130000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.051 was kept constant

T/K 451.45 459.95 468.95 469.05 479.65 P/bar 1936.2 1770.7 1500.3 1485.9 1449.3 Polymer (B): poly(decyl acrylate) 2006BY3 Characterization: Mw/g.mol1 = 130000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.044 was kept constant

T/K 374.65 392.45 414.85 432.85 454.95 P/bar 44.5 81.0 129.3 156.9 177.6

Type of data: cloud points

wB 0.046 was kept constant

T/K 332.05 353.75 375.25 392.55 414.65 435.35 453.55 P/bar 169.0 181.0 205.9 228.6 258.6 273.5 285.9 Polymer (B): poly(decyl acrylate) 2006BY3 Characterization: Mw/g.mol1 = 130000, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.056 was kept constant

T/K 334.05 356.15 372.75 393.15 415.35 431.75 453.65 P/bar 96.6 142.4 174.1 208.6 245.2 256.9 277.6 Polymer (B): poly[4-(decyloxymethyl)styrene] 2008SH3 Characterization: Mn/g.mol1 = 12100, Mw/g.mol1 = 33700, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.039 was kept constant

T/K 372.05 392.35 412.55 432.65 452.35 P/bar 50.0 101.7 150.0 181.0 191.0 Polymer (B): poly[4-(decylsulfonylmethyl)styrene] 2008SH3 Characterization: Mn/g.mol1 = 18400, Mw/g.mol1 = 49300, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.045 was kept constant

T/K 325.35 333.55 353.15 373.65 394.05 414.85 435.75 452.15 P/bar 110.3 125.9 162.1 198.3 236.2 270.7 301.7 315.5

_______________________________________________________________________________ Polymer (B): poly[4-(decylthiomethyl)styrene] 2008SH3 Characterization: Mn/g.mol1 = 10700, Mw/g.mol1 = 43700, synthesized in the laboratory Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.037 was kept constant

T/K 330.45 354.05 374.95 394.75 412.95 433.95 453.15 P/bar 17.2 63.8 115.5 170.7 196.6 234.5 258.6 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 38900, Mw/Mn = 2.84, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points

wB 0.067 was kept constant

T/K 413.5 432.6 452.9 P/MPa 3.10 4.83 6.90 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points and bubble points

wB 0.073 was kept constant

T/K 341.6 354.5 373.7 393.9 411.9 433.6 454.0 P/MPa 0.52 0.86 1.55 2.24 3.28 5.35 7.50 BP BP BP BP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points

wB 0.074 was kept constant

T/K 411.5 435.8 452.6 P/MPa 3.33 5.86 7.61

_______________________________________________________________________________ Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 38900, Mw/Mn = 2.84, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points and bubble points

wB 0.071 was kept constant

T/K 338.2 354.1 372.9 393.1 412.1 35.7 453.6 P/MPa 0.52 0.86 1.55 2.14 2.93 5.86 8.28 BP BP BP BP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points and bubble points

wB 0.075 was kept constant

T/K 341.4 354.7 374.6 391.4 413.9 433.1 454.9 P/MPa 0.52 0.86 1.48 2.07 3.28 5.52 7.79 BP BP BP BP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points and bubble points

wB 0.073 was kept constant

T/K 340.4 354.4 373.9 393.2 413.9 432.2 452.2 P/MPa 0.52 0.86 1.45 2.11 3.62 5.52 7.36 BP BP BP BP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 38900, Mw/Mn = 2.84, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.050 was kept constant

T/K 315.2 335.0 353.3 374.0 393.7 414.2 433.2 452.6 P/MPa 33.13 34.14 37.07 40.86 43.97 47.41 49.14 51.38

_______________________________________________________________________________ Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.049 was kept constant

T/K 333.7 353.3 374.1 393.6 413.3 432.4 453.8 P/MPa 39.14 40.86 44.48 47.59 50.52 52.41 54.83 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.055 was kept constant

T/K 334.5 354.2 373.0 391.9 413.9 434.7 454.3 P/MPa 40.52 42.24 45.00 47.76 50.86 53.28 55.52 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 38900, Mw/Mn = 2.84, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points and bubble points

wB 0.052 was kept constant

T/K 334.4 353.2 372.4 393.3 413.9 433.4 452.5 P/MPa 1.21 2.24 2.76 4.14 7.41 10.00 12.41 BP BP BP CP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points and bubble points

wB 0.056 was kept constant

T/K 334.1 354.9 372.8 394.2 413.2 432.9 453.0 P/MPa 1.21 2.07 3.10 4.66 7.76 10.52 12.59 BP BP BP CP CP CP CP

_______________________________________________________________________________ Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points and bubble points

wB 0.058 was kept constant

T/K 333.8 352.4 372.4 393.1 413.2 434.6 454.5 P/MPa 1.21 1.90 3.28 4.83 8.28 11.21 13.79 BP BP BP CP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 38900, Mw/Mn = 2.84, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propane C3H8 74-98-6

Type of data: cloud points and bubble points

wB 0.052 was kept constant

T/K 333.5 353.6 373.2 394.5 414.0 33.4 452.7 P/MPa 1.55 2.41 5.35 8.79 11.03 13.28 15.00 BP CP CP CP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propane C3H8 74-98-6

Type of data: cloud points and bubble points

wB 0.051 was kept constant

T/K 334.0 354.1 373.5 393.5 412.9 434.2 452.7 P/MPa 1.89 3.28 6.21 9.14 11.55 4.31 15.69 BP CP CP CP CP CP CP Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propane C3H8 74-98-6

Type of data: cloud points and bubble points

wB 0.049 was kept constant

T/K 333.5 355.2 373.2 393.2 413.0 434.1 452.7 P/MPa 1.90 3.84 6.72 9.54 12.07 14.61 16.03 BP CP CP CP CP CP CP

Type of data: cloud points

wB 0.064 was kept constant

T/K 355.7 375.5 394.7 14.6 432.1 P/MPa 3.97 7.24 9.66 12.41 14.48 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 90200, Mw/Mn = 1.96, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.078 was kept constant

T/K 354.0 372.8 395.0 412.1 435.2 P/MPa 4.14 7.39 10.66 12.76 15.69 Polymer (B): poly(dimethylsiloxane) 2013BYU Characterization: Mw/g.mol1 = 170300, Mw/Mn = 1.75, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.073 was kept constant

T/K 355.1 374.2 393.1 412.1 434.6 442.4 P/MPa 4.31 7.76 10.75 13.23 15.86 16.58 Polymer (B): poly(dimethylsiloxane) monomethacrylate 2005TAI Characterization: Mn/g.mol1 = 10000, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.012 was kept constant

