Pvt Data Of Polymers And Solutions

P/MPa T/K 306.21 315.50 325.05 334.73 344.40 354.59 364.18 374.04 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.94562 0.95169 0.95777 0.96385 0.96998 0.97577 0.98156 0.98781 10 0.94099 0.94675 0.95256 0.95835 0.96412 0.96964 0.97504 0.98089 20 0.93661 0.94204 0.94765 0.95312 0.95868 0.96393 0.96891 0.97445 30 0.93240 0.93768 0.94304 0.94827 0.95347 0.95849 0.96333 0.96850 40 0.92834 0.93345 0.93860 0.94369 0.94866 0.95345 0.95800 0.96311 50 0.92459 0.92945 0.93448 0.93929 0.94405 0.94873 0.95310 0.95796 60 0.92092 0.92573 0.93059 0.93524 0.93985 0.94435 0.94854 0.95322 70 0.91741 0.92218 0.92672 0.93135 0.93589 0.94009 0.94420 0.94868 80 0.91421 0.91876 0.92328 0.92768 0.93202 0.93613 0.94013 0.94444 90 0.91110 0.91542 0.91991 0.92415 0.92844 0.93238 0.93616 0.94046 100 0.90815 0.91230 0.91669 0.92083 0.92495 0.92893 0.93262 0.93669 110 0.90522 0.90932 0.91359 0.91760 0.92163 0.92541 0.92911 0.93302 120 0.90244 0.90640 0.91062 0.91459 0.91850 0.92211 0.92571 0.92954 130 0.89978 0.90373 0.90767 0.91164 0.91546 0.91911 0.92245 0.92630 140 0.89727 0.90102 0.90489 0.90877 0.91254 0.91598 0.91931 0.92311 150 0.89474 0.89846 0.90230 0.90608 0.90972 0.91309 0.91644 0.91994 160 0.89244 0.89587 0.89965 0.90342 0.90690 0.91023 0.91349 0.91696 170 0.89011 0.89345 0.89708 0.90077 0.90421 0.90751 0.91083 0.91413 180 0.88787 0.89110 0.89471 0.89824 0.90168 0.90486 0.90802 0.91125 190 0.88571 0.88879 0.89224 0.89589 0.89914 0.90225 0.90536 0.90862 200 0.88355 0.88653 0.88991 0.89334 0.89658 0.89965 0.90270 0.90588 _______________________________________________________________________________

continued

_______________________________________________________________________________

P/MPa T/K 384.25 394.24 404.38 414.34 424.67 434.61 Vspec/cm3g1 _________________________________________________________________________________________________

0.1 0.99409 1.00107 1.00834 1.01573 1.02336 1.03111 10 0.98691 0.99343 1.00023 1.00706 1.01414 1.02139 20 0.98025 0.98634 0.99263 0.99911 1.00570 1.01258 30 0.97407 0.97990 0.98614 0.99192 0.99820 1.00463 40 0.96837 0.97387 0.97992 0.98536 0.99134 0.99748 50 0.96298 0.96835 0.97409 0.97931 0.98503 0.99093 60 0.95800 0.96318 0.96860 0.97374 0.97919 0.98490 70 0.95330 0.95833 0.96353 0.96849 0.97375 0.97925 80 0.94887 0.95375 0.95877 0.96358 0.96870 0.97397 90 0.94474 0.94941 0.95436 0.95901 0.96387 0.96899 100 0.94086 0.94543 0.95015 0.95458 0.95939 0.96435 110 0.93716 0.94158 0.94615 0.95044 0.95509 0.95991 120 0.93350 0.93785 0.94232 0.94651 0.95096 0.95577 130 0.93018 0.93433 0.93869 0.94279 0.94714 0.95170 140 0.92682 0.93092 0.93516 0.93913 0.94345 0.94795 150 0.92368 0.92771 0.93179 0.93571 0.93984 0.94430 160 0.92065 0.92454 0.92853 0.93235 0.93648 0.94076 170 0.91767 0.92152 0.92543 0.92915 0.93315 0.93732 180 0.91481 0.91853 0.92235 0.92612 0.92992 0.93403 190 0.91196 0.91572 0.91947 0.92307 0.92686 0.93086 200 0.90930 0.91284 0.91656 0.92009 0.92384 0.92775 _________________________________________________________________________________________________ Polymer (B): poly(-caprolactone) 2011SCH Characterization: Mw/g.mol1 = 80000, CAPA® FB100, Solvay Warrington, Cheshire, United Kingdom _________________________________________________________________________________________________

P/MPa T/K 400.93 421.04 431.10 441.31 451.42 471.87 /(g/cm3) _________________________________________________________________________________________________

110 1.0691 1.0591 1.0538 1.0486 1.0437 1.0336 120 1.0732 1.0631 1.0580 1.0529 1.0480 1.0382 130 1.0769 1.0671 1.0622 1.0571 1.0522 1.0425 140 1.0807 1.0710 1.0660 1.0610 1.0563 1.0469 150 1.0843 1.0747 1.0700 1.0649 1.0601 1.0510 160 1.0878 1.0783 1.0736 1.0687 1.0641 1.0549 170 1.0910 1.0820 1.0774 1.0725 1.0679 1.0590 180 1.0944 1.0854 1.0809 1.0761 1.0715 1.0628 190 1.0977 1.0889 1.0844 1.0797 1.0751 1.0666 200 1.1009 1.0921 1.0878 1.0832 1.0786 1.0702 _________________________________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(diglycidyl ether of bisphenol A) 2007DL2 Characterization: Mn/g.mol1 = 1750, Tg/K = 332, polymerization degree about 5

_______________________________________________________________________________

P/MPa T/K 369.00 388.89 410.90 429.27 439.52 449.44 459.55 469.79 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.88230 0.89287 0.90392 0.91552 0.92063 0.92595 0.93113 0.93674 10 0.87867 0.88882 0.89934 0.91041 0.91532 0.92032 0.92525 0.93046 20 0.87512 0.88492 0.89493 0.90556 0.91029 0.91493 0.91969 0.92450 30 0.87190 0.88134 0.89093 0.90116 0.90568 0.91022 0.91470 0.91926 40 0.86868 0.87786 0.88725 0.89693 0.90143 0.90581 0.91006 0.91450 50 0.86569 0.87463 0.88368 0.89310 0.89728 0.90155 0.90570 0.90993 60 0.86281 0.87151 0.88031 0.88943 0.89353 0.89765 0.90164 0.90577 70 0.86003 0.86850 0.87702 0.88599 0.88990 0.89394 0.89784 0.90175 80 0.85746 0.86574 0.87416 0.88262 0.88657 0.89037 0.89417 0.89791 90 0.85492 0.86299 0.87109 0.87946 0.88325 0.88704 0.89067 0.89436 100 0.85249 0.86042 0.86833 0.87651 0.88007 0.88375 0.88732 0.89089 110 0.85023 0.85783 0.86563 0.87345 0.87703 0.88066 0.88410 0.88761 120 0.84793 0.85547 0.86300 0.87074 0.87416 0.87767 0.88107 0.88446 130 0.84579 0.85308 0.86047 0.86800 0.87138 0.87482 0.87815 0.88143 140 0.84361 0.85077 0.85809 0.86535 0.86871 0.87202 0.87523 0.87852 150 0.84154 0.84856 0.85573 0.86283 0.86612 0.86940 0.87247 0.87561 160 0.83950 0.84649 0.85341 0.86046 0.86363 0.86676 0.86982 0.87292 170 0.83755 0.84431 0.85116 0.85802 0.86111 0.86418 0.86720 0.87019 180 0.83563 0.84222 0.84898 0.85567 0.85874 0.86176 0.86470 0.86764 190 0.83381 0.84023 0.84684 0.85340 0.85631 0.85938 0.86229 0.86520 200 0.83214 0.83841 0.84494 0.85130 0.85419 0.85714 0.85993 0.86277 _______________________________________________________________________________ Polymer (B): poly(1H,1H-dihydroperfluorooctyl methacrylate) 2009SAN Characterization: Mw/g.mol1 = 110000, synthesized in the laboratory by ATRP

_______________________________________________________________________________

P/MPa T/K 303.15 313.15 323.15 333.15 343.15 353.15 373.15 393.15 Vspec/cm3g1 _______________________________________________________________________________

100 0.6591 0.6637 0.6673 0.6727 0.6770 0.6812 0.6910 0.7011 200 0.6542 0.6584 0.6622 0.6664 0.6709 0.6753 0.6836 0.6931 300 0.6504 0.6543 0.6579 0.6618 0.6660 0.6700 0.6780 0.6868 400 0.6472 0.6506 0.6540 0.6575 0.6616 0.6655 0.6728 0.6812 500 0.6443 0.6474 0.6505 0.6539 0.6577 0.6615 0.6684 0.6765 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

600 0.6414 0.6447 0.6473 0.6506 0.6542 0.6578 0.6646 0.6722 700 0.6390 0.6420 0.6444 0.6475 0.6509 0.6543 0.6610 0.6682 800 0.6367 0.6395 0.6418 0.6446 0.6479 0.6511 0.6575 0.6647 900 0.6343 0.6370 0.6393 0.6418 0.6450 0.6481 0.6543 0.6609 1000 0.6322 0.6349 0.6367 0.6392 0.6423 0.6452 0.6513 0.6579 1100 0.6303 0.6327 0.6345 0.6369 0.6398 0.6424 0.6482 0.6548 1200 0.6284 0.6307 0.6324 0.6347 0.6375 0.6400 0.6457 0.6520 1300 0.6266 0.6289 0.6303 0.6327 0.6353 0.6377 0.6432 0.6493 1400 0.6249 0.6269 0.6286 0.6306 0.6331 0.6354 0.6408 0.6467 1500 0.6233 0.6253 0.6268 0.6286 0.6310 0.6332 0.6385 0.6444 1600 0.6217 0.6238 0.6252 0.6269 0.6290 0.6310 0.6363 0.6419 1700 0.6202 0.6223 0.6235 0.6252 0.6273 0.6289 0.6342 0.6398 1800 0.6198 0.6208 0.6221 0.6236 0.6255 0.6270 0.6321 0.6376 1900 0.6173 0.6193 0.6204 0.6221 0.6238 0.6252 0.6300 0.6354 2000 0.6160 0.6178 0.6190 0.6203 0.6221 0.6234 0.6280 0.6334 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 413.15 433.15 453.15 473.15 Vspec/cm3g1 _______________________________________________________________________________

100 0.7184 0.7394 0.7515 0.7724 200 0.7086 0.7279 0.7388 0.7564 300 0.7011 0.7191 0.7294 0.7450 400 0.6943 0.7118 0.7218 0.7360 500 0.6884 0.7054 0.7151 0.7281 600 0.6836 0.6997 0.7094 0.7214 700 0.6790 0.6946 0.7040 0.7154 800 0.6747 0.6894 0.6988 0.7098 900 0.6706 0.6850 0.6934 0.7049 1000 0.6669 0.6805 0.6891 0.7005 1100 0.6632 0.6760 0.6847 0.6959 1200 0.6598 0.6722 0.6808 0.6923 1300 0.6570 0.6688 0.6772 0.6884 1400 0.6540 0.6653 0.6737 0.6849 1500 0.6513 0.6619 0.6704 0.6814 1600 0.6486 0.6587 0.6672 0.6778 1700 0.6461 0.6555 0.6641 0.6747 1800 0.6437 0.6525 0.6606 0.6715 1900 0.6413 0.6497 0.6572 0.6683 2000 0.6392 0.6469 0.6537 0.6651 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): polyester (hyperbranched, aliphatic) 2006SEI Characterization: Mn/g.mol1 = 1620, Mw/g.mol1 = 2100, 16 OH groups per macromolecule, hydroxyl no. = 490-520 mg KOH/g, acid no. = 5-9 mg KOH/g, Boltorn H20, Perstorp Speciality Chemicals AB, Sweden _________________________________________________________________________________________________

P/MPa T/K 343.15 383.15 423.15 ρ/kg m3 _________________________________________________________________________________________________

5 1241.6 1214.7 1188.3 10 1245.1 1217.6 1191.5 20 1249.2 1222.3 1197.0 35 1255.6 1229.4 1205.4 60 1265.2 1240.2 1216.2 _________________________________________________________________________________________________ Polymer (B): polyethylene 2007FU2 Characterization: Mw/g.mol1 = 127000, linear, ρ(293.15 K) = 0.9254 g/cm3, Tg/K = 195, Tm/K = 390, PE A27MA, Leuna AG, Germany _________________________________________________________________________________________________

P/MPa T/K 427.18 437.55 448.00 457.84 468.60 478.99 488.90 499.83 Vspec/cm3g1 _________________________________________________________________________________________________