T/K 319.15 328.15 338.15 347.15 P/MPa 19.5 22.1 24.6 26.8

_______________________________________________________________________________ Polymer (B): poly(dimethylsiloxane) monomethacrylate 2010LE1 Characterization: Mn/g.mol1 = 10000 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.002 was kept constant

T/K 298.15 308.15 318.15 328.15 338.15 P/bar 112 141 166 198 225 Polymer (B): poly(1,4-dioxan-2-one) 2012KIR Characterization: Mn/g.mol1 = 35700, Mw/g.mol1 = 89400, Tg/K = 259.2, Tm/K = 382.2, Johnson & Johnson Corporate Biomaterials Center, Somerville, NJ Solvent (A): 2-propanone C3H6O 67-64-1

Type of data: cloud points

wB 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 T/K 441.55 429.75 418.55 403.75 393.85 386.75 377.55 367.35 357.55 P/MPa 16.47 15.15 13.52 13.48 13.55 13.56 13.03 13.42 14.07

wB 0.010 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 T/K 350.55 440.75 422.35 412.75 401.25 390.15 380.15 372.05 365.15 P/MPa 14.24 22.18 21.22 21.17 21.49 22.25 24.66 27.42 29.98

wB 0.025 0.025 0.050 0.050 0.050 0.050 0.050 0.050 0.050 T/K 356.05 346.65 439.45 432.75 423.25 406.65 393.85 384.55 375.55 P/MPa 32.73 38.36 25.05 25.20 24.52 25.41 27.39 28.86 31.97

wB 0.050 0.050 0.050 0.075 0.075 0.075 0.075 0.075 0.075 T/K 368.25 360.25 353.05 440.65 430.25 418.35 405.75 396.05 386.35 P/MPa 34.59 36.89 41.68 25.36 25.09 25.03 25.63 26.83 29.17

wB 0.075 0.075 0.075 0.075 0.100 0.100 0.100 0.100 0.100 T/K 377.35 369.35 361.05 352.55 439.05 425.45 417.45 409.25 400.95 P/MPa 31.32 34.07 38.74 44.69 22.76 22.31 22.39 22.45 23.08

wB 0.100 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 T/K 394.05 387.45 376.55 368.45 361.65 352.85 443.15 429.55 420.85 P/MPa 23.74 24.60 26.84 29.84 32.44 36.07 19.69 18.84 18.94

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 T/K 411.65 401.55 395.15 388.15 374.85 364.85 357.45 350.35 P/MPa 18.36 18.32 18.82 19.59 22.70 24.88 28.03 32.86

_______________________________________________________________________________ Polymer (B): poly(dodecyl acrylate) 2010LE2 Characterization: Mw/g.mol1 = 44000, Mw/Mn = 1.6, Tg/K = 243.2, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points

wB 0.050 was kept constant

T/K 392.1 413.5 433.1 454.6 P/MPa 4.31 7.76 10.66 13.28 Polymer (B): poly(dodecyl acrylate) 2010LE2 Characterization: Mw/g.mol1 = 44000, Mw/Mn = 1.6, Tg/K = 243.2, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.054 was kept constant

T/K 394.6 413.5 434.0 453.7 P/MPa 3.97 6.72 9.83 12.72 Polymer (B): poly(dodecyl acrylate) 2010LE2 Characterization: Mw/g.mol1 = 44000, Mw/Mn = 1.6, Tg/K = 243.2, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.052 was kept constant

T/K 456.9 459.0 460.5 463.4 P/MPa 205.28 169.55 157.07 150.14 Polymer (B): poly(dodecyl acrylate) 2010LE2 Characterization: Mw/g.mol1 = 44000, Mw/Mn = 1.6, Tg/K = 243.2, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.047 was kept constant

T/K 374.3 392.3 413.2 432.5 454.5 P/MPa 3.62 7.76 12.03 15.35 18.10

Type of data: cloud points

wB 0.056 was kept constant

T/K 333.9 354.2 375.2 395.0 413.8 435.1 455.6 P/MPa 8.79 12.93 16.72 19.66 22.24 24.66 26.38 Polymer (B): poly(dodecyl acrylate) 2010LE2 Characterization: Mw/g.mol1 = 44000, Mw/Mn = 1.6, Tg/K = 243.2, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.051 was kept constant

T/K 333.4 354.1 375.4 395.4 413.3 435.2 454.7 P/MPa 7.76 12.24 16.38 20.17 22.59 25.35 27.76 Polymer (B): poly(dodecyl methacrylate) 2009LIU Characterization: Mw/g.mol1 = 250000, Tg/K = 208, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): n-butane C4H10 106-97-8

Type of data: cloud points

wB 0.056 was kept constant

T/K 374.9 393.4 412.3 433.1 454.1 P/MPa 4.66 7.76 10.86 13.62 16.03 Polymer (B): poly(dodecyl methacrylate) 2009LIU Characterization: Mw/g.mol1 = 250000, Tg/K = 208, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 1-butene C4H8 106-98-9

Type of data: cloud points

wB 0.049 was kept constant

T/K 394.0 413.1 435.0 453.7 P/MPa 5.45 8.79 12.59 14.66

_______________________________________________________________________________ Polymer (B): poly(dodecyl methacrylate) 2009LIU Characterization: Mw/g.mol1 = 250000, Tg/K = 208, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): dimethyl ether C2H6O 115-10-6

Type of data: cloud points

wB 0.042 was kept constant

T/K 374.2 394.2 414.0 434.8 P/MPa 7.07 11.55 15.35 18.79 Polymer (B): poly(dodecyl methacrylate) 2009LIU Characterization: Mw/g.mol1 = 250000, Tg/K = 208, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.052 was kept constant

T/K 334.4 355.6 374.4 394.9 414.7 435.5 453.5 P/MPa 14.66 18.45 21.21 24.31 27.07 29.14 30.52 Polymer (B): poly(dodecyl methacrylate) 2009LIU Characterization: Mw/g.mol1 = 250000, Tg/K = 208, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): propene C3H6 115-07-1