0.1 1.2883 1.2981 1.3070 1.3163 1.3265 1.3368 1.3462 1.3573 10 1.2759 1.2849 1.2932 1.3018 1.3110 1.3204 1.3291 1.3391 20 1.2647 1.2730 1.2808 1.2888 1.2973 1.3059 1.3140 1.3233 30 1.2545 1.2624 1.2698 1.2772 1.2852 1.2932 1.3009 1.3093 40 1.2452 1.2526 1.2597 1.2667 1.2742 1.2817 1.2890 1.2969 50 1.2367 1.2436 1.2503 1.2571 1.2642 1.2713 1.2782 1.2857 60 1.2286 1.2353 1.2417 1.2482 1.2550 1.2618 1.2683 1.2755 70 1.2211 1.2277 1.2337 1.2399 1.2464 1.2529 1.2592 1.2660 80 1.2141 1.2205 1.2262 1.2321 1.2384 1.2446 1.2508 1.2572 90 1.2076 1.2136 1.2191 1.2250 1.2310 1.2369 1.2429 1.2491 100 1.2013 1.2072 1.2125 1.2181 1.2239 1.2298 1.2355 1.2414 110 1.1954 1.2011 1.2063 1.2117 1.2173 1.2230 1.2285 1.2344 120 1.1898 1.1953 1.2003 1.2056 1.2110 1.2165 1.2219 1.2276 130 1.1845 1.1897 1.1947 1.1998 1.2051 1.2104 1.2155 1.2210 140 1.1793 1.1845 1.1892 1.1942 1.1994 1.2045 1.2097 1.2148 150 1.1744 1.1795 1.1841 1.1890 1.1939 1.1990 1.2038 1.2090 160 1.1697 1.1746 1.1792 1.1839 1.1887 1.1937 1.1985 1.2035 170 1.1652 1.1700 1.1744 1.1791 1.1838 1.1887 1.1933 1.1981 180 1.1609 1.1655 1.1698 1.1743 1.1791 1.1838 1.1883 1.1929 190 1.1566 1.1613 1.1655 1.1698 1.1745 1.1791 1.1834 1.1881 200 1.1526 1.1571 1.1613 1.1655 1.1700 1.1746 1.1789 1.1834 _________________________________________________________________________________________________

_______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 509.94 519.47 530.59 540.05 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.3681 1.3786 1.3908 1.4013 10 1.3488 1.3583 1.3690 1.3785 20 1.3321 1.3408 1.3504 1.3592 30 1.3175 1.3258 1.3345 1.3428 40 1.3046 1.3124 1.3204 1.3281 50 1.2930 1.3003 1.3080 1.3153 60 1.2823 1.2895 1.2965 1.3036 70 1.2725 1.2794 1.2862 1.2931 80 1.2636 1.2701 1.2765 1.2829 90 1.2552 1.2615 1.2676 1.2738 100 1.2473 1.2533 1.2593 1.2651 110 1.2399 1.2457 1.2516 1.2572 120 1.2329 1.2386 1.2443 1.2496 130 1.2263 1.2319 1.2374 1.2424 140 1.2201 1.2254 1.2307 1.2359 150 1.2140 1.2193 1.2245 1.2293 160 1.2083 1.2135 1.2185 1.2232 170 1.2028 1.2078 1.2129 1.2174 180 1.1977 1.2026 1.2073 1.2118 190 1.1926 1.1974 1.2021 1.2065 200 1.1878 1.1926 1.1971 1.2014 _______________________________________________________________________________ Polymer (B): polyethylene 2007SAT Characterization: Mn/g.mol1 = 34000, Mw/g.mol1 = 215000, linear, HDPE, 74.7 wt% crystallinity, unspecified industrial source

_______________________________________________________________________________

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

414.1 1.263 1.250 1.239 433.9 1.280 1.267 1.255 1.226 1.190 453.8 1.298 1.284 1.271 1.240 1.201 1.172 1.149 473.7 1.318 1.302 1.288 1.254 1.213 1.182 1.157 493.6 1.339 1.321 1.304 1.267 1.224 1.192 1.166 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): polyethylene 2006PAR Characterization: Mn/g.mol1 = 8200, Mw/g.mol1 = 111000, Tm/K = 407

Tait equation parameter functions: Range of data: T/K = 423-483, P/MPa = 0.1-80 _________________________________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

V(0,T/K)/cm3g1 B(T/K)/MPa 0.876 + 9.84 104T 677.0 exp(4.83 103T ) _________________________________________________________________________________________________ Polymer (B): poly(ethylene-co-1-butene) 2007SAT Characterization: Mn/g.mol1 = 53000, Mw/g.mol1 = 110000, 10 mol% 1-butene, 12 wt% crystallinity, unspecified industrial source

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _________________________________________________________________________________________________

373.8 1.236 1.226 1.217 1.194 1.165 393.9 1.254 1.243 1.233 1.208 1.176 1.152 1.131 414.0 1.271 1.260 1.248 1.222 1.188 1.162 1.140 433.9 1.289 1.276 1.264 1.235 1.199 1.172 1.149 453.7 1.307 1.293 1.280 1.249 1.210 1.181 1.158 473.6 1.326 1.310 1.296 1.262 1.221 1.191 1.166 493.5 1.345 1.328 1.312 1.275 1.232 1.200 1.175 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-hexene) 2007SAT Characterization: Mn/g.mol1 = 28000, Mw/g.mol1 = 63000, 3.5 mol% 1-hexene, 51 wt% crystallinity, unspecified industrial source

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _________________________________________________________________________________________________

414.0 1.274 1.263 1.252 1.226 433.9 1.293 1.280 1.270 1.240 1.204 1.177 453.8 1.311 1.297 1.284 1.253 1.215 1.186 1.163 473.7 1.329 1.314 1.300 1.266 1.226 1.196 1.171 493.6 1.349 1.331 1.315 1.279 1.236 1.205 1.179 _________________________________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethylene-co-norbornene) 2013SAT Characterization: Mn/g.mol1 = 38800, Mw/g.mol1 = 74600, 52 mol% ethylene, Tg/K = 411.15, Topas Advanced Polymers GmbH

_______________________________________________________________________________

P/MPa T/K 414.3 444.1 473.9 503.9 534.1 564.3 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.025 1.043 1.061 1.077 1.094 1.112 20 1.018 1.033 1.048 1.064 1.080 1.097 40 1.011 1.022 1.036 1.051 1.065 1.080 60 1.005 1.012 1.025 1.038 1.052 1.065 80 0.999 1.004 1.015 1.028 1.040 1.053 100 0.994 0.999 1.007 1.019 1.030 1.042 120 0.989 0.994 0.999 1.010 1.021 1.032 140 0.985 0.990 0.992 1.002 1.013 1.023 160 0.980 0.987 0.986 0.995 1.004 1.015 180 0.975 0.983 0.981 0.988 0.997 1.007 200 0.971 0.979 0.977 0.981 0.990 0.999 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-norbornene) 2006BLO Characterization: Mn/g.mol1 = 56000, Mw/g.mol1 = 101000, Tg/K = 415, 51.8 mol% norbornene, commercial sample

Tait equation parameter functions: Range of data: T/K = 415-550, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.927 + 5.5 104 − 3.0 108 2 238.0 exp(0.3 102 ) _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethylene-co-1-octene) 2007SAT Characterization: Mn/g.mol1 = 106000, Mw/g.mol1 = 196000, 8.9 mol% 1-octene, 17.6 wt% crystallinity, unspecified industrial source

_______________________________________________________________________________

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

373.9 1.238 1.228 1.219 394.0 1.258 1.247 1.237 1.212 1.180 414.1 1.275 1.265 1.253 1.226 1.191 1.165 1.143 434.0 1.293 1.281 1.269 1.240 1.203 1.175 1.152 453.8 1.311 1.298 1.285 1.253 1.214 1.185 1.161 473.6 1.330 1.316 1.302 1.267 1.226 1.195 1.170 493.4 1.349 1.333 1.318 1.281 1.237 1.204 1.178 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-propylene) 2007SAT Characterization: Mn/g.mol1 = 87000, Mw/g.mol1 = 190000, 19 mol% propylene, 10 wt% crystallinity, unspecified industrial source

_______________________________________________________________________________

T/K P/MPa 0.1 10 20 50 100 150 200 Vspec/cm3g1 _______________________________________________________________________________

333.7 1.200 1.192 1.184 1.165 353.8 1.217 1.209 1.200 1.179 1.151 1.130 1.111 374.0 1.234 1.225 1.215 1.192 1.163 1.140 1.120 394.0 1.252 1.241 1.230 1.206 1.174 1.150 1.129 414.2 1.269 1.257 1.246 1.219 1.185 1.159 1.138 434.1 1.287 1.274 1.262 1.232 1.196 1.169 1.147 454.0 1.306 1.291 1.278 1.246 1.207 1.179 1.155 473.9 1.324 1.308 1.294 1.259 1.218 1.188 1.164 493.8 1.343 1.326 1.309 1.273 1.229 1.197 1.172 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 15 mol% ethylene, ρ(293.15 K) = 1.2522 g/cm3, Tg/K = 341, Tm/K = 484, Kuraray Specialities, Japan

_______________________________________________________________________________

P/MPa T/K 483.55 493.80 503.38 514.05 523.80 534.11 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8783 0.8852 0.8908 0.8964 0.9034 0.9133 10 0.8744 0.8810 0.8863 0.8918 0.8987 0.9083 20 0.8706 0.8769 0.8818 0.8874 0.8940 0.9036 30 0.8671 0.8734 0.8783 0.8837 0.8901 0.8994 40 0.8640 0.8701 0.8749 0.8801 0.8865 0.8958 50 0.8609 0.8670 0.8718 0.8768 0.8831 0.8921 60 0.8581 0.8642 0.8686 0.8736 0.8799 0.8887 70 0.8551 0.8614 0.8659 0.8707 0.8768 0.8854 80 0.8523 0.8587 0.8629 0.8679 0.8738 0.8823 90 0.8492 0.8562 0.8604 0.8651 0.8709 0.8795 100 0.8463 0.8536 0.8577 0.8624 0.8681 0.8765 110 0.8433 0.8512 0.8552 0.8600 0.8655 0.8740 120 0.8404 0.8488 0.8528 0.8574 0.8628 0.8712 130 0.8374 0.8464 0.8505 0.8550 0.8604 0.8687 140 0.8341 0.8443 0.8482 0.8526 0.8581 0.8661 150 0.8313 0.8421 0.8461 0.8505 0.8556 0.8638 160 0.8284 0.8400 0.8439 0.8483 0.8534 0.8615 170 0.8258 0.8379 0.8418 0.8461 0.8513 0.8593 180 0.8234 0.8358 0.8398 0.8440 0.8491 0.8572 190 0.8208 0.8337 0.8379 0.8419 0.8470 0.8550 200 0.8185 0.8316 0.8360 0.8400 0.8451 0.8531 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 27 mol% ethylene, ρ(293.15 K) = 1.1959 g/cm3, Tg/K = 339, Tm/K = 466, Kuraray Specialities, Japan

_______________________________________________________________________________

P/MPa T/K 466.52 477.39 487.28 497.68 508.00 518.11 528.90 539.09 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9234 0.9290 0.9340 0.9392 0.9453 0.9576 0.9702 0.9821 10 0.9189 0.9243 0.9292 0.9341 0.9402 0.9522 0.9641 0.9754 20 0.9146 0.9196 0.9244 0.9292 0.9352 0.9469 0.9584 0.9691 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

30 0.9109 0.9158 0.9204 0.9250 0.9309 0.9425 0.9534 0.9638 40 0.9075 0.9121 0.9167 0.9212 0.9271 0.9385 0.9488 0.9589 50 0.9042 0.9088 0.9132 0.9175 0.9235 0.9346 0.9445 0.9543 60 0.9010 0.9055 0.9098 0.9141 0.9200 0.9309 0.9405 0.9500 70 0.8981 0.9024 0.9066 0.9107 0.9167 0.9273 0.9366 0.9458 80 0.8951 0.8994 0.9035 0.9075 0.9136 0.9239 0.9330 0.9419 90 0.8924 0.8965 0.9006 0.9045 0.9105 0.9208 0.9295 0.9382 100 0.8897 0.8938 0.8977 0.9016 0.9076 0.9175 0.9260 0.9346 110 0.8872 0.8910 0.8949 0.8987 0.9048 0.9146 0.9228 0.9311 120 0.8846 0.8885 0.8923 0.8960 0.9020 0.9117 0.9197 0.9278 130 0.8821 0.8860 0.8897 0.8934 0.8994 0.9088 0.9166 0.9246 140 0.8798 0.8835 0.8871 0.8909 0.8968 0.9060 0.9137 0.9215 150 0.8772 0.8812 0.8847 0.8883 0.8944 0.9033 0.9109 0.9186 160 0.8746 0.8789 0.8824 0.8858 0.8919 0.9008 0.9081 0.9156 170 0.8717 0.8766 0.8801 0.8835 0.8895 0.8982 0.9055 0.9129 180 0.8685 0.8745 0.8779 0.8813 0.8873 0.8958 0.9028 0.9101 190 0.8650 0.8724 0.8757 0.8790 0.8850 0.8933 0.9003 0.9075 200 0.8616 0.8703 0.8736 0.8769 0.8828 0.8910 0.8978 0.9049 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 32 mol% ethylene, ρ(293.15 K) = 1.1810 g/cm3, Tg/K = 335, Tm/K = 457, Kuraray Specialities, Japan

_______________________________________________________________________________

P/MPa T/K 467.46 477.59 488.37 498.75 508.97 519.72 529.57 539.30 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9363 0.9420 0.9479 0.9536 0.9599 0.9673 0.9753 0.9841 10 0.9318 0.9372 0.9428 0.9483 0.9543 0.9613 0.9691 0.9775 20 0.9273 0.9325 0.9378 0.9432 0.9488 0.9555 0.9632 0.9712 30 0.9235 0.9286 0.9335 0.9388 0.9444 0.9507 0.9582 0.9660 40 0.9200 0.9249 0.9297 0.9348 0.9401 0.9464 0.9536 0.9612 50 0.9164 0.9213 0.9260 0.9308 0.9361 0.9423 0.9493 0.9566 60 0.9132 0.9179 0.9225 0.9272 0.9323 0.9383 0.9451 0.9524 70 0.9100 0.9147 0.9190 0.9238 0.9287 0.9347 0.9413 0.9483 80 0.9070 0.9115 0.9159 0.9204 0.9253 0.9311 0.9375 0.9445 90 0.9042 0.9086 0.9128 0.9173 0.9220 0.9277 0.9340 0.9407 100 0.9014 0.9057 0.9098 0.9142 0.9190 0.9245 0.9306 0.9371 110 0.8988 0.9028 0.9069 0.9112 0.9158 0.9213 0.9274 0.9337 120 0.8962 0.9002 0.9042 0.9084 0.9129 0.9183 0.9242 0.9304 130 0.8936 0.8976 0.9015 0.9057 0.9100 0.9153 0.9212 0.9273 140 0.8911 0.8951 0.8989 0.9031 0.9073 0.9125 0.9182 0.9243 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

150 0.8888 0.8926 0.8964 0.9005 0.9047 0.9097 0.9154 0.9213 160 0.8866 0.8903 0.8940 0.8980 0.9021 0.9071 0.9126 0.9184 170 0.8842 0.8880 0.8916 0.8955 0.8996 0.9045 0.9099 0.9157 180 0.8820 0.8856 0.8893 0.8931 0.8972 0.9020 0.9073 0.9130 190 0.8799 0.8835 0.8871 0.8907 0.8947 0.8996 0.9047 0.9103 200 0.8778 0.8813 0.8849 0.8885 0.8925 0.8972 0.9023 0.9079 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 38 mol% ethylene, ρ(293.15 K) = 1.1690 g/cm3, Tg/K = 332, Tm/K = 450, Kuraray Specialities, Japan

_______________________________________________________________________________

P/MPa T/K 467.82 477.75 488.37 499.04 509.02 519.75 529.66 539.20 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9530 0.9585 0.9643 0.9705 0.9769 0.9858 0.9963 1.0071 10 0.9482 0.9535 0.9590 0.9649 0.9711 0.9798 0.9899 1.0002 20 0.9434 0.9486 0.9539 0.9595 0.9656 0.9740 0.9837 0.9936 30 0.9394 0.9444 0.9495 0.9549 0.9608 0.9690 0.9784 0.9880 40 0.9355 0.9403 0.9452 0.9505 0.9563 0.9642 0.9733 0.9828 50 0.9318 0.9365 0.9413 0.9464 0.9521 0.9598 0.9686 0.9777 60 0.9283 0.9329 0.9376 0.9425 0.9481 0.9556 0.9642 0.9730 70 0.9250 0.9294 0.9339 0.9388 0.9443 0.9515 0.9600 0.9686 80 0.9218 0.9261 0.9305 0.9353 0.9406 0.9477 0.9560 0.9644 90 0.9187 0.9229 0.9272 0.9318 0.9372 0.9441 0.9521 0.9603 100 0.9156 0.9199 0.9241 0.9286 0.9337 0.9407 0.9485 0.9565 110 0.9128 0.9170 0.9211 0.9253 0.9306 0.9373 0.9449 0.9528 120 0.9100 0.9139 0.9181 0.9224 0.9275 0.9341 0.9416 0.9492 130 0.9073 0.9112 0.9152 0.9194 0.9244 0.9310 0.9383 0.9458 140 0.9047 0.9086 0.9125 0.9167 0.9216 0.9280 0.9353 0.9425 150 0.9021 0.9060 0.9099 0.9138 0.9188 0.9251 0.9322 0.9394 160 0.8998 0.9034 0.9073 0.9112 0.9160 0.9223 0.9292 0.9363 170 0.8974 0.9010 0.9047 0.9086 0.9133 0.9196 0.9263 0.9333 180 0.8951 0.8986 0.9023 0.9062 0.9108 0.9170 0.9236 0.9303 190 0.8927 0.8963 0.8999 0.9037 0.9083 0.9144 0.9209 0.9276 200 0.8906 0.8941 0.8977 0.9013 0.9058 0.9118 0.9183 0.9248 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 44 mol% ethylene, ρ(293.15 K) = 1.1359 g/cm3, Tg/K = 327, Tm/K = 439, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 450.10 460.43 471.16 481.64 492.41 502.47 512.67 523.20 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9751 0.9813 0.9879 0.9945 1.0012 1.0075 1.0141 1.0214 10 0.9702 0.9762 0.9825 0.9888 0.9952 1.0013 1.0077 1.0145 20 0.9655 0.9713 0.9774 0.9834 0.9895 0.9954 1.0015 1.0081 30 0.9613 0.9669 0.9727 0.9787 0.9845 0.9901 0.9961 1.0024 40 0.9574 0.9627 0.9684 0.9742 0.9798 0.9853 0.9910 0.9971 50 0.9535 0.9587 0.9643 0.9700 0.9752 0.9807 0.9863 0.9921 60 0.9499 0.9550 0.9603 0.9659 0.9711 0.9764 0.9817 0.9875 70 0.9465 0.9515 0.9566 0.9620 0.9671 0.9722 0.9774 0.9830 80 0.9431 0.9479 0.9530 0.9582 0.9632 0.9682 0.9733 0.9788 90 0.9400 0.9446 0.9497 0.9546 0.9596 0.9644 0.9694 0.9748 100 0.9369 0.9415 0.9464 0.9513 0.9560 0.9608 0.9656 0.9709 110 0.9339 0.9385 0.9432 0.9480 0.9526 0.9573 0.9621 0.9671 120 0.9310 0.9354 0.9401 0.9449 0.9493 0.9539 0.9585 0.9636 130 0.9282 0.9327 0.9373 0.9418 0.9462 0.9508 0.9553 0.9601 140 0.9256 0.9300 0.9344 0.9389 0.9433 0.9477 0.9521 0.9569 150 0.9231 0.9272 0.9316 0.9361 0.9403 0.9447 0.9489 0.9537 160 0.9204 0.9247 0.9290 0.9334 0.9375 0.9418 0.9459 0.9507 170 0.9180 0.9221 0.9264 0.9307 0.9347 0.9389 0.9432 0.9476 180 0.9155 0.9197 0.9238 0.9281 0.9321 0.9362 0.9403 0.9449 190 0.9128 0.9173 0.9215 0.9257 0.9295 0.9335 0.9376 0.9420 200 0.9096 0.9150 0.9191 0.9231 0.9269 0.9309 0.9349 0.9392 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 533.89 543.95 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0293 1.0378 10 1.0220 1.0301 20 1.0153 1.0230 30 1.0093 1.0166 40 1.0037 1.0108 50 0.9985 1.0054 60 0.9937 1.0003 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

70 0.9891 0.9954 80 0.9846 0.9909 90 0.9804 0.9866 100 0.9764 0.9825 110 0.9726 0.9785 120 0.9689 0.9747 130 0.9654 0.9710 140 0.9620 0.9675 150 0.9588 0.9641 160 0.9556 0.9608 170 0.9525 0.9578 180 0.9495 0.9547 190 0.9467 0.9517 200 0.9438 0.9488 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FU2 Characterization: 48 mol% ethylene, ρ(293.15 K) = 1.1243 g/cm3, Tg/K = 321, Tm/K = 436, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 447.09 456.99 467.74 478.12 488.02 493.16 503.16 519.30 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9886 0.9947 1.0010 1.0072 1.0135 1.0199 1.0264 1.0336 10 0.9833 0.9891 0.9951 1.0011 1.0071 1.0132 1.0193 1.0260 20 0.9781 0.9838 0.9895 0.9954 1.0010 1.0067 1.0127 1.0188 30 0.9736 0.9791 0.9845 0.9902 0.9957 1.0013 1.0069 1.0128 40 0.9694 0.9748 0.9800 0.9854 0.9906 0.9961 1.0014 1.0070 50 0.9654 0.9704 0.9757 0.9809 0.9860 0.9912 0.9964 1.0018 60 0.9616 0.9665 0.9715 0.9767 0.9816 0.9866 0.9916 0.9969 70 0.9579 0.9628 0.9676 0.9726 0.9773 0.9824 0.9873 0.9922 80 0.9545 0.9592 0.9638 0.9687 0.9733 0.9781 0.9829 0.9877 90 0.9511 0.9556 0.9602 0.9649 0.9695 0.9742 0.9788 0.9836 100 0.9479 0.9522 0.9568 0.9615 0.9658 0.9705 0.9749 0.9796 110 0.9447 0.9491 0.9535 0.9580 0.9623 0.9667 0.9711 0.9757 120 0.9417 0.9460 0.9504 0.9547 0.9588 0.9632 0.9676 0.9721 130 0.9388 0.9429 0.9473 0.9516 0.9556 0.9599 0.9641 0.9685 140 0.9361 0.9402 0.9443 0.9485 0.9524 0.9567 0.9608 0.9651 150 0.9333 0.9373 0.9414 0.9456 0.9494 0.9535 0.9575 0.9618 160 0.9307 0.9346 0.9386 0.9427 0.9466 0.9505 0.9545 0.9586 170 0.9281 0.9321 0.9359 0.9399 0.9437 0.9476 0.9516 0.9556 180 0.9257 0.9295 0.9334 0.9373 0.9408 0.9448 0.9486 0.9525 200 0.9209 0.9246 0.9282 0.9322 0.9355 0.9394 0.9431 0.9468 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 528.86 539.38 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0406 1.0491 10 1.0328 1.0408 20 1.0254 1.0330 30 1.0191 1.0264 40 1.0134 1.0202 50 1.0078 1.0146 60 1.0029 1.0093 70 0.9979 1.0042 80 0.9935 0.9996 90 0.9891 0.9951 100 0.9849 0.9909 110 0.9810 0.9867 120 0.9772 0.9827 130 0.9735 0.9790 140 0.9700 0.9754 150 0.9666 0.9719 160 0.9633 0.9685 170 0.9601 0.9653 180 0.9571 0.9621 200 0.9512 0.9562 _______________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2006LEE Characterization: Mn/g.mol1 = 260, Mw/g.mol1 = 280, Aldrich Chem. Co., Inc., St. Louis, MO _______________________________________________________________________________

P/MPa T/K 298.15 318.15 348.15 Vspec/cm3g1 _________________________________________________________________________________________________

0.1 1.1200 1.1038 1.0802 10 1.1243 1.1087 1.0854 15 1.1264 1.1110 1.0880 20 1.1284 1.1134 1.0905 25 1.1303 1.1157 1.0929 30 1.1323 1.1179 1.0952 35 1.1342 1.1201 1.0975 40 1.1361 1.1222 1.0998 45 1.1379 1.1243 1.1019 50 1.1397 1.1263 1.1041 _________________________________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethylene glycol) monomethyl ether 2010PFE Characterization: Mn/g.mol1 = 5000, Mw/Mn = 1.03

_______________________________________________________________________________

P/MPa T/K 346.45 351.45 356.65 361.35 366.35 371.35 376.35 381.15 386.35 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9266 0.9304 0.9338 0.9372 0.9407 0.9442 0.9480 0.9513 0.9548 10 0.9221 0.9256 0.9289 0.9322 0.9355 0.9389 0.9423 0.9456 0.9489 20 0.9178 0.9212 0.9243 0.9273 0.9306 0.9339 0.9371 0.9402 0.9435 30 0.9136 0.9167 0.9199 0.9229 0.9260 0.9291 0.9322 0.9351 0.9383 40 0.9096 0.9126 0.9156 0.9185 0.9216 0.9246 0.9275 0.9305 0.9334 50 0.9057 0.9086 0.9115 0.9144 0.9174 0.9202 0.9231 0.9259 0.9288 60 0.9021 0.9049 0.9077 0.9105 0.9134 0.9162 0.9189 0.9217 0.9244 70 0.8985 0.9013 0.9041 0.9067 0.9095 0.9123 0.9150 0.9176 0.9203 80 0.8952 0.8980 0.9005 0.9033 0.9060 0.9085 0.9112 0.9138 0.9165 90 0.8920 0.8946 0.8972 0.8999 0.9024 0.9050 0.9076 0.9100 0.9127 100 0.8889 0.8914 0.8941 0.8966 0.8991 0.9016 0.9041 0.9065 0.9091 110 0.8859 0.8884 0.8909 0.8934 0.8959 0.8983 0.9008 0.9031 0.9057 120 0.8831 0.8856 0.8880 0.8905 0.8928 0.8952 0.8976 0.8998 0.9024 130 0.8802 0.8826 0.8850 0.8874 0.8897 0.8922 0.8944 0.8966 0.8990 140 0.8775 0.8799 0.8822 0.8845 0.8869 0.8893 0.8915 0.8936 0.8959 150 0.8749 0.8772 0.8794 0.8818 0.8842 0.8863 0.8886 0.8906 0.8930 160 0.8723 0.8746 0.8768 0.8791 0.8815 0.8836 0.8858 0.8878 0.8901 170 0.8699 0.8720 0.8742 0.8765 0.8787 0.8809 0.8831 0.8851 0.8873 180 0.8674 0.8696 0.8718 0.8740 0.8762 0.8782 0.8804 0.8824 0.8844 190 0.8651 0.8671 0.8694 0.8716 0.8737 0.8758 0.8778 0.8797 0.8818 200 0.8628 0.8648 0.8670 0.8691 0.8712 0.8733 0.8754 0.8771 0.8792 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 391.65 396.75 401.65 406.95 412.05 417.05 421.95 427.05 432.45 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9585 0.9622 0.9657 0.9693 0.9730 0.9768 0.9806 0.9843 0.9885 10 0.9524 0.9559 0.9593 0.9627 0.9662 0.9697 0.9733 0.9769 0.9807 20 0.9467 0.9500 0.9533 0.9565 0.9598 0.9631 0.9666 0.9700 0.9735 30 0.9414 0.9446 0.9478 0.9508 0.9539 0.9572 0.9603 0.9636 0.9670 40 0.9364 0.9395 0.9425 0.9455 0.9485 0.9515 0.9547 0.9579 0.9611 50 0.9316 0.9346 0.9376 0.9404 0.9433 0.9462 0.9493 0.9524 0.9554 60 0.9273 0.9300 0.9329 0.9357 0.9385 0.9413 0.9442 0.9472 0.9502 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