Type of data: cloud points

wB 0.052 was kept constant

T/K 332.9 354.4 375.9 394.2 416.0 434.0 455.1 P/MPa 12.24 17.41 21.21 23.97 27.07 29.48 31.55 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 1200, Boltorn-type, OH-endgroups are esterified to -O(CO)CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 T/K 422.85 422.84 422.86 402.43 402.42 402.44 381.94 381.93 381.94 P/MPa 183.59 183.01 183.34 182.66 182.28 182.44 180.86 181.12 181.25

wB 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 0.1052 T/K 360.99 360.99 360.98 340.45 340.45 340.44 320.06 320.07 320.07 P/MPa 176.15 175.87 175.54 168.90 169.14 169.27 160.88 161.12 160.66

continued

_______________________________________________________________________________

continued

wB 0.1052 0.1052 0.1052 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 303.65 303.65 303.64 423.05 423.04 423.03 412.81 412.81 412.83 P/MPa 152.32 152.55 151.91 181.55 181.14 180.90 180.67 180.72 180.57

wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 402.61 402.62 402.62 392.38 392.38 392.37 382.09 382.10 382.12 P/MPa 180.94 180.84 181.59 180.49 179.82 180.22 179.08 179.22 179.59

wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 371.86 371.86 371.87 361.08 361.09 361.12 350.88 350.85 350.85 P/MPa 176.25 176.10 175.86 173.21 173.88 174.22 171.19 170.64 170.32

wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 340.49 340.51 340.52 330.25 330.26 330.27 320.86 320.87 320.87 P/MPa 167.48 167.10 166.87 161.89 162.62 162.57 158.07 158.40 158.75

wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 310.45 310.45 310.50 302.32 302.31 302.31 P/MPa 152.40 152.66 152.94 147.99 148.57 148.86 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 2100, Boltorn-type, OH-endgroups are esterified to -O(CO)CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0989 was kept constant

T/K 422.84 422.85 422.86 412.65 412.66 412.67 402.56 402.57 402.57 P/MPa 104.68 104.37 104.14 103.33 103.55 103.15 100.87 101.06 101.27

T/K 392.08 392.10 392.11 381.79 381.79 381.80 371.22 371.23 371.23 P/MPa 98.75 98.44 98.61 94.67 94.87 95.14 92.49 92.66 92.88

T/K 361.13 361.13 361.14 350.67 350.69 350.70 340.55 340.54 340.54 P/MPa 89.03 88.77 88.59 85.44 85.24 85.11 80.37 80.12 79.86

T/K 330.15 330.16 330.16 320.94 320.93 320.94 310.58 310.57 310.56 P/MPa 76.79 76.44 76.17 72.58 72.18 72.34 67.47 67.67 67.82 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 4250, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)5CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 T/K 422.81 422.80 422.81 402.33 402.32 402.32 381.81 381.81 381.81 P/MPa 83.84 83.62 83.76 81.36 80.41 80.73 78.72 79.02 79.14

continued

_______________________________________________________________________________

continued

wB 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 0.1005 T/K 361.66 361.66 361.67 340.34 340.35 340.35 319.79 319.78 319.79 P/MPa 78.16 78.06 78.28 76.65 76.77 76.88 78.80 78.44 78.62

wB 0.1005 0.1005 0.1005 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 T/K 303.63 303.60 303.60 22.92 422.91 422.91 402.47 402.48 402.48 P/MPa 92.09 91.83 92.11 65.09 65.24 64.90 62.60 62.24 62.18

wB 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 T/K 381.66 381.67 381.68 361.09 361.09 361.08 340.53 340.53 340.54 P/MPa 59.54 59.33 59.20 56.78 56.52 56.32 53.72 53.98 54.05

wB 0.3515 0.3515 0.3515 0.3515 0.3515 0.3515 T/K 319.98 319.99 319.99 304.65 304.64 304.63 P/MPa 49.19 48.97 48.72 47.40 47.54 47.66 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 2150, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)10CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 T/K 422.63 422.64 422.64 402.24 402.23 402.24 381.77 381.76 381.76 P/MPa 87.56 87.28 87.32 89.38 89.22 89.18 95.22 95.15 94.74

wB 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 T/K 422.84 422.84 422.83 402.27 402.28 402.28 381.75 381.74 381.74 P/MPa 87.62 87.18 87.24 91.43 91.28 91.08 101.93 102.06 101.86

wB 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 0.1047 T/K 371.08 371.09 371.08 365.99 365.98 365.98 363.89 363.90 363.91 P/MPa 117.10 116.83 117.16 132.00 131.87 131.67 145.23 144.78 144.94

wB 0.1047 0.1047 0.1047 0.1047 0.3038 0.3038 0.3038 0.3038 0.3038 T/K 362.87 362.88 362.89 362.63 422.57 422.60 422.64 402.23 402.24 P/MPa 160.38 159.74 160.77 185.21 75.18 75.55 75.33 77.62 77.48

wB 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 T/K 402.24 381.73 381.75 381.77 360.94 360.94 360.93 350.60 350.63 P/MPa 77.30 80.23 80.36 80.43 90.83 91.04 91.23 110.52 109.52

wB 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 0.3038 T/K 350.65 348.49 348.53 348.55 346.47 346.47 346.48 345.86 345.86 P/MPa 109.93 116.43 115.57 116.23 126.28 127.18 127.34 158.58 158.95

wB 0.3038 0.3038 T/K 345.86 346.50 P/MPa 159.72 185.66

_______________________________________________________________________________ Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 5600, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)10CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 T/K 422.98 422.97 422.97 412.59 412.59 412.58 402.39 402.40 402.40 P/MPa 94.32 94.55 94.19 96.90 97.13 96.56 98.41 98.67 98.83

wB 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 T/K 392.17 392.17 392.16 381.94 381.95 381.95 371.25 371.26 371.27 P/MPa 104.30 104.84 105.12 110.75 110.47 110.22 136.54 136.82 137.03

wB 0.0069 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 T/K 369.35 423.34 423.34 423.34 413.10 413.11 413.12 402.87 402.88 P/MPa 182.56 98.44 98.67 98.87 100.84 101.06 101.34 103.53 103.90

wB 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 0.0116 T/K 402.89 392.63 392.63 392.64 382.16 382.17 382.18 375.76 375.76 P/MPa 104.35 113.86 114.28 114.44 128.74 129.21 129.45 162.49 163.29

wB 0.0116 0.0116 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 T/K 375.77 374.97 423.10 423.11 423.12 413.68 413.68 413.69 402.73 P/MPa 163.84 187.56 102.95 102.57 102.34 106.18 105.88 105.68 112.77

wB 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 T/K 402.72 402.72 392.35 392.35 392.36 382.23 382.24 379.14 379.14 P/MPa 112.24 112.59 122.36 121.89 122.12 144.85 145.38 183.80 184.37

wB 0.0229 0.0229 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 T/K 379.14 378.45 423.32 423.31 423.32 413.23 413.22 413.22 402.86 P/MPa 184.71 194.56 101.54 101.34 101.19 105.67 105.42 105.31 111.83

wB 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 0.0567 T/K 402.87 402.87 392.46 392.45 392.45 382.35 382.34 382.35 379.25 P/MPa 111.57 111.47 121.14 120.84 120.53 151.49 151.22 150.80 189.77