70 0.9230 0.9258 0.9285 0.9312 0.9339 0.9366 0.9395 0.9425 0.9453 80 0.9190 0.9217 0.9243 0.9271 0.9296 0.9322 0.9350 0.9378 0.9406 90 0.9152 0.9177 0.9204 0.9230 0.9254 0.9281 0.9308 0.9335 0.9362 100 0.9115 0.9140 0.9166 0.9191 0.9215 0.9241 0.9267 0.9294 0.9320 110 0.9080 0.9105 0.9131 0.9154 0.9177 0.9203 0.9228 0.9254 0.9280 120 0.9046 0.9070 0.9095 0.9118 0.9141 0.9166 0.9189 0.9217 0.9241 130 0.9014 0.9036 0.9061 0.9085 0.9107 0.9130 0.9153 0.9179 0.9205 140 0.8982 0.9005 0.9029 0.9050 0.9073 0.9096 0.9120 0.9145 0.9168 150 0.8951 0.8974 0.8997 0.9019 0.9040 0.9064 0.9086 0.9111 0.9135 160 0.8922 0.8943 0.8967 0.8988 0.9010 0.9032 0.9055 0.9077 0.9100 170 0.8893 0.8916 0.8937 0.8958 0.8980 0.9002 0.9023 0.9047 0.9068 180 0.8866 0.8887 0.8909 0.8930 0.8950 0.8971 0.8993 0.9016 0.9037 190 0.8838 0.8859 0.8881 0.8901 0.8922 0.8942 0.8963 0.8986 0.9007 200 0.8812 0.8833 0.8853 0.8873 0.8894 0.8913 0.8934 0.8957 0.8978 _______________________________________________________________________________ Polymer (B): poly(ethylene glycol) mono-4-octylphenyl ether 2009LEE Characterization: Mn/g.mol1 = 576, Mw/g.mol1 = 606, Tokyo Kasei Organic Chemicals, Japan

_______________________________________________________________________________

P/MPa T/K 298.15 318.15 348.15 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0636 1.0475 1.0248 10 1.0684 1.0527 1.0307 15 1.0707 1.0554 1.0334 20 1.0731 1.0580 1.0362 25 1.0753 1.0604 1.0390 30 1.0775 1.0627 1.0417 35 1.0797 1.0651 1.0443 40 1.0818 1.0673 1.0468 45 1.0839 1.0695 1.0494 50 1.0860 1.0717 1.0519 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(ethyl methacrylate) 2006KI2 Characterization: Mw/g.mol1 = 154000, Tg/K = 334

_______________________________________________________________________________

P/MPa T/K 364.05 374.25 384.25 394.15 404.05 414.25 424.65 434.65 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.91057 0.91640 0.92240 0.92828 0.93429 0.94066 0.94687 0.95341 10 0.90531 0.91086 0.91650 0.92206 0.92778 0.93367 0.93952 0.94556 20 0.90034 0.90568 0.91094 0.91628 0.92168 0.92714 0.93273 0.93830 30 0.89576 0.90088 0.90586 0.91094 0.91614 0.92125 0.92660 0.93178 40 0.89136 0.89629 0.90109 0.90596 0.91117 0.91586 0.92078 0.92599 50 0.88728 0.89194 0.89659 0.90133 0.90634 0.91084 0.91559 0.92046 60 0.88344 0.88802 0.89240 0.89691 0.90180 0.90613 0.91068 0.91528 70 0.87984 0.88417 0.88851 0.89288 0.89748 0.90163 0.90612 0.91060 80 0.87640 0.88062 0.88471 0.88900 0.89345 0.89751 0.90177 0.90610 90 0.87309 0.87723 0.88120 0.88536 0.88971 0.89361 0.89772 0.90191 100 0.87005 0.87399 0.87784 0.88196 0.88608 0.88989 0.89394 0.89795 110 0.86707 0.87082 0.87459 0.87862 0.88266 0.88641 0.89027 0.89425 120 0.86433 0.86791 0.87159 0.87546 0.87942 0.88299 0.88676 0.89067 130 0.86165 0.86505 0.86866 0.87242 0.87617 0.87978 0.88340 0.88717 140 0.85917 0.86238 0.86585 0.86951 0.87328 0.87665 0.88024 0.88390 150 0.85676 0.85975 0.86315 0.86666 0.87039 0.87365 0.87714 0.88072 160 0.85434 0.85717 0.86047 0.86399 0.86758 0.87079 0.87427 0.87775 170 0.85216 0.85473 0.85791 0.86129 0.86479 0.86799 0.87139 0.87481 180 0.84999 0.85236 0.85542 0.85874 0.86216 0.86533 0.86854 0.87190 190 0.84793 0.85011 0.85304 0.85624 0.85962 0.86265 0.86590 0.86916 200 0.84579 0.84785 0.85066 0.85379 0.85713 0.86008 0.86320 0.86640 _______________________________________________________________________________ Polymer (B): poly(glycerol), hyperbranched 2006SEI Characterization: Mn/g.mol1 = 2000, Mw/g.mol1 = 3000,

_______________________________________________________________________________

P/MPa T/K 343.15 383.15 423.15 ρ/kg m3 _______________________________________________________________________________

5 1263.5 1234.9 1211.8 10 1266.7 1238.8 1216.8 20 1270.5 1244.7 1222.4 35 1274.7 1250.4 1226.2 60 1282.4 1258.8 1235.9 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): polyisobutylene 2006KI1 Characterization: Mw/g.mol1 = 1300000, Mw/Mn = 4.7, synthesized in the laboratory _______________________________________________________________________________

T/K P/MPa 0.1 40 80 120 160 200 Vspec/cm3g1 _______________________________________________________________________________

293.50 1.09472 1.07707 1.06247 1.05022 1.03958 1.03003 293.83 1.09619 1.07834 1.06362 1.05129 1.04057 1.03087 300.76 1.09929 1.08102 1.06604 1.05351 1.04260 1.03280 305.63 1.10224 1.08357 1.06837 1.05554 1.04459 1.03462 310.60 1.10531 1.08622 1.07066 1.05767 1.04643 1.03628 315.15 1.10834 1.08865 1.07280 1.05966 1.04826 1.03808 319.97 1.11130 1.09133 1.07518 1.06179 1.05032 1.03989 324.70 1.11460 1.09379 1.07745 1.06400 1.05227 1.04178 329.50 1.11760 1.09654 1.07977 1.06607 1.05412 1.04361 339.60 1.12402 1.10179 1.08441 1.07016 1.05802 1.04713 354.46 1.13354 1.10965 1.09121 1.07639 1.06378 1.05249 369.40 1.14309 1.11771 1.09834 1.08272 1.06963 1.05793 384.29 1.15302 1.12571 1.10529 1.08889 1.07526 1.06319 399.30 1.16291 1.13364 1.11218 1.09519 1.08081 1.06841 414.30 1.17307 1.14188 1.11915 1.10137 1.08648 1.07347 429.70 1.18313 1.14961 1.12581 1.10728 1.09183 1.07835 444.80 1.19320 1.15747 1.13244 1.11308 1.09713 1.08317 460.40 1.20337 1.16523 1.13895 1.11883 1.10223 1.08784 475.60 1.21383 1.17315 1.14573 1.12470 1.10761 1.09276 491.00 1.22438 1.18106 1.15223 1.13041 1.11268 1.09740 506.30 1.23569 1.18926 1.15905 1.13633 1.11796 1.10212 521.50 1.24703 1.19745 1.16571 1.14214 1.12317 1.10701 _______________________________________________________________________________ Polymer (B): poly(DL-lactic acid) 2014MA1, 2014MA2 Characterization: Mn/g.mol1 = 72000, Mw/g.mol1 = 136000, 1.4 % D-content, NatureWorks™ LLC

Tait equation parameter functions: Range of data: T/K = 343-473, P/MPa = 0.1-60 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 _______________________________________________________________________________

V(0,T/K)/cm3g1 B(T/K)/MPa 0.7666 exp(9.6372 104T ) 17352.1 exp(4.7825 103T ) _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(DL-lactic acid) 2014MA1, 2014MA2 Characterization: Mn/g.mol1 = 85000, Mw/g.mol1 = 161000, 4.2 % D-content, NatureWorks™ LLC

Tait equation parameter functions: Range of data: T/K = 343-473, P/MPa = 0.1-60 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 _______________________________________________________________________________

V(0,T/K)/cm3g1 B(T/K)/MPa 0.7447 exp(10.3241 104T ) 17245.3 exp(5.6021 103T ) _______________________________________________________________________________ Polymer (B): poly(DL-lactic acid) 2014MA1, 2014MA2 Characterization: Mn/g.mol1 = 100000, Mw/g.mol1 = 190000, 1.2 % D-content, NatureWorks™ LLC

Tait equation parameter functions: Range of data: T/K = 343-473, P/MPa = 0.1-60 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 _______________________________________________________________________________

V(0,T/K)/cm3g1 B(T/K)/MPa 0.7599 exp(9.4544 104T ) 15897.8 exp(4.1801 103T ) _______________________________________________________________________________ Polymer (B): poly(methyl acrylate) 2010PFE Characterization: Mn/g.mol1 = 5400, Mw/Mn = 1.35, synthesized in the laboratory

_______________________________________________________________________________

P/MPa T/K 345.25 350.25 355.45 369.15 365.15 370.45 375.35 379.95 385.25 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8678 0.8702 0.8731 0.8760 0.8788 0.8818 0.8845 0.8873 0.8900 10 0.8638 0.8662 0.8690 0.8717 0.8744 0.8772 0.8798 0.8824 0.8851 20 0.8600 0.8625 0.8652 0.8677 0.8703 0.8728 0.8753 0.8777 0.8805 30 0.8564 0.8588 0.8614 0.8638 0.8664 0.8687 0.8712 0.8736 0.8761 40 0.8530 0.8553 0.8578 0.8601 0.8625 0.8649 0.8671 0.8695 0.8719 50 0.8497 0.8520 0.8543 0.8567 0.8590 0.8612 0.8635 0.8657 0.8679 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

60 0.8466 0.8488 0.8511 0.8533 0.8555 0.8579 0.8598 0.8621 0.8642 70 0.8436 0.8458 0.8480 0.8503 0.8523 0.8544 0.8564 0.8586 0.8607 80 0.8407 0.8428 0.8450 0.8471 0.8492 0.8512 0.8533 0.8553 0.8573 90 0.8380 0.8400 0.8422 0.8443 0.8462 0.8482 0.8501 0.8522 0.8542 100 0.8353 0.8374 0.8395 0.8415 0.8434 0.8453 0.8473 0.8492 0.8511 110 0.8327 0.8348 0.8367 0.8388 0.8406 0.8425 0.8444 0.8462 0.8482 120 0.8303 0.8323 0.8342 0.8363 0.8380 0.8399 0.8416 0.8435 0.8453 130 0.8279 0.8298 0.8319 0.8338 0.8355 0.8374 0.8391 0.8409 0.8427 140 0.8256 0.8275 0.8294 0.8314 0.8330 0.8348 0.8365 0.8382 0.8400 150 0.8234 0.8252 0.8272 0.8290 0.8306 0.8323 0.8342 0.8358 0.8375 160 0.8212 0.8231 0.8250 0.8269 0.8283 0.8299 0.8317 0.8334 0.8351 170 0.8191 0.8209 0.8228 0.8246 0.8261 0.8277 0.8293 0.8310 0.8327 180 0.8170 0.8188 0.8206 0.8226 0.8239 0.8256 0.8272 0.8286 0.8303 190 0.8151 0.8169 0.8187 0.8204 0.8218 0.8234 0.8250 0.8266 0.8282 200 0.8132 0.8148 0.8168 0.8184 0.8197 0.8214 0.8229 0.8244 0.8261 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 390.05 394.85 400.25 405.35 410.05 414.25 419.15 424.55 429.55 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8929 0.8956 0.8983 0.9013 0.9043 0.9066 0.9098 0.9128 0.9160 10 0.8878 0.8904 0.8930 0.8958 0.8985 0.9008 0.9038 0.9066 0.9097 20 0.8830 0.8855 0.8880 0.8906 0.8931 0.8956 0.8981 0.9009 0.9038 30 0.8785 0.8809 0.8833 0.8858 0.8879 0.8904 0.8931 0.8957 0.8985 40 0.8742 0.8766 0.8790 0.8813 0.8834 0.8857 0.8883 0.8907 0.8934 50 0.8703 0.8725 0.8747 0.8769 0.8790 0.8813 0.8837 0.8862 0.8887 60 0.8665 0.8687 0.8708 0.8728 0.8750 0.8773 0.8796 0.8818 0.8842 70 0.8629 0.8650 0.8670 0.8692 0.8712 0.8733 0.8755 0.8778 0.8802 80 0.8595 0.8616 0.8635 0.8655 0.8676 0.8696 0.8717 0.8739 0.8762 90 0.8563 0.8583 0.8601 0.8620 0.8640 0.8660 0.8681 0.8702 0.8724 100 0.8531 0.8552 0.8570 0.8588 0.8607 0.8626 0.8647 0.8667 0.8689 110 0.8501 0.8521 0.8539 0.8556 0.8575 0.8594 0.8614 0.8633 0.8654 120 0.8473 0.8492 0.8508 0.8526 0.8544 0.8563 0.8582 0.8601 0.8621 130 0.8445 0.8464 0.8481 0.8497 0.8514 0.8534 0.8553 0.8571 0.8591 140 0.8418 0.8436 0.8453 0.8468 0.8488 0.8504 0.8523 0.8541 0.8560 150 0.8393 0.8411 0.8426 0.8442 0.8459 0.8477 0.8495 0.8512 0.8531 160 0.8368 0.8385 0.8400 0.8417 0.8433 0.8450 0.8469 0.8485 0.8503 170 0.8344 0.8361 0.8376 0.8390 0.8408 0.8425 0.8442 0.8458 0.8478 180 0.8321 0.8337 0.8352 0.8367 0.8382 0.8399 0.8417 0.8433 0.8451 190 0.8298 0.8314 0.8329 0.8343 0.8359 0.8375 0.8393 0.8408 0.8426 200 0.8276 0.8292 0.8306 0.8321 0.8337 0.8352 0.8370 0.8384 0.8401 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(methyl methacrylate) 2006KI2 Characterization: Mw/g.mol1 = 86000, Tg/K = 376