wB 0.0567 0.0567 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 T/K 379.25 379.26 423.61 423.60 423.59 413.35 413.36 413.36 405.57 P/MPa 190.64 191.29 96.36 95.88 95.94 99.07 98.64 99.11 102.28

wB 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 T/K 405.57 405.58 398.76 398.76 398.75 392.75 392.76 392.76 381.59 P/MPa 101.87 101.71 106.58 105.97 106.04 110.69 110.53 110.85 126.08

wB 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.0952 0.2212 T/K 381.58 381.58 374.03 374.03 374.04 371.92 371.92 371.92 422.96 P/MPa 125.77 125.81 160.31 159.44 159.66 196.68 197.15 197.60 84.85

continued

_______________________________________________________________________________

continued

wB 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 T/K 422.96 422.97 412.70 412.71 412.72 402.39 402.38 402.38 392.08 P/MPa 84.47 84.66 86.53 85.97 89.19 88.58 88.35 88.19 91.89

wB 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 0.2212 T/K 392.08 392.09 381.93 381.93 382.93 371.24 371.25 371.26 360.93 P/MPa 91.58 91.34 98.50 97.57 97.33 107.09 106.68 106.88 134.31

wB 0.2212 0.2212 0.2212 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 T/K 360.94 360.95 359.20 423.16 423.19 423.21 413.11 413.11 413.12 P/MPa 134.89 135.28 195.59 78.35 78.01 77.94 78.04 78.11 78.09

wB 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 T/K 402.75 402.76 402.76 392.54 392.55 392.55 382.23 382.23 382.24 P/MPa 79.53 79.49 79.42 80.15 80.28 80.20 83.37 83.53 83.61

wB 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 0.3050 T/K 372.33 372.33 372.34 361.26 361.26 361.25 350.97 350.96 350.96 P/MPa 87.67 87.75 87.83 97.88 97.95 98.02 136.79 136.90 137.03

wB 0.3050 0.3050 0.3050 0.3050 0.6036 0.6036 0.6036 0.6036 0.6036 T/K 349.88 349.88 349.87 349.87 423.17 423.19 423.19 402.73 402.72 P/MPa 193.78 194.05 193.59 193.81 49.49 48.91 49.24 47.09 46.55

wB 0.6036 0.6036 0.6036 0.6036 0.6036 0.6036 0.6036 0.6036 0.6036 T/K 402.73 423.17 382.22 382.23 382.24 361.32 361.32 361.33 382.22 P/MPa 46.77 49.49 44.34 44.12 44.02 41.42 41.39 41.11 44.34 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 7200, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)16CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.1755 was kept constant

T/K 423.31 423.51 423.51 413.19 413.18 413.18 410.10 410.10 410.11 P/MPa 124.82 124.95 125.02 142.86 143.04 143.34 149.02 149.66 150.13

T/K 407.05 407.06 407.07 404.99 405.00 404.99 403.17 402.18 403.18 P/MPa 158.87 159.58 159.89 167.59 168.25 168.85 180.65 180.92 181.21

T/K 401.89 401.88 401.90 P/MPa 195.57 196.30 197.24

_______________________________________________________________________________ Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 1200, Boltorn-type, OH-endgroups are esterified to -O(CO)CF3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 T/K 270.82 270.95 270.99 291.47 291.49 291.46 302.19 302.15 302.18 P/MPa 12.17 12.30 12.22 21.11 21.18 21.17 24.43 24.44 24.46

wB 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 T/K 312.25 312.41 312.41 332.78 332.89 332.90 354.36 355.55 354.95 P/MPa 28.38 28.49 28.57 34.71 34.72 34.66 40.23 39.08 39.20

wB 0.0206 0.0206 0.0206 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 375.94 376.03 376.07 282.30 282.17 282.09 282.04 281.99 281.96 P/MPa 45.31 45.35 45.18 13.37 16.96 16.44 15.81 15.67 14.03

wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 287.70 287.76 287.83 287.89 287.89 295.10 295.14 295.16 295.18 P/MPa 15.86 18.59 15.75 15.92 18.16 18.30 22.69 21.29 20.69

wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 295.18 295.18 301.16 301.14 301.13 301.14 300.74 301.10 301.09 P/MPa 19.91 19.74 22.82 22.67 22.64 22.65 21.35 21.12 21.14

wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 311.24 311.30 311.31 311.35 321.28 321.59 321.61 321.63 331.92 P/MPa 25.40 25.80 25.62 25.65 29.35 29.39 29.42 29.38 30.93

wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 331.91 331.86 331.82 342.07 342.01 341.97 341.98 352.32 352.41 P/MPa 31.37 31.20 31.13 34.14 34.57 34.52 34.56 37.64 36.78

wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 T/K 352.39 352.37 362.52 362.58 362.57 362.52 374.98 374.78 374.80 P/MPa 37.78 37.00 40.33 40.57 40.80 40.62 43.19 43.33 43.46

wB 0.0495 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 T/K 374.83 282.01 282.02 282.02 301.99 302.01 301.99 319.33 320.97 P/MPa 43.41 17.47 17.38 17.62 26.05 26.03 26.06 32.52 32.58

wB 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 0.1007 T/K 319.28 339.60 339.57 339.53 354.94 354.89 354.82 375.98 376.00 P/MPa 32.58 39.14 39.10 39.11 43.15 43.13 43.15 47.67 47.89

wB 0.1007 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 T/K 375.99 281.97 282.06 282.07 282.07 282.05 300.10 300.12 300.09 P/MPa 47.95 14.42 14.43 15.23 15.98 15.47 22.71 22.66 22.62

wB 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 0.2028 T/K 320.29 320.51 320.55 340.96 341.02 355.47 355.48 355.48 375.95 P/MPa 30.51 30.49 30.60 37.38 37.39 41.32 41.38 41.38 45.92

continued

_______________________________________________________________________________

continued

wB 0.2028 0.2028 0.2028 T/K 375.95 375.96 341.06 P/MPa 46.01 46.08 37.39 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 3950, Boltorn-type, OH-endgroups are esterified to -O(CO)CF3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 T/K 281.15 281.14 281.19 300.61 300.62 300.62 320.24 320.28 320.29 P/MPa 18.32 18.46 18.43 27.80 27.53 27.43 33.38 33.14 33.09

wB 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 0.0218 T/K 340.77 340.74 340.82 361.42 361.42 361.39 376.20 376.36 376.32 P/MPa 38.31 38.52 38.52 44.09 44.22 44.28 47.57 47.76 47.84

wB 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 T/K 281.71 281.71 281.71 281.71 291.26 291.23 291.23 291.23 299.89 P/MPa 18.49 18.68 18.70 18.71 22.30 22.80 22.82 22.75 27.01