_______________________________________________________________________________

P/MPa T/K 388.79 393.85 398.55 403.71 410.89 413.87 418.70 433.95 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.84725 0.84986 0.85289 0.85545 0.85801 0.86072 0.86345 0.87242 10 0.84306 0.84530 0.84799 0.85043 0.85291 0.85544 0.85805 0.86647 20 0.83903 0.84095 0.84329 0.84567 0.84811 0.85045 0.85296 0.86084 30 0.83543 0.83697 0.83914 0.84131 0.84367 0.84592 0.84831 0.85585 40 0.83208 0.83338 0.83528 0.83735 0.83956 0.84172 0.84405 0.85123 50 0.82901 0.83003 0.83167 0.83353 0.83570 0.83783 0.84001 0.84697 60 0.82621 0.82697 0.82848 0.83008 0.83207 0.83416 0.83627 0.84301 70 0.82358 0.82417 0.82538 0.82683 0.82870 0.83062 0.83272 0.83919 80 0.82097 0.82146 0.82254 0.82383 0.82546 0.82733 0.82937 0.83561 90 0.81866 0.81897 0.81992 0.82096 0.82245 0.82420 0.82615 0.83216 100 0.81630 0.81661 0.81746 0.81832 0.81956 0.82120 0.82316 0.82895 110 0.81414 0.81436 0.81508 0.81580 0.81691 0.81841 0.82013 0.82583 120 0.81200 0.81224 0.81286 0.81344 0.81437 0.81571 0.81736 0.82285 130 0.80996 0.81026 0.81076 0.81121 0.81200 0.81319 0.81468 0.82004 140 0.80803 0.80825 0.80866 0.80906 0.80976 0.81073 0.81212 0.81720 150 0.80614 0.80636 0.80672 0.80707 0.80762 0.80842 0.80968 0.81465 160 0.80426 0.80446 0.80478 0.80505 0.80553 0.80628 0.80733 0.81204 170 0.80249 0.80264 0.80292 0.80314 0.80355 0.80423 0.80517 0.80956 180 0.80067 0.80088 0.80113 0.80137 0.80160 0.80218 0.80303 0.80713 190 0.79893 0.79907 0.79938 0.79957 0.79976 0.80026 0.80095 0.80481 200 0.79712 0.79733 0.79763 0.79783 0.79798 0.79837 0.79894 0.80241 _______________________________________________________________________________ Polymer (B): poly(methylphenylsiloxane) 2003PAL Characterization: Mn/g.mol1 = 32100, Mw/g.mol1 = 35300

Tait equation parameter functions: Range of data: T/K = 293-423, P/MPa = 10-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.8835 + 5.1 104 + 1.06 107 2 220.1 exp(4.01 103 ) _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(methyltolylsiloxane) 2003PAL Characterization: Mn/g.mol1 = 20140, Mw/g.mol1 = 23360

Tait equation parameter functions: Range of data: T/K = 303-373, P/MPa = 10-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.7928 + 5.0 104 + 6.49 107 2 179.7 exp(4.73 103 ) _______________________________________________________________________________ Polymer (B): poly[perfluoro(but-3-enyl vinyl ether)] 2007DL1 Characterization: CYTOP, Asahi Glass, Japan

_______________________________________________________________________________

P/MPa T/K 383.86 398.98 404.04 414.27 429.33 444.61 454.81 459.63 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.50875 0.51601 0.51928 0.52254 0.52939 0.53610 0.54212 0.54250 10 0.50430 0.51005 0.51329 0.51596 0.52213 0.52798 0.53351 0.53369 20 0.50470 0.50791 0.51013 0.51574 0.52090 0.52600 0.52609 30 0.50018 0.50326 0.50515 0.51041 0.51518 0.52003 0.51993 40 0.49926 0.50091 0.50586 0.51018 0.51478 0.51463 50 0.49590 0.49706 0.50172 0.50584 0.51027 0.50992 60 0.49322 0.49372 0.49805 0.50188 0.50609 0.50579 70 0.49468 0.49835 0.50242 0.50207 80 0.49162 0.49507 0.49902 0.49862 90 0.49205 0.49588 0.49548 100 0.48931 0.49298 0.49255 110 0.48676 0.49033 0.48982 120 0.48775 0.48721 130 0.48535 0.48490 140 0.48306 0.48262 150 0.48053 160 0.47862 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 475.10 480.25 490.80 506.22 521.53 531.61 537.07 552.35 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.54932 0.55386 0.55663 0.56419 0.57213 0.57904 0.58067 0.58913 10 0.53961 0.54359 0.54585 0.55228 0.55890 0.56469 0.56581 0.57262 20 0.53135 0.53493 0.53685 0.54253 0.54824 0.55331 0.55405 0.55998 30 0.52475 0.52805 0.52974 0.53473 0.53999 0.54460 0.54521 0.55029 40 0.51913 0.52221 0.52367 0.52828 0.53301 0.53725 0.53776 0.54247 50 0.51414 0.51715 0.51836 0.52273 0.52710 0.53107 0.53139 0.53578 60 0.50971 0.51259 0.51370 0.51777 0.52186 0.52557 0.52588 0.52999 70 0.50579 0.50861 0.50949 0.51336 0.51729 0.52078 0.52098 0.52485 80 0.50216 0.50492 0.50573 0.50938 0.51312 0.51647 0.51661 0.52029 90 0.49888 0.50150 0.50227 0.50569 0.50923 0.51253 0.51263 0.51613 100 0.49581 0.49835 0.49904 0.50242 0.50575 0.50890 0.50894 0.51229 110 0.49298 0.49547 0.49604 0.49933 0.50253 0.50557 0.50560 0.50879 120 0.49033 0.49274 0.49336 0.49639 0.49951 0.50247 0.50244 0.50558 130 0.48786 0.49018 0.49074 0.49373 0.49677 0.49959 0.49953 0.50253 140 0.48549 0.48772 0.48831 0.49119 0.49411 0.49682 0.49671 0.49968 150 0.48327 0.48537 0.48596 0.48877 0.49159 0.49423 0.49415 0.49697 160 0.48110 0.48323 0.48371 0.48648 0.48922 0.49184 0.49169 0.49448 170 0.47910 0.48119 0.48155 0.48425 0.48687 0.48946 0.48939 0.49204 180 0.47715 0.47915 0.47951 0.48216 0.48479 0.48727 0.48710 0.48971 190 0.47533 0.47720 0.47765 0.48012 0.48264 0.48511 0.48496 0.48746 200 0.47539 0.47570 0.47819 0.48060 0.48305 0.48283 0.48531 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 400-553, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0759 _______________________________________________________________________________

V(0,T/K)/cm3g1 B(T/K)/MPa 0.4258 + 4.0 105T + 4.602 107T2 1193.7 exp(7.18 103T ) _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(perfluoropropyl ether) 2012BAM Characterization: Mn/g.mol1 = 1726, branched, Krytox® GPL 102, DuPont Corporation

T/K = 298.05

P/MPa 1.2 3.3 10.8 27.5 55.0 97.7 151.1 208.2 272.9 /(kg/m3) 1850 1856 1879 1925 1973 2022 2076 2121 2164

T/K = 323.25

P/MPa 3.0 4.1 6.9 14.0 41.5 64.1 103.5 140.2 172.0 /(kg/m3) 1810 1814 1824 1851 1923 1959 2006 2043 2070

P/MPa 207.7 240.0 274.0 /(kg/m3) 2098 2121 2136

T/K = 353.25

P/MPa 1.7 2.9 10.2 27.3 54.8 81.2 110.8 139.4 174.3 /(kg/m3) 1777 1783 1815 1864 1912 1948 1983 2013 2046

P/MPa 205.0 238.7 272.1 /(kg/m3) 2067 2095 2120

T/K = 404.05

P/MPa 1.8 3.8 11.1 27.7 49.0 78.4 111.2 141.1 170.0 /(kg/m3) 1696 1711 1752 1809 1856 1905 1948 1982 2006

P/MPa 208.2 240.0 274.4 /(kg/m3) 2042 2067 2094

T/K = 473.15

P/MPa 5.1 14.7 29.1 42.2 55.9 83.3 103.8 110.8 136.1 /(kg/m3) 1566 1627 1688 1735 1771 1828 1862 1867 1907

P/MPa 172.6 201.8 237.1 238.9 268.9 /(kg/m3) 1937 1979 2010 2009 2038

T/K = 503.15

P/MPa 6.9 15.4 29.5 42.6 56.2 56.5 72.7 81.2 109.1 /(kg/m3) 1528 1585 1654 1698 1736 1740 1773 1795 1844

P/MPa 135.8 171.7 203.9 234.6 269.3 /(kg/m3) 1883 1922 1961 1989 2021

T/K = 533.05

P/MPa 31.6 41.9 43.2 55.1 55.2 83.2 111.8 111.9 137.1 /(kg/m3) 1622 1662 1663 1701 1698 1772 1821 1822 1861

P/MPa 172.2 205.3 240.0 240.1 269.4 /(kg/m3) 1909 1948 1984 1984 2012

_______________________________________________________________________________ Polymer (B): poly(propylene glycol) dimethyl ether 2010FAN Characterization: Mw/g.mol1 = 1385, Mw/Mn = 1.017

_______________________________________________________________________________

P/MPa T/K 298.15 323.15 348.15 373.15 398.15 /(g/cm3) _______________________________________________________________________________

0.10 0.9846 0.9654 0.9462 1.00 0.9852 0.9660 0.9469 0.9282 0.9093 5.00 0.9878 0.9690 0.9502 0.9318 0.9134 10.00 0.9910 0.9725 0.9541 0.9362 0.9183 15.00 0.9941 0.9759 0.9579 0.9403 0.9230 20.00 0.9971 0.9792 0.9616 0.9443 0.9274 30.00 1.0028 0.9855 0.9685 0.9519 0.9356 40.00 1.0081 0.9914 0.9750 0.9589 0.9432 45.00 1.0107 0.9942 0.9781 0.9622 0.9468 50.00 1.0133 0.9969 0.9810 0.9654 0.9503 60.00 1.0182 1.0022 0.9868 0.9717 0.9570 _______________________________________________________________________________ Polymer (B): poly(propylene glycol) dimethyl ether 2010FAN Characterization: Mw/g.mol1 = 1717, Mw/Mn = 1.022

_______________________________________________________________________________

P/MPa T/K 298.15 323.15 348.15 373.15 398.15 /(g/cm3) _______________________________________________________________________________

0.10 0.9863 0.9671 0.9480 1.00 0.9869 0.9678 0.9488 0.9301 0.9115 5.00 0.9895 0.9707 0.9520 0.9337 0.9156 10.00 0.9926 0.9742 0.9559 0.9381 0.9205 15.00 0.9957 0.9776 0.9597 0.9422 0.9251 20.00 0.9987 0.9809 0.9633 0.9462 0.9295 30.00 1.0043 0.9871 0.9702 0.9537 0.9377 40.00 1.0097 0.9930 0.9767 0.9606 0.9452 45.00 1.0123 0.9958 0.9797 0.9639 0.9487 50.00 1.0148 0.9985 0.9827 0.9671 0.9522 60.00 1.0198 1.0038 0.9884 0.9733 0.9589 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(propyl methacrylate) 2006KI2 Characterization: Mw/g.mol1 = 283000, Tg/K = 324

_______________________________________________________________________________

P/MPa T/K 364.05 373.85 383.65 393.97 404.01 414.20 424.02 434.22 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.94290 0.94900 0.95537 0.96144 0.96791 0.97469 0.98102 0.98791 10 0.93724 0.94300 0.94895 0.95473 0.96086 0.96708 0.97302 0.97949 20 0.93191 0.93741 0.94296 0.94852 0.95427 0.96007 0.96568 0.97182 30 0.92695 0.93217 0.93747 0.94275 0.94830 0.95369 0.95896 0.96480 40 0.92227 0.92728 0.93232 0.93736 0.94284 0.94777 0.95287 0.95841 50 0.91786 0.92266 0.92742 0.93246 0.93766 0.94237 0.94721 0.95251 60 0.91377 0.91837 0.92304 0.92771 0.93280 0.93725 0.94198 0.94713 70 0.90984 0.91430 0.91889 0.92331 0.92823 0.93258 0.93715 0.94193 80 0.90613 0.91047 0.91489 0.91920 0.92393 0.92811 0.93260 0.93719 90 0.90267 0.90687 0.91113 0.91537 0.91996 0.92397 0.92822 0.93267 100 0.89939 0.90341 0.90750 0.91166 0.91605 0.92002 0.92410 0.92849 110 0.89620 0.90014 0.90410 0.90805 0.91245 0.91618 0.92032 0.92449 120 0.89318 0.89701 0.90090 0.90470 0.90894 0.91262 0.91653 0.92070 130 0.89018 0.89408 0.89777 0.90156 0.90574 0.90930 0.91313 0.91705 140 0.88740 0.89111 0.89482 0.89846 0.90239 0.90605 0.90968 0.91351 150 0.88472 0.88824 0.89189 0.89552 0.89936 0.90283 0.90646 0.91018 160 0.88205 0.88557 0.88905 0.89263 0.89638 0.89974 0.90330 0.90701 170 0.87954 0.88296 0.88637 0.88985 0.89357 0.89681 0.90035 0.90390 180 0.87703 0.88036 0.88380 0.88713 0.89077 0.89391 0.89733 0.90082 190 0.87464 0.87784 0.88124 0.88450 0.88805 0.89110 0.89450 0.89789 200 0.87222 0.87540 0.87869 0.88188 0.88534 0.88851 0.89173 0.89509 _______________________________________________________________________________ Polymer (B): polystyrene 2008QIA Characterization: Mn/g.mol1 = 2140, Tg/K = 324

_______________________________________________________________________________

T/K P/MPa 10 20 30 40 Vspec/cm3g1 _______________________________________________________________________________

383.66 0.98474 0.97970 0.97505 0.97109 393.61 0.98995 0.98466 0.97954 0.97501 403.00 0.99573 0.99027 0.98499 0.98020 413.23 1.0014 0.9958 0.99035 0.98539 422.50 1.0066 1.0006 0.99502 0.98990 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

432.61 1.0123 1.0061 1.0002 0.99483 442.59 1.0178 1.0114 1.0053 0.99969 452.68 1.0239 1.0169 1.0105 1.0049 463.08 1.0296 1.0222 1.0156 1.0097 472.89 1.0353 1.0277 1.0210 1.0149 482.82 1.0413 1.0334 1.0261 1.0199 493.17 1.0472 1.0388 1.0314 1.0246 504.23 1.0539 1.0450 1.0372 1.0302 _______________________________________________________________________________ Polymer (B): polystyrene, 4-arm star polymer 2008QIA Characterization: Mn/g.mol1 = 6300, Mw/Mn = 1.02, per arm Mn/g.mol1 = 1500, Tg/K = 352, synthesized in the laboratory

_______________________________________________________________________________

T/K P/MPa 10 20 30 40 Vspec/cm3g1 _______________________________________________________________________________

378.66 0.98337 0.97751 0.97213 0.96696 388.73 0.98876 0.98276 0.97725 0.97201 398.95 0.99479 0.98860 0.98271 0.97718 409.10 1.0005 0.99381 0.98782 0.98209 419.15 1.0062 0.99912 0.99282 0.98699 429.24 1.0119 1.0048 0.99825 0.99208 439.39 1.0180 1.0104 1.0034 0.99711 449.05 1.0235 1.0156 1.0085 1.0020 459.49 1.0299 1.0214 1.0139 1.0070 469.76 1.0358 1.0270 1.0192 1.0121 480.22 1.0420 1.0327 1.0247 1.0171 489.69 1.0476 1.0381 1.0297 1.0220 500.21 1.0542 1.0440 1.0352 1.0273 510.51 1.0605 1.0498 1.0407 1.0325 520.88 1.0672 1.0562 1.0467 1.0382 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): polystyrene, 4-arm star polymer 2012CLA Characterization: Mw/g.mol1 = 520000, per arm Mw/g.mol1 = 130000 _______________________________________________________________________________

T/K P/MPa 0.1 40 80 120 160 200 Vspec/cm3g1 _______________________________________________________________________________

305.15 0.9506 0.9386 0.9276 0.9171 0.9087 0.9008 315.15 0.9533 0.9402 0.9271 0.9201 0.9072 0.9025 324.15 0.9544 0.9429 0.9309 0.9212 0.9122 0.9045 339.15 0.9588 0.9446 0.9311 0.9217 0.9128 0.9047 354.15 0.9634 0.9478 0.9355 0.9245 0.9151 0.9071 368.15 0.9669 0.9502 0.9367 0.9259 0.9157 0.9079 384.15 0.9752 0.9523 0.9378 0.9261 0.9161 0.9082 398.15 0.9833 0.9577 0.9388 0.9260 0.9153 0.9065 414.15 0.9929 0.9647 0.9440 0.9275 0.9158 0.9064 429.15 1.0011 0.9714 0.9496 0.9324 0.9184 0.9071 444.15 1.0110 0.9779 0.9557 0.9379 0.9230 0.9102 459.15 1.0199 0.9856 0.9615 0.9432 0.9274 0.9147 474.15 1.0304 0.9925 0.9678 0.9487 0.9323 0.9194 490.15 1.0389 0.9987 0.9733 0.9524 0.9363 0.9224 505.15 1.0483 1.0055 0.9788 0.9573 0.9408 0.9258 _______________________________________________________________________________ Polymer (B): polystyrene, 11-arm star polymer 2008QIA Characterization: Mn/g.mol1 = 7500, Mw/Mn = 1.03, per arm Mn/g.mol1 = 660, Tg/K = 342, synthesized in the laboratory _______________________________________________________________________________

T/K P/MPa 10 20 30 40 Vspec/cm3g1 _______________________________________________________________________________

378.65 0.99188 0.98610 0.98066 0.97557 388.85 0.99737 0.99133 0.98560 0.98033 398.54 1.0032 0.99689 0.99086 0.98532 408.95 1.0090 1.0022 0.99612 0.99031 419.08 1.0146 1.0076 1.0011 0.99525 429.04 1.0205 1.0130 1.0063 1.0001 439.43 1.0265 1.0186 1.0116 1.0052 449.02 1.0319 1.0237 1.0165 1.0098 459.13 1.0377 1.0292 1.0216 1.0147 468.92 1.0435 1.0346 1.0267 1.0195 479.30 1.0495 1.0401 1.0320 1.0244 489.50 1.0554 1.0455 1.0371 1.0294 499.99 1.0616 1.0513 1.0425 1.0345 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(styrene-co-acrylonitrile) 2005BRI Characterization: Mw/g.mol1 = 80000, 33 wt% acrylonitrile

Tait equation parameter functions: Range of data: T/K = 380-460, P/MPa = 0.1-200 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0894 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.8892 + 5.23 104  − 3.0 108  2 294.0 exp(3.86 103  ) _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 46000, Mw/g.mol1 = 89000, 11.8 mol% maleic anhydride, Tg/K = 391, Dylark 232, Acro Chemicals

_______________________________________________________________________________

P/MPa T/K 429.93 439.99 450.33 460.55 470.95 481.28 491.35 501.55 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.9734 0.9789 0.9846 0.9902 0.9959 1.0015 1.0072 1.0128 10 0.9668 0.9720 0.9774 0.9826 0.9879 0.9933 0.9985 1.0038 20 0.9606 0.9656 0.9706 0.9756 0.9806 0.9857 0.9906 0.9955 30 0.9551 0.9598 0.9644 0.9693 0.9741 0.9789 0.9836 0.9882 40 0.9498 0.9543 0.9589 0.9635 0.9680 0.9728 0.9771 0.9815 50 0.9450 0.9493 0.9537 0.9581 0.9625 0.9670 0.9713 0.9754 60 0.9405 0.9447 0.9488 0.9531 0.9573 0.9617 0.9658 0.9697 70 0.9361 0.9402 0.9442 0.9484 0.9525 0.9567 0.9606 0.9645 80 0.9320 0.9360 0.9400 0.9440 0.9479 0.9520 0.9558 0.9595 90 0.9282 0.9320 0.9359 0.9397 0.9436 0.9475 0.9511 0.9548 100 0.9245 0.9283 0.9320 0.9357 0.9395 0.9433 0.9469 0.9503 110 0.9210 0.9246 0.9283 0.9319 0.9356 0.9392 0.9428 0.9461 120 0.9176 0.9211 0.9247 0.9282 0.9318 0.9355 0.9388 0.9421 130 0.9144 0.9178 0.9213 0.9247 0.9283 0.9318 0.9350 0.9382 140 0.9114 0.9145 0.9180 0.9213 0.9248 0.9283 0.9314 0.9345 150 0.9086 0.9114 0.9148 0.9180 0.9215 0.9249 0.9279 0.9310 160 0.9059 0.9085 0.9118 0.9149 0.9183 0.9215 0.9246 0.9275 170 0.9034 0.9057 0.9087 0.9119 0.9152 0.9184 0.9213 0.9242 180 0.9011 0.9029 0.9058 0.9089 0.9121 0.9153 0.9181 0.9209 190 0.8989 0.9003 0.9030 0.9060 0.9092 0.9122 0.9151 0.9179 200 0.8967 0.8978 0.9002 0.9032 0.9063 0.9093 0.9120 0.9147 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 38000, Mw/g.mol1 = 73000, 14.5 mol% maleic anhydride, Tg/K = 403, Dylark 332, Acro Chemicals _______________________________________________________________________________

P/MPa T/K 438.23 453.03 468.23 483.07 497.88 512.98 527.76 543.63 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.95312 0.96159 0.97020 0.97900 0.98749 0.99685 1.00636 1.01598 10 0.94661 0.95461 0.96278 0.97117 0.97948 0.98793 0.99676 1.00574 20 0.94047 0.94803 0.95577 0.96382 0.97192 0.97952 0.98791 0.99625 30 0.93511 0.94234 0.94975 0.95748 0.96543 0.97267 0.98049 0.98853 40 0.93010 0.93709 0.94426 0.95172 0.95932 0.96613 0.97361 0.98087 50 0.92552 0.93227 0.93920 0.94633 0.95360 0.96026 0.96731 0.97434 60 0.92108 0.92769 0.93438 0.94137 0.94835 0.95479 0.96157 0.96835 70 0.91696 0.92343 0.92993 0.93663 0.94346 0.94965 0.95619 0.96272 80 0.91317 0.91930 0.92561 0.93221 0.93881 0.94477 0.95114 0.95738 90 0.90939 0.91538 0.92155 0.92801 0.93436 0.94026 0.94640 0.95243 100 0.90588 0.91173 0.91776 0.92398 0.93019 0.93594 0.94183 0.94766 110 0.90270 0.90821 0.91401 0.92017 0.92614 0.93175 0.93749 0.94317 120 0.89964 0.90468 0.91046 0.91646 0.92221 0.92786 0.93336 0.93898 130 0.89684 0.90147 0.90698 0.91297 0.91855 0.92405 0.92940 0.93488 140 0.89423 0.89822 0.90368 0.90952 0.91502 0.92029 0.92574 0.93086 150 0.89170 0.89524 0.90047 0.90623 0.91165 0.91686 0.92204 0.92717 160 0.88941 0.89232 0.89749 0.90306 0.90838 0.91345 0.91864 0.92349 170 0.88715 0.88970 0.89444 0.89995 0.90514 0.91016 0.91521 0.92001 180 0.88503 0.88713 0.89162 0.89714 0.90203 0.90713 0.91202 0.91675 190 0.88301 0.88478 0.88883 0.89424 0.89914 0.90410 0.90891 0.91352 200 0.88108 0.88259 0.88618 0.89154 0.89639 0.90118 0.90599 0.91042 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 27000, Mw/g.mol1 = 52000, 25.3 mol% maleic anhydride, Tg/K = 426, DSM Research, The Netherlands _______________________________________________________________________________

P/MPa T/K 433.38 443.34 453.79 463.81 474.02 484.58 494.50 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.90381 0.90882 0.91386 0.91875 0.92377 0.92873 0.93396 10 0.89850 0.90314 0.90789 0.91255 0.91728 0.92207 0.92699 20 0.89344 0.89774 0.90231 0.90672 0.91115 0.91581 0.92040 30 0.88892 0.89294 0.89719 0.90150 0.90574 0.91025 0.91469 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

40 0.88492 0.88847 0.89250 0.89665 0.90077 0.90501 0.90940 50 0.88133 0.88425 0.88818 0.89210 0.89614 0.90017 0.90438 60 0.87808 0.88035 0.88407 0.88792 0.89178 0.89574 0.89980 70 0.87505 0.87682 0.88013 0.88393 0.88762 0.89144 0.89543 80 0.87238 0.87359 0.87644 0.88011 0.88372 0.88748 0.89127 90 0.86978 0.87061 0.87307 0.87653 0.88004 0.88366 0.88744 100 0.86734 0.86786 0.86982 0.87307 0.87652 0.87999 0.88366 110 0.86506 0.86533 0.86676 0.86981 0.87317 0.87661 0.88014 120 0.86290 0.86291 0.86403 0.86666 0.86995 0.87326 0.87673 130 0.86076 0.86075 0.86139 0.86362 0.86684 0.87000 0.87352 140 0.85863 0.85853 0.85901 0.86086 0.86381 0.86699 0.87036 150 0.85664 0.85644 0.85671 0.85814 0.86093 0.86403 0.86745 160 0.85467 0.85438 0.85454 0.85567 0.85811 0.86115 0.86448 170 0.85279 0.85244 0.85243 0.85324 0.85543 0.85836 0.86164 180 0.85099 0.85063 0.85046 0.85102 0.85281 0.85562 0.85894 190 0.84910 0.84870 0.84853 0.84888 0.85036 0.85299 0.85618 200 0.84736 0.84696 0.84661 0.84688 0.84798 0.85036 0.85346 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 28000, Mw/g.mol1 = 54000, 30.9 mol% maleic anhydride, Tg/K = 439, DSM Research, The Netherlands