wB 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 T/K 300.12 300.12 310.12 310.40 310.39 320.22 320.67 320.65 330.58 P/MPa 26.98 26.90 30.23 30.25 30.16 33.01 33.57 33.34 36.75

wB 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 T/K 331.03 330.95 341.24 341.27 341.29 341.27 351.52 351.56 351.56 P/MPa 36.83 36.84 39.08 39.35 39.84 40.06 42.25 42.42 42.39

wB 0.0639 0.0639 0.0639 0.0639 0.0639 0.0639 0.1022 0.1022 0.1022 T/K 361.72 361.75 361.70 375.44 375.63 375.42 281.06 281.01 280.99 P/MPa 44.63 44.72 44.76 47.59 47.62 47.72 19.73 19.92 19.94

wB 0.1022 0.1022 0.1022 0.1022 0.1022 0.1022 0.1022 0.1022 0.1022 T/K 301.74 301.85 301.86 320.47 320.43 320.43 340.93 340.93 340.94 P/MPa 29.41 29.00 28.95 35.06 34.87 34.88 41.11 40.99 40.87

wB 0.1022 0.1022 0.1022 0.1022 0.1022 0.1022 0.2001 0.2001 0.2001 T/K 361.43 361.45 361.41 375.96 376.06 376.15 281.15 281.08 281.18 P/MPa 46.17 46.08 46.11 49.15 49.37 49.30 15.74 15.97 16.01

wB 0.2001 0.2001 0.2001 0.2001 0.2001 0.2001 0.2001 0.2001 0.2001 T/K 301.03 301.18 301.29 320.47 320.54 320.55 341.04 341.01 341.00 P/MPa 25.08 25.04 25.06 31.93 31.85 31.80 38.47 38.38 38.35

wB 0.2001 0.2001 0.2001 0.2001 0.2001 0.2001 T/K 361.59 361.58 361.53 376.22 376.23 376.18 P/MPa 43.95 43.93 43.81 46.94 46.91 46.93

_______________________________________________________________________________ Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 10500, Boltorn-type, OH-endgroups are esterified to -O(CO)CF3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 T/K 280.52 280.52 280.54 301.31 301.74 302.08 320.24 320.47 320.37 P/MPa 21.92 22.04 21.92 30.33 30.56 30.66 37.11 37.15 37.11

wB 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 T/K 339.24 339.74 339.81 339.83 361.61 361.68 361.55 376.22 376.19 P/MPa 42.79 44.32 44.21 44.05 48.55 49.01 49.14 51.43 51.57

wB 0.0229 0.0229 0.0229 0.0229 0.0502 0.0502 0.0502 0.0502 0.0502 T/K 376.17 376.02 376.09 375.92 281.19 281.18 281.18 291.68 291.58 P/MPa 51.65 51.66 51.84 51.79 23.66 23.77 23.75 27.47 27.83

wB 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 T/K 291.56 299.10 299.11 299.11 310.12 310.36 310.38 320.43 320.70 P/MPa 27.69 30.06 29.90 29.79 33.92 34.33 34.25 37.62 37.81

wB 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 T/K 320.71 330.97 330.96 330.96 341.07 341.10 341.05 351.33 351.34 P/MPa 37.79 41.05 40.71 40.99 43.76 44.08 44.11 47.01 47.19

wB 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.0502 0.1002 0.1002 T/K 351.33 361.46 361.53 361.39 374.89 374.63 374.56 280.12 280.03 P/MPa 47.32 49.50 49.83 49.69 52.87 52.95 52.94 22.87 23.25

wB 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 T/K 280.03 280.02 300.08 300.05 300.04 320.46 320.44 320.46 341.17 P/MPa 23.25 23.05 31.56 31.53 31.40 39.18 39.08 39.07 45.62

wB 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.1002 0.2032 T/K 341.33 341.35 362.04 362.14 362.11 376.81 376.78 376.75 281.16 P/MPa 45.63 45.51 50.52 50.38 50.25 53.56 53.62 53.73 19.33

wB 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 T/K 281.17 280.98 301.06 301.19 301.28 319.46 319.36 319.30 340.79 P/MPa 19.17 19.00 27.89 27.84 27.86 34.66 34.56 34.55 41.54

wB 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 0.2032 T/K 341.03 341.11 361.58 361.57 361.52 376.24 376.00 376.02 P/MPa 41.40 41.41 46.85 46.66 46.62 49.61 49.44 49.46

_______________________________________________________________________________ Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 1400, Boltorn-type, OH-endgroups are modified to -OSi(CH3)3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 T/K 280.96 281.06 281.05 281.05 290.49 290.49 290.50 290.49 300.98 P/MPa 5.44 5.45 5.38 5.27 8.88 9.16 9.20 9.26 15.33

wB 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 T/K 301.11 301.12 301.13 301.17 301.15 311.26 311.26 311.26 311.25 P/MPa 15.56 15.50 15.42 13.79 13.93 17.36 17.63 17.72 17.64

wB 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 T/K 311.48 321.20 321.61 321.66 321.65 331.74 331.81 331.89 331.92 P/MPa 17.05 20.38 20.62 20.71 20.91 24.28 24.55 24.60 24.61

wB 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 T/K 342.16 342.14 342.07 342.05 352.22 352.33 352.32 352.33 362.62 P/MPa 27.91 28.17 28.18 28.27 31.20 31.42 31.48 31.46 33.80

wB 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0189 0.0575 0.0575 T/K 362.64 362.62 362.59 374.92 375.01 375.06 375.01 279.52 279.26 P/MPa 34.02 34.03 34.01 36.52 36.60 36.64 36.63 6.81 6.71

wB 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 T/K 279.24 279.30 291.01 291.25 291.42 291.49 301.10 301.09 301.07 P/MPa 6.71 6.73 11.36 11.41 11.44 11.47 16.20 16.25 16.25

wB 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 T/K 301.05 311.35 311.34 311.33 311.32 321.25 321.28 321.23 321.28 P/MPa 16.25 20.83 20.73 20.64 20.60 23.50 23.58 23.66 23.58

wB 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 T/K 331.56 331.60 331.53 331.48 341.56 341.58 341.58 341.61 352.07 P/MPa 25.99 26.19 26.18 26.17 29.01 29.17 29.20 29.19 31.19

wB 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 0.0575 T/K 352.04 352.01 352.00 362.05 361.94 361.86 361.92 375.22 375.28 P/MPa 31.18 31.13 31.08 33.32 33.28 33.27 33.26 35.65 35.89