_______________________________________________________________________________

P/MPa T/K 449.64 459.76 470.05 480.33 490.76 501.01 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.88563 0.89054 0.89530 0.90032 0.90511 0.91030 10 0.88037 0.88501 0.88956 0.89428 0.89892 0.90383 20 0.87534 0.87973 0.88410 0.88852 0.89309 0.89770 30 0.87093 0.87511 0.87925 0.88354 0.88787 0.89238 40 0.86679 0.87074 0.87472 0.87881 0.88301 0.88742 50 0.86311 0.86668 0.87057 0.87448 0.87853 0.88271 60 0.85976 0.86287 0.86657 0.87037 0.87427 0.87833 70 0.85681 0.85936 0.86286 0.86660 0.87037 0.87430 80 0.85412 0.85597 0.85938 0.86288 0.86661 0.87041 90 0.85160 0.85304 0.85601 0.85944 0.86303 0.86679 100 0.84933 0.85019 0.85276 0.85614 0.85961 0.86332 110 0.84707 0.84771 0.84979 0.85296 0.85639 0.85997 120 0.84500 0.84528 0.84693 0.84992 0.85330 0.85683 130 0.84297 0.84311 0.84432 0.84701 0.85030 0.85373 140 0.84103 0.84099 0.84186 0.84423 0.84742 0.85078 150 0.83916 0.83900 0.83956 0.84157 0.84463 0.84795 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

160 0.83728 0.83711 0.83743 0.83909 0.84197 0.84515 170 0.83556 0.83521 0.83539 0.83667 0.83930 0.84247 180 0.83384 0.83341 0.83348 0.83440 0.83681 0.83993 190 0.83210 0.83168 0.83156 0.83229 0.83437 0.83736 200 0.83043 0.82993 0.82977 0.83025 0.83197 0.83483 _______________________________________________________________________________ Polymer (B): poly(styrene-co-maleic anhydride) 2005KIL Characterization: Mn/g.mol1 = 30000, Mw/g.mol1 = 58000, 34.7 mol% maleic anhydride, Tg/K = 449, DSM Research, The Netherlands

_______________________________________________________________________________

P/MPa T/K 460.25 470.41 480.76 491.06 501.28 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.87138 0.87623 0.88109 0.88602 0.89124 10 0.86613 0.87072 0.87531 0.87999 0.88490 20 0.86112 0.86542 0.86981 0.87428 0.87890 30 0.85668 0.86087 0.86501 0.86928 0.87372 40 0.85255 0.85653 0.86055 0.86471 0.86895 50 0.84869 0.85252 0.85639 0.86037 0.86454 60 0.84526 0.84872 0.85248 0.85633 0.86023 70 0.84203 0.84511 0.84879 0.85250 0.85636 80 0.83917 0.84175 0.84526 0.84886 0.85264 90 0.83657 0.83862 0.84191 0.84541 0.84913 100 0.83421 0.83568 0.83877 0.84214 0.84573 110 0.83193 0.83304 0.83571 0.83902 0.84257 120 0.82982 0.83053 0.83280 0.83603 0.83948 130 0.82778 0.82827 0.83012 0.83319 0.83653 140 0.82589 0.82609 0.82758 0.83043 0.83372 150 0.82407 0.82411 0.82520 0.82774 0.83096 160 0.82221 0.82212 0.82299 0.82519 0.82829 170 0.82052 0.82026 0.82087 0.82277 0.82567 180 0.81877 0.81848 0.81893 0.82048 0.82319 190 0.81707 0.81679 0.81704 0.81824 0.82074 200 0.81546 0.81506 0.81521 0.81612 0.81838 _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-2,2-bis(trifluoro-methyl)-4,5-difluoro-1,3-dioxole] 2008DLU Characterization: 13 mol% tetrafluoroethylene, Tg/K = 513, Teflon AF2400, Random Technologies, San Francisco _______________________________________________________________________________

T/K P/MPa 0.1 10 20 30 40 50 80 120 Vspec/cm3g1 _______________________________________________________________________________

515.46 0.60962 530.86 0.61813 0.60334 545.85 0.63020 0.60984 0.59384 561.43 0.64216 0.61663 0.59853 0.58673 576.08 0.65486 0.62419 0.60382 0.59045 0.58055 591.38 0.66872 0.63258 0.61011 0.59535 0.58425 0.57576 606.33 0.68364 0.64084 0.61603 0.59990 0.58794 0.57845 0.56060 620.76 0.70048 0.64989 0.62279 0.60520 0.59233 0.58215 0.56155 0.54661 635.12 0.71977 0.65951 0.62983 0.61103 0.59729 0.58644 0.56364 0.54727 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 515-635, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0781 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.6490 − 8.8 104 + 2.97 106 2 978.0 exp(1.45 102 ) _______________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-2,2-bis(trifluoro-methyl)-4,5-difluoro-1,3-dioxole 2008DLU Characterization: 35 mol% tetrafluoroethylene, Tg/K = 433, Teflon AF1600, Random Technologies, San Francisco _______________________________________________________________________________

T/K P/MPa 0.1 10 20 30 40 50 80 120 Vspec/cm3g1 _______________________________________________________________________________

439.42 0.57117 454.64 0.58246 0.57009 469.94 0.59302 0.57728 0.56497 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

485.28 0.60202 0.58446 0.57119 0.56091 494.60 0.61134 0.59105 0.57604 0.56521 0.55659 500.69 0.61170 0.59195 0.57741 0.56647 0.55760 515.39 0.62201 0.59985 0.58398 0.57223 0.56280 0.55493 520.34 0.62808 0.60361 0.58650 0.57425 0.56463 0.55659 0.53843 530.90 0.63310 0.60801 0.59068 0.57796 0.56798 0.55979 0.54113 546.16 0.64493 0.61633 0.59731 0.58374 0.57312 0.56451 0.54493 561.62 0.65675 0.62455 0.60397 0.58959 0.57826 0.56910 0.54876 0.53038 576.55 0.66967 0.63313 0.61082 0.59535 0.58353 0.57393 0.55259 0.53351 592.00 0.68299 0.64161 0.61745 0.60112 0.58871 0.57854 0.55629 0.53669 607.04 0.69873 0.65091 0.62464 0.60721 0.59390 0.58332 0.56014 0.53994 621.74 0.71654 0.66043 0.63173 0.61320 0.59920 0.58808 0.56414 0.54318 636.12 0.74124 0.67156 0.63966 0.61976 0.60489 0.59319 0.56818 0.54651 _______________________________________________________________________________

continued

_______________________________________________________________________________

T/K P/MPa 160 200 Vspec/cm3g1 _______________________________________________________________________________

592.00 0.52248 607.04 0.52524 0.51358 621.74 0.52817 0.51602 636.12 0.53105 0.51860 _______________________________________________________________________________

Tait equation parameter functions: Range of data: T/K = 435-635, P/MPa = 0.1-120 _______________________________________________________________________________

V(P/MPa, T/K) = V(0, T/K){1  C*ln[1 + (P/MPa)/B(T/K)]}

with C = 0.0760 and  = T/K  273.15 _______________________________________________________________________________

V(0,  /°C)/cm3g1 B( /°C)/MPa 0.5494 − 1.4 104 + 1.80 106 2 256.0 exp(1.13 102 ) _______________________________________________________________________________

_______________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-perfluoro(methyl vinyl ether)] 2004DLU Characterization: Mw/g.mol1 = 100000, 15-55 mol% perfluoro(methyl vinyl ether), Tg/K = 271, Dyneon Perfluoroelastomer PFE, Dyneon GmbH & Co. KG, Burgkirchen, Germany

_______________________________________________________________________________

P/MPa T/K 298.94 299.465 300.77 305.746 310.59 315.415 320.21 324.945 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.48071 0.48126 0.48153 0.48376 0.48600 0.48813 0.49042 0.49279 10 0.47712 0.47765 0.47790 0.47996 0.48204 0.48410 0.48621 0.48841 20 0.47372 0.47426 0.47449 0.47640 0.47832 0.48041 0.48235 0.48437 30 0.47071 0.47124 0.47141 0.47321 0.47505 0.47704 0.47886 0.48080 40 0.46793 0.46837 0.46866 0.47039 0.47208 0.47395 0.47571 0.47748 50 0.46540 0.46582 0.46600 0.46777 0.46943 0.47121 0.47282 0.47452 60 0.46304 0.46345 0.46370 0.46524 0.46684 0.46854 0.47016 0.47184 70 0.46084 0.46125 0.46146 0.46303 0.46453 0.46612 0.46772 0.46928 80 0.45884 0.45916 0.45941 0.46087 0.46232 0.46395 0.46540 0.46697 90 0.45695 0.45726 0.45744 0.45890 0.46032 0.46189 0.46318 0.46477 100 0.45511 0.45545 0.45566 0.45706 0.45840 0.45987 0.46128 0.46266 110 0.45351 0.45376 0.45398 0.45519 0.45661 0.45801 0.45936 0.46071 120 0.45193 0.45224 0.45239 0.45361 0.45484 0.45628 0.45757 0.45887 130 0.45055 0.45078 0.45096 0.45204 0.45321 0.45460 0.45581 0.45721 140 0.44923 0.44943 0.44957 0.45058 0.45170 0.45298 0.45426 0.45552 150 0.44791 0.44820 0.44826 0.44918 0.45019 0.45142 0.45266 0.45394 160 0.44676 0.44695 0.44702 0.44788 0.44882 0.45002 0.45110 0.45241 170 0.44563 0.44582 0.44585 0.44662 0.44742 0.44861 0.44976 0.45084 180 0.44452 0.44470 0.44477 0.44541 0.44627 0.44723 0.44832 0.44954 190 0.44343 0.44361 0.44369 0.44436 0.44506 0.44599 0.44701 0.44816 200 0.44242 0.44258 0.44266 0.44322 0.44392 0.44481 0.44567 0.44676 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 329.77 334.65 364.545 379.32 394.37 409.58 424.67 439.995 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.49520 0.49745 0.51195 0.51929 0.52691 0.53482 0.54252 0.55074 10 0.49061 0.49271 0.50598 0.51266 0.51952 0.52655 0.53330 0.54041 20 0.48639 0.48837 0.50055 0.50673 0.51302 0.51934 0.52541 0.53170 30 0.48264 0.48451 0.49599 0.50175 0.50756 0.51336 0.51890 0.52470 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued 40 0.47945 0.48103 0.49190 0.49731 0.50279 0.50820 0.51337 0.51865 50 0.47626 0.47791 0.48826 0.49338 0.49852 0.50358 0.50850 0.51349 60 0.47346 0.47505 0.48494 0.48979 0.49466 0.49952 0.50412 0.50880 70 0.47096 0.47246 0.48189 0.48655 0.49125 0.49588 0.50018 0.50469 80 0.46853 0.46997 0.47916 0.48354 0.48807 0.49252 0.49670 0.50088 90 0.46624 0.46773 0.47648 0.48076 0.48512 0.48939 0.49340 0.49743 100 0.46419 0.46555 0.47409 0.47822 0.48244 0.48652 0.49034 0.49431 110 0.46222 0.46357 0.47181 0.47581 0.47989 0.48386 0.48750 0.49127 120 0.46034 0.46153 0.46968 0.47350 0.47752 0.48124 0.48489 0.48853 130 0.45847 0.45977 0.46768 0.47141 0.47524 0.47902 0.48239 0.48589 140 0.45672 0.45802 0.46567 0.46939 0.47313 0.47665 0.48003 0.48346 150 0.45513 0.45636 0.46387 0.46750 0.47107 0.47458 0.47781 0.48110 160 0.45359 0.45478 0.46212 0.46567 0.46918 0.47257 0.47571 0.47888 170 0.45209 0.45318 0.46039 0.46382 0.46733 0.47060 0.47365 0.47682 180 0.45064 0.45179 0.45881 0.46219 0.46550 0.46875 0.47174 0.47473 190 0.44922 0.45039 0.45715 0.46048 0.46379 0.46693 0.46986 0.47291 200 0.44789 0.44897 0.45558 0.45885 0.46211 0.46517 0.46805 0.47099 _________________________________________________________________________________________________

P/MPa T/K 455.57 470.84 486.094 501.76 516.876 532.605 547.58 563.503 Vspec/cm3g1 _________________________________________________________________________________________________