wB 0.0575 0.0575 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 T/K 375.27 375.32 280.45 280.52 292.11 292.06 292.05 292.07 302.42 P/MPa 35.95 35.98 7.93 7.89 12.99 12.92 12.89 12.87 17.15

wB 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 T/K 302.17 302.01 301.92 311.28 311.28 311.28 311.29 321.29 321.53 P/MPa 17.01 16.89 16.84 19.59 19.66 19.63 19.66 23.09 23.28

continued

_______________________________________________________________________________

continued

wB 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 T/K 321.51 321.50 321.49 331.64 331.69 331.73 331.71 331.56 331.60 P/MPa 23.29 23.30 22.99 26.59 26.66 26.71 26.72 25.99 26.19

wB 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 T/K 341.93 341.92 341.91 341.92 352.04 352.05 352.05 352.06 362.20 P/MPa 29.57 29.80 29.82 29.86 32.65 32.90 32.95 32.97 35.46

wB 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1012 0.1889 0.1889 T/K 362.28 362.31 362.24 375.57 375.56 375.59 375.58 280.94 280.90 P/MPa 35.60 35.67 35.67 38.48 38.59 38.61 38.62 4.64 4.61

wB 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 T/K 280.87 280.87 290.11 290.18 290.19 290.17 302.09 302.15 302.16 P/MPa 4.51 4.49 8.84 8.91 9.23 8.72 15.39 15.37 15.33

wB 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 T/K 302.13 312.01 312.24 312.25 312.27 322.14 322.48 322.51 322.50 P/MPa 15.30 17.43 17.46 17.52 17.55 21.01 21.37 21.42 21.44

wB 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 T/K 332.58 332.52 332.54 332.57 342.86 342.89 342.89 342.89 353.09 P/MPa 24.44 24.31 24.24 24.27 27.84 27.87 27.89 27.85 30.81

wB 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 0.1889 T/K 353.10 353.11 353.11 363.18 363.07 362.95 362.92 375.26 375.47 P/MPa 30.98 30.96 30.98 33.37 33.50 33.48 33.47 36.07 36.24

wB 0.1889 0.1889 T/K 375.55 375.54 P/MPa 36.27 36.23 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 3450, Boltorn-type, OH-endgroups are modified to -OSi(CH3)3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 T/K 280.64 280.70 280.77 299.85 300.27 300.27 320.38 320.45 320.49 P/MPa 21.71 22.09 22.00 25.67 25.71 25.68 31.09 31.13 31.16

wB 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246 T/K 341.10 341.15 341.15 361.52 361.38 361.31 375.62 375.39 375.29 P/MPa 36.86 36.98 37.00 41.97 42.02 42.10 44.97 45.12 44.99

wB 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 T/K 279.92 279.97 279.92 299.97 299.98 299.98 320.06 320.29 320.30 P/MPa 23.06 23.18 23.14 26.66 26.72 26.73 31.85 31.93 31.98

continued

_______________________________________________________________________________

continued

wB 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 T/K 340.65 340.81 340.75 361.23 361.23 361.18 375.92 376.02 375.92 P/MPa 37.32 37.36 37.38 42.30 42.34 42.31 45.40 45.41 45.42

wB 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 T/K 280.44 280.42 280.42 299.00 298.99 298.98 320.32 320.34 320.32 P/MPa 21.57 21.43 21.31 24.80 24.80 24.88 31.22 31.22 31.22

wB 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 0.1089 T/K 340.71 340.72 340.71 361.16 361.15 361.13 375.62 375.53 375.53 P/MPa 36.93 36.88 36.87 42.01 42.05 42.01 45.07 45.07 45.04

wB 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 T/K 280.07 280.00 280.00 299.67 300.00 300.02 320.45 320.38 320.36 P/MPa 17.77 17.78 17.64 22.80 23.09 23.19 28.87 28.67 28.72

wB 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 0.2091 T/K 340.83 340.74 340.75 361.82 361.52 361.38 375.86 375.76 375.72 P/MPa 34.66 34.62 34.62 39.99 39.96 39.83 42.93 42.89 42.97 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 5200, Boltorn-type, OH-endgroups are modified to -OSi(CH3)3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 T/K 278.56 278.24 278.07 277.96 280.24 280.16 280.16 290.28 290.31 P/MPa 38.00 39.34 39.86 39.60 39.93 40.17 40.23 38.14 38.46

wB 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 T/K 290.32 300.91 300.97 301.04 320.48 320.53 320.51 340.90 341.02 P/MPa 38.47 39.04 38.97 39.21 42.39 42.48 42.50 46.39 46.31

wB 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0206 0.0515 0.0515 T/K 341.02 355.26 355.40 355.41 376.28 376.22 376.32 277.35 277.30 P/MPa 46.23 49.21 49.12 49.04 52.74 52.45 52.71 54.75 54.35

wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 T/K 277.38 277.40 283.01 282.99 282.99 283.00 289.80 290.31 290.50 P/MPa 54.42 54.21 44.60 45.16 45.54 45.97 40.30 40.21 40.27

wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 T/K 292.54 292.54 292.54 299.81 300.28 300.59 300.63 300.12 300.14 P/MPa 40.54 40.89 40.74 42.03 41.57 41.57 41.34 39.02 40.41

wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 T/K 300.14 300.14 310.38 310.32 310.31 310.29 320.19 320.43 320.45 P/MPa 40.20 40.19 40.62 40.73 40.66 40.61 44.46 43.83 43.67

continued

_______________________________________________________________________________

continued

wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 T/K 320.48 330.78 330.78 330.80 330.79 341.08 341.11 341.12 341.11 P/MPa 43.64 45.62 45.24 45.12 44.84 46.51 46.56 46.75 46.78

wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 T/K 351.35 351.38 351.35 351.34 361.45 361.60 361.62 375.07 375.07 P/MPa 48.97 48.88 48.89 48.96 51.06 51.06 51.07 53.64 53.65

wB 0.0515 0.0515 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 T/K 375.07 375.09 284.90 284.49 284.41 284.31 290.58 290.09 289.78 P/MPa 53.61 53.60 58.90 60.77 61.08 61.41 50.73 52.05 52.57

wB 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 T/K 289.67 300.26 300.67 300.82 300.92 320.62 320.60 320.58 341.14 P/MPa 52.80 42.25 43.48 43.36 43.30 44.32 44.75 44.78 48.17

wB 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 0.1334 T/K 341.20 341.18 361.78 361.80 361.78 376.38 376.41 376.48 P/MPa 48.23 48.29 52.16 52.21 52.15 54.64 54.57 54.85 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 1550, Boltorn-type, OH-endgroups are esterified to -O[(CO)(CH2)5O]5Si(CH3)3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0511 was kept constant

T/K 280.11 280.15 300.13 300.13 300.13 300.12 320.70 320.72 320.73 P/MPa 58.47 58.55 63.50 63.81 62.98 62.79 69.00 68.86 69.11

T/K 340.51 341.08 341.35 361.97 361.99 362.01 376.38 376.21 376.21 P/MPa 72.54 72.36 72.46 77.57 77.48 77.27 80.82 80.66 80.92 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 4600, Boltorn-type, OH-endgroups are esterified to -O[(CO)O(CH2)5O]5(CO)CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

continued

_______________________________________________________________________________

continued

wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1326 T/K 310.45 310.45 310.50 302.32 302.31 302.31 P/MPa 152.40 152.66 152.94 147.99 148.57 148.86 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 4450, Boltorn-type, OH-endgroups are esterified to -O[(CO)(CH2)5O]5(CO)CH3 Solvent (A): carbon dioxide CO2 124-38-9

Type of data: cloud points

wB 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 T/K 423.36 423.37 423.35 12.95 412.95 412.96 402.88 402.89 402.89 P/MPa 159.10 158.59 158.74 159.48 159.62 159.52 159.88 160.24 160.44

wB 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 T/K 392.56 392.57 392.57 382.40 382.41 382.40 371.89 371.90 371.91 P/MPa 162.17 161.84 161.91 163.40 163.52 163.86 165.18 165.24 165.32

wB 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 0.0215 T/K 361.44 361.43 361.44 351.17 351.17 351.16 340.88 340.89 330.60 P/MPa 168.34 168.26 168.20 172.55 172.38 172.15 176.73 177.03 184.98

wB 0.0215 0.0215 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 T/K 330.60 330.60 423.52 423.52 423.51 413.28 413.28 413.28 402.98 P/MPa 185.22 185.57 172.56 171.56 171.87 170.69 170.72 170.66 169.92

wB 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 T/K 402.31 402.31 392.47 392.49 392.50 382.52 382.53 382.52 372.33 P/MPa 169.84 170.43 171.55 171.90 172.14 175.52 175.89 176.02 177.27

wB 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 0.0859 T/K 372.33 372.35 361.55 361.55 361.54 351.22 351.22 351.21 340.84 P/MPa 177.08 177.18 178.30 178.47 179.02 181.60 181.86 182.27 185.17

continued

_______________________________________________________________________________

continued

wB 0.0859 0.0859 0.0859 0.0859 0.0859 0.2882 0.2882 0.2882 0.2882 T/K 340.92 340.93 330.58 330.58 330.57 423.33 423.35 423.34 423.34 P/MPa 185.24 185.53 195.38 195.20 194.87 145.29 144.98 144.57 144.94

wB 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 T/K 423.32 413.26 413.25 413.25 402.87 402.88 402.87 392.57 392.57 P/MPa 144.63 144.78 144.83 144.89 145.90 145.07 145.24 145.16 145.07

wB 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 T/K 392.56 382.32 382.36 382.33 371.89 371.89 371.88 361.39 361.39 P/MPa 145.14 145.06 145.24 145.44 145.98 146.06 146.11 146.52 146.44

wB 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 0.2882 T/K 361.41 351.15 351.14 351.15 340.87 340.86 340.88 330.37 330.36 P/MPa 146.63 147.08 147.22 147.43 148.35 147.77 147.87 148.56 148.63 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 5600, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)10CH3 Solvent (A): ethane C2H6 74-84-0

Type of data: cloud points

wB 0.0768 was kept constant

T/K 280.47 280.41 280.40 290.13 290.22 290.22 300.03 300.06 300.06 P/MPa 42.34 42.28 42.20 42.41 42.37 42.35 42.92 42.84 42.91

T/K 310.22 310.20 310.21 320.34 320.34 320.35 330.53 330.51 330.52 P/MPa 42.97 43.27 43.29 43.87 43.94 43.91 44.75 44.78 44.82

T/K 340.35 340.32 340.42 350.76 350.78 350.78 360.93 361.00 361.04 P/MPa 45.61 45.67 45.68 46.49 46.53 46.59 47.28 47.31 47.37

T/K 371.30 371.22 371.19 P/MPa 48.05 48.15 48.14 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 7200, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)16CH3 Solvent (A): ethane C2H6 74-84-0

Type of data: cloud points

wB 0.0769 was kept constant

T/K 300.00 300.02 300.01 310.09 310.17 310.19 319.97 320.20 320.28 P/MPa 46.47 46.46 46.49 47.59 47.61 47.59 48.31 48.36 48.40

T/K 330.55 330.60 330.61 340.79 340.76 340.78 351.00 351.15 351.17 P/MPa 49.53 49.50 49.46 50.88 50.60 50.48 51.26 51.36 51.28

continued

_______________________________________________________________________________

continued

T/K 361.46 361.45 361.42 371.80 371.75 371.75 P/MPa 52.19 52.16 52.16 52.92 52.81 52.90 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 3450, Boltorn-type, OH-endgroups are modified to -OSi(CH3)3 Solvent (A): ethane C2H6 74-84-0

Type of data: cloud points

wB 0.0755 was kept constant

T/K 280.48 280.24 280.13 290.70 290.68 290.69 300.08 300.08 300.08 P/MPa 31.28 31.47 31.37 31.84 31.60 31.44 31.24 31.18 31.08

T/K 310.21 310.28 310.29 320.67 320.66 320.65 330.94 330.92 330.94 P/MPa 31.40 31.84 31.67 32.34 32.15 31.81 34.07 33.02 33.71

T/K 330.92 341.23 341.24 341.24 341.23 351.51 351.49 351.49 361.74 P/MPa 33.48 35.22 34.93 34.65 34.52 35.41 35.89 35.87 36.38

T/K 361.76 361.75 372.11 372.11 372.10 P/MPa 36.66 36.68 37.92 37.71 37.56 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 7200, Boltorn-type, OH-endgroups are esterified to -O(CO)(CH2)16CH3 Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.0780 was kept constant

T/K 310.27 310.30 310.30 320.61 320.63 320.52 330.73 330.77 330.72 P/MPa 3.09 3.06 3.04 5.62 5.56 5.51 7.79 7.84 7.82

T/K 340.97 340.94 340.95 351.21 351.22 351.21 361.45 361.49 361.48 P/MPa 9.95 10.03 10.02 12.05 12.05 12.04 13.99 13.99 14.07

T/K 372.02 372.03 371.96 P/MPa 15.93 15.92 15.92 Polymer (B): polyester (hyperbranched) 2010GRE Characterization: Mn/g.mol1 = 3450, Boltorn-type, OH-endgroups are modified to -OSi(CH3)3 Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.1051 was kept constant

continued

_______________________________________________________________________________

continued

T/K 341.09 341.08 341.09 351.23 351.31 351.32 361.56 361.52 361.52 P/MPa 3.31 3.37 3.38 5.36 5.46 5.51 7.55 7.37 7.44

T/K 371.56 371.68 371.70 382.25 382.24 382.24 395.10 395.22 395.16 P/MPa 8.92 8.94 9.00 10.47 10.47 10.46 12.15 12.28 12.20 Polymer (B): polyester (hyperbranched) 2009POR Characterization: Mn/g.mol1 = 6560, Mw/g.mol1 = 10500, Boltorn H3200, solid, fatty acid (C20/C22) modified, Perstorp Speciality Chemicals AB, Sweden Solvent (A): propane C3H8 74-98-6

Type of data: cloud points

wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 T/K 313.43 315.36 318.28 320.22 323.17 325.12 328.10 333.03 337.98 P/MPa 4.06 4.45 5.31 5.71 6.50 6.85 7.27 8.28 9.03

wB 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050 0.050 T/K 342.95 347.88 352.86 357.77 312.96 315.00 316.50 317.91 320.96 P/MPa 9.94 10.78 11.43 11.75 5.15 5.30 5.75 5.76 6.75

wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.099 0.099 T/K 322.70 327.50 332.11 336.96 341.90 346.85 351.71 308.51 313.21 P/MPa 6.83 7.86 8.64 9.59 10.60 11.65 12.57 4.50 5.72

wB 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.200 0.200 T/K 317.91 322.67 327.41 332.21 337.13 342.04 346.93 313.57 318.37 P/MPa 6.82 7.89 8.93 9.97 11.00 11.99 13.00 5.83 6.93

wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.301 0.301 T/K 323.30 328.19 333.09 337.97 342.86 347.77 352.67 308.54 313.38 P/MPa 8.02 9.08 10.10 11.09 12.06 13.01 13.92 4.45 5.57

wB 0.301 0.301 0.301 0.301 0.301 0.301 0.301 0.401 0.401 T/K 318.29 323.22 328.18 333.08 338.11 343.07 348.06 313.17 317.64 P/MPa 6.69 7.77 8.83 9.87 10.87 11.84 12.79 5.27 6.30

wB 0.401 0.401 0.401 0.401 0.401 0.401 0.401 0.501 0.501 T/K 322.10 326.34 330.85 336.12 340.94 345.77 350.74 308.61 310.57 P/MPa 7.35 8.32 9.34 10.32 11.27 12.19 13.08 3.15 3.55

wB 0.501 0.501 0.501 0.501 0.501 0.501 0.501 0.501 0.501 T/K 312.62 318.73 323.28 328.17 333.12 338.04 342.94 347.88 352.79 P/MPa 4.05 5.39 6.46 7.52 8.55 9.55 10.52 11.46 12.38

wB 0.501 0.603 0.603 0.603 0.603 0.603 0.603 0.603 0.603 T/K 357.62 315.94 318.38 323.33 328.33 333.24 338.15 343.02 347.90 P/MPa 13.24 1.75 2.32 3.43 4.51 5.55 6.55 7.53 8.48

continued

_______________________________________________________________________________

continued

wB 0.603 0.603 0.603 0.603 0.701 0.701 0.701 0.701 0.701 T/K 352.80 357.74 362.67 367.63 345.27 346.76 347.69 348.76 350.10 P/MPa 9.41 10.32 11.20 12.06 2.78 3.00 3.21 3.39 3.65

wB 0.701 0.701 0.701 0.701 0.701 0.701 0.701 0.701 0.701 T/K 351.88 353.94 356.79 358.82 361.64 363.60 366.20 370.92 380.62 P/MPa 4.02 4.47 4.96 5.29 5.90 6.23 6.65 7.47 9.08

wB 0.701 0.701 0.701 T/K 390.73 400.82 410.66 P/MPa 10.66 12.13 13.48

Type of data: vapor-liquid-liquid equilibrium data

wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.050 T/K 312.06 313.42 323.22 333.05 343.04 352.96 362.90 370.04 307.34 P/MPa 1.34 1.38 1.72 2.12 2.59 3.13 3.75 4.25 (*) 1.22

wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 T/K 308.48 310.84 313.30 314.16 322.99 331.59 341.84 351.62 361.35 P/MPa 1.25 1.32 1.40 1.42 1.73 2.04 2.54 3.06 3.66

wB 0.050 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099 T/K 369.98 303.70 306.25 308.67 313.21 322.77 332.21 341.97 351.72 P/MPa 4.30 (*) 1.14 1.21 1.27 1.41 1.75 2.12 2.58 3.09

wB 0.099 0.099 0.099 0.200 0.200 0.200 0.200 0.200 0.200 T/K 361.51 369.99 369.82 308.65 309.43 313.52 318.36 323.26 333.08 P/MPa 3.70 4.27 4.27 (*) 1.25 1.27 1.40 1.55 1.73 2.13

wB 0.200 0.200 0.200 0.200 0.301 0.301 0.301 0.301 0.301 T/K 343.03 352.79 362.58 369.99 308.52 308.66 313.42 323.20 333.12 P/MPa 2.60 3.12 3.73 4.25 (*) 1.24 1.24 1.38 1.72 2.12

wB 0.301 0.301 0.301 0.301 0.301 0.401 0.401 0.401 0.401 T/K 343.19 353.05 362.92 370.00 369.99 308.48 308.89 312.93 322.19 P/MPa 2.59 3.13 3.75 4.23 4.25 (*) 1.25 1.26 1.38 1.71

wB 0.401 0.401 0.401 0.401 0.401 0.401 0.501 0.501 0.501 T/K 331.20 340.63 350.04 359.81 369.15 369.34 311.42 313.41 323.28 P/MPa 2.08 2.53 3.02 3.62 4.25 4.25 (*) 1.37 1.43 1.77

wB 0.501 0.501 0.501 0.501 0.501 0.603 0.603 0.603 0.603 T/K 333.11 342.99 352.78 362.63 369.85 308.58 313.17 312.52 323.31 P/MPa 2.17 2.63 3.16 3.78 4.27 (*) 1.25 1.39 1.40 1.74

wB 0.603 0.603 0.603 0.603 0.603 0.701 0.701 0.701 T/K 333.20 343.07 352.90 362.70 369.91 351.99 361.62 369.93 P/MPa 2.13 2.60 3.13 3.74 4.26 (*) 3.10 3.69 4.29 (*)

Comments: (*) Critical end point. VLE data are given in Chapter 2. Equilibrium data with a solid phase are not included here and have to be found in the original source.