0.1 0.55918 0.56803 0.57704 0.58677 0.59692 0.60765 0.61919 0.63239 10 0.54763 0.55503 0.56253 0.57050 0.57862 0.58717 0.59594 0.60571 20 0.53807 0.54446 0.55103 0.55784 0.56481 0.57220 0.57940 0.58748 30 0.53042 0.53616 0.54196 0.54819 0.55429 0.56079 0.56720 0.57425 40 0.52403 0.52922 0.53460 0.54012 0.54576 0.55170 0.55735 0.56373 50 0.51842 0.52327 0.52822 0.53327 0.53858 0.54396 0.54926 0.55514 60 0.51345 0.51811 0.52263 0.52743 0.53235 0.53729 0.54220 0.54772 70 0.50910 0.51340 0.51768 0.52218 0.52679 0.53149 0.53613 0.54126 80 0.50509 0.50925 0.51334 0.51764 0.52191 0.52631 0.53066 0.53556 90 0.50142 0.50530 0.50926 0.51334 0.51748 0.52170 0.52591 0.53049 100 0.49808 0.50178 0.50558 0.50952 0.51339 0.51749 0.52140 0.52594 110 0.49496 0.49864 0.50221 0.50600 0.50975 0.51358 0.51737 0.52174 120 0.49211 0.49556 0.49911 0.50260 0.50625 0.51003 0.51358 0.51789 130 0.48939 0.49276 0.49614 0.49960 0.50307 0.50661 0.51018 0.51428 140 0.48683 0.49005 0.49329 0.49668 0.50015 0.50351 0.50701 0.51089 150 0.48440 0.48752 0.49069 0.49400 0.49720 0.50054 0.50394 0.50768 160 0.48209 0.48515 0.48820 0.49137 0.49448 0.49781 0.50102 0.50473 170 0.47982 0.48284 0.48579 0.48898 0.49200 0.49513 0.49831 0.50202 180 0.47771 0.48076 0.48353 0.48662 0.48957 0.49270 0.49574 0.49930 190 0.47574 0.47852 0.48133 0.48431 0.48729 0.49021 0.49331 0.49668 200 0.47374 0.47647 0.47923 0.48212 0.48504 0.48780 0.49075 0.49425 _________________________________________________________________________________________________

continued

_______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 578.20 593.788 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.64774 0.66445 10 0.61667 0.62784 20 0.59638 0.60530 30 0.58195 0.58955 40 0.57068 0.57742 50 0.56140 0.56751 60 0.55359 0.55915 70 0.54677 0.55204 80 0.54072 0.54569 90 0.53548 0.54008 100 0.53064 0.53501 110 0.52626 0.53044 120 0.52224 0.52617 130 0.51841 0.52227 140 0.51490 0.51863 150 0.51161 0.51522 160 0.50851 0.51203 170 0.50566 0.50896 180 0.50287 0.50608 190 0.50014 0.50333 200 0.49764 0.50070 _______________________________________________________________________________ Polymer (B): poly(vinyl alcohol) 2007FU2 Characterization: Mw/g.mol1 = 195000, ρ(293.15 K) = 1.2906 g/cm3, Tg/K = 350, Tm/K = 493, Mowiol 56-98, Kuraray Specialities, Japan _______________________________________________________________________________

P/MPa T/K 499.16 504.17 508.69 513.70 518.52 523.47 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.8581 0.8611 0.8646 0.8679 0.8726 0.8782 10 0.8544 0.8573 0.8606 0.8640 0.8684 0.8738 20 0.8507 0.8536 0.8566 0.8601 0.8644 0.8697 30 0.8477 0.8504 0.8535 0.8568 0.8608 0.8659 40 0.8448 0.8475 0.8504 0.8535 0.8576 0.8628 50 0.8420 0.8446 0.8476 0.8505 0.8546 0.8596 60 0.8392 0.8419 0.8447 0.8476 0.8516 0.8567 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

70 0.8369 0.8392 0.8421 0.8450 0.8488 0.8539 80 0.8342 0.8367 0.8395 0.8424 0.8461 0.8512 90 0.8318 0.8343 0.8371 0.8399 0.8435 0.8486 100 0.8296 0.8319 0.8346 0.8375 0.8411 0.8460 110 0.8272 0.8296 0.8322 0.8350 0.8387 0.8436 120 0.8252 0.8274 0.8301 0.8327 0.8364 0.8410 130 0.8231 0.8253 0.8279 0.8306 0.8344 0.8388 140 0.8210 0.8232 0.8259 0.8284 0.8321 0.8366 150 0.8190 0.8212 0.8237 0.8265 0.8300 0.8345 160 0.8171 0.8194 0.8218 0.8245 0.8280 0.8324 170 0.8153 0.8175 0.8200 0.8226 0.8260 0.8304 180 0.8135 0.8156 0.8182 0.8207 0.8242 0.8285 200 0.8102 0.8123 0.8146 0.8171 0.8205 0.8248 _________________________________________________________________________________________________ Polymer (B): poly(vinylidene fluoride-co-hexafluoropropylene) 2004DLU Characterization: Mw/g.mol1 = 85000, 22.0 mol% hexafluoropropylene, Tg/K = 255, Fluorel FC-2175, Dyneon GmbH & Co. KG, Burgkirchen, Germany _________________________________________________________________________________________________

P/MPa T/K 302.885 305.956 310.925 315.605 320.35 325.19 329.995 334.935 Vspec/cm3g1 _________________________________________________________________________________________________

0.1 0.55660 0.55805 0.56011 0.56223 0.56447 0.56675 0.56887 0.57099 10 0.55358 0.55495 0.55696 0.55897 0.56106 0.56321 0.56523 0.56728 20 0.55065 0.55193 0.55394 0.55582 0.55787 0.55982 0.56176 0.56377 30 0.54808 0.54935 0.55120 0.55309 0.55497 0.55686 0.55872 0.56064 40 0.54569 0.54693 0.54870 0.55053 0.55234 0.55417 0.55590 0.55782 50 0.54343 0.54463 0.54633 0.54810 0.54981 0.55163 0.55342 0.55518 60 0.54133 0.54249 0.54418 0.54591 0.54761 0.54932 0.55098 0.55277 70 0.53940 0.54049 0.54214 0.54378 0.54537 0.54712 0.54876 0.55041 80 0.53749 0.53853 0.54017 0.54178 0.54333 0.54501 0.54663 0.54827 90 0.53565 0.53677 0.53823 0.53991 0.54140 0.54304 0.54450 0.54615 100 0.53396 0.53501 0.53643 0.53804 0.53958 0.54112 0.54264 0.54422 110 0.53221 0.53333 0.53480 0.53631 0.53782 0.53930 0.54073 0.54233 120 0.53066 0.53170 0.53316 0.53464 0.53609 0.53752 0.53900 0.54051 130 0.52918 0.53019 0.53149 0.53301 0.53444 0.53591 0.53729 0.53880 140 0.52763 0.52869 0.53001 0.53144 0.53282 0.53421 0.53564 0.53712 150 0.52615 0.52720 0.52850 0.52993 0.53128 0.53276 0.53405 0.53545 160 0.52477 0.52572 0.52714 0.52850 0.52984 0.53118 0.53256 0.53389 170 0.52349 0.52441 0.52572 0.52703 0.52845 0.52971 0.53105 0.53239 180 0.52215 0.52302 0.52438 0.52558 0.52699 0.52831 0.52959 0.53093 190 0.52081 0.52176 0.52298 0.52428 0.52562 0.52697 0.52812 0.52944 200 0.51953 0.52041 0.52171 0.52299 0.52421 0.52559 0.52680 0.52805 _________________________________________________________________________________________________

continued

_______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 349.80 364.62 379.445 394.216 409.46 424.545 439.605 454.74 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.57769 0.58435 0.59123 0.59827 0.60540 0.61294 0.62032 0.62744 10 0.57356 0.57983 0.58628 0.59284 0.59946 0.60644 0.61322 0.61975 20 0.56971 0.57563 0.58170 0.58779 0.59404 0.60059 0.60689 0.61288 30 0.56623 0.57190 0.57767 0.58355 0.58938 0.59549 0.60147 0.60710 40 0.56319 0.56863 0.57411 0.57969 0.58527 0.59106 0.59665 0.60202 50 0.56033 0.56552 0.57083 0.57611 0.58144 0.58707 0.59231 0.59740 60 0.55765 0.56272 0.56776 0.57286 0.57806 0.58335 0.58840 0.59319 70 0.55520 0.56007 0.56495 0.56984 0.57481 0.57995 0.58475 0.58938 80 0.55282 0.55756 0.56230 0.56702 0.57188 0.57678 0.58137 0.58584 90 0.55069 0.55527 0.55981 0.56448 0.56910 0.57384 0.57824 0.58255 100 0.54855 0.55302 0.55745 0.56186 0.56643 0.57104 0.57530 0.57949 110 0.54655 0.55089 0.55522 0.55956 0.56398 0.56849 0.57259 0.57661 120 0.54460 0.54892 0.55313 0.55738 0.56164 0.56598 0.56997 0.57386 130 0.54282 0.54703 0.55108 0.55524 0.55938 0.56359 0.56745 0.57123 140 0.54103 0.54515 0.54915 0.55318 0.55722 0.56137 0.56509 0.56879 150 0.53936 0.54337 0.54727 0.55125 0.55516 0.55922 0.56282 0.56635 160 0.53775 0.54162 0.54547 0.54937 0.55325 0.55710 0.56065 0.56413 170 0.53621 0.53996 0.54374 0.54756 0.55129 0.55517 0.55859 0.56194 180 0.53461 0.53835 0.54207 0.54574 0.54949 0.55313 0.55655 0.55985 190 0.53311 0.53679 0.54046 0.54401 0.54762 0.55131 0.55461 0.55780 200 0.53163 0.53527 0.53886 0.54236 0.54592 0.54949 0.55268 0.55579 _______________________________________________________________________________

continued _______________________________________________________________________________

P/MPa T/K 470.07 485.945 501.34 516.63 531.755 547.27 562.18 576.84 Vspec/cm3g1 _______________________________________________________________________________

0.1 0.63500 0.64298 0.65111 0.65955 0.66830 0.67810 0.68808 0.69928 10 0.62653 0.63368 0.64087 0.64826 0.65593 0.66419 0.67261 0.68196 20 0.61908 0.62559 0.63210 0.63869 0.64560 0.65275 0.66017 0.66837 30 0.61287 0.61886 0.62481 0.63088 0.63724 0.64374 0.65032 0.65774 40 0.60735 0.61294 0.61853 0.62416 0.63006 0.63601 0.64214 0.64887 50 0.60244 0.60776 0.61295 0.61818 0.62378 0.62926 0.63504 0.64125 60 0.59799 0.60304 0.60795 0.61296 0.61811 0.62328 0.62876 0.63461 70 0.59400 0.59874 0.60344 0.60814 0.61309 0.61796 0.62306 0.62870 80 0.59021 0.59479 0.59932 0.60382 0.60845 0.61315 0.61801 0.62331 90 0.58676 0.59116 0.59549 0.59978 0.60422 0.60870 0.61329 0.61844 _______________________________________________________________________________

continued

_______________________________________________________________________________

continued

100 0.58355 0.58779 0.59187 0.59607 0.60036 0.60465 0.60907 0.61389 110 0.58053 0.58454 0.58854 0.59262 0.59671 0.60086 0.60510 0.60977 120 0.57767 0.58160 0.58544 0.58931 0.59331 0.59728 0.60138 0.60594 130 0.57499 0.57878 0.58251 0.58619 0.59014 0.59393 0.59791 0.60227 140 0.57236 0.57607 0.57975 0.58332 0.58714 0.59076 0.59469 0.59890 150 0.56987 0.57353 0.57705 0.58056 0.58423 0.58786 0.59154 0.59570 160 0.56753 0.57107 0.57451 0.57795 0.58148 0.58494 0.58855 0.59262 170 0.56529 0.56868 0.57212 0.57539 0.57888 0.58221 0.58578 0.58972 180 0.56315 0.56646 0.56974 0.57293 0.57632 0.57966 0.58308 0.58694 190 0.56106 0.56421 0.56752 0.57058 0.57389 0.57713 0.58046 0.58424 200 0.55896 0.56207 0.56531 0.56830 0.57162 0.57463 0.57796 0.58170 _______________________________________________________________________________ Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2008SHI Characterization: Mw/g.mol1 = 55000, Aldrich Chem. Co., Inc., St. Louis, MO

_______________________________________________________________________________

P/MPa T/K 445.15 455.15 465.15 475.15 485.15 Vspec/cm3g1 _______________________________________________________________________________

10 0.7418 0.7445 0.7474 0.7503 0.7533 20 0.7397 0.7423 0.7450 0.7476 0.7506 30 0.7377 0.7400 0.7426 0.7452 0.7479 40 0.7358 0.7382 0.7405 0.7431 0.7455 50 0.7340 0.7364 0.7387 0.7410 0.7434 60 0.7325 0.7346 0.7369 0.7390 0.7413 70 0.7310 0.7330 0.7351 0.7371 0.7395 80 0.7295 0.7315 0.7335 0.7356 0.7377 90 0.7282 0.7300 0.7320 0.7340 0.7361 100 0.7269 0.7287 0.7305 0.7325 0.7343 110 0.7257 0.7274 0.7292 0.7310 0.7330 120 0.7244 0.7262 0.7279 0.7297 0.7315 130 0.7234 0.7249 0.7267 0.7284 0.7302 140 0.7224 0.7239 0.7257 0.7272 0.7290 150 0.7214 0.7229 0.7244 0.7262 0.7277 160 0.7205 0.7219 0.7234 0.7249 0.7267 170 0.7197 0.7209 0.7224 0.7239 0.7254 180 0.7187 0.7202 0.7217 0.7229 0.7244 190 0.7180 0.7195 0.7207 0.7222 0.7234 200 0.7173 0.7185 0.7200 0.7212 0.7227 _______________________________________________________________________________

_______________________________________________________________________________

Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2003KIM Characterization: −

_______________________________________________________________________________

P/MPa T/K 439.85 449.45 458.95 467.95 476.35 485.95 495.05 504.55 513.35 Vspec/cm3g1 _______________________________________________________________________________

0.1 1.0035 1.0088 1.0137 1.0191 1.0239 1.0291 1.0343 1.0396 1.0453 10 0.9989 1.0039 1.0087 1.0137 1.0183 1.0234 1.0283 1.0333 1.0385 20 0.9945 0.9993 1.0038 1.0086 1.0130 1.0178 1.0225 1.0271 1.0319 30 0.9905 0.9952 0.9996 1.0041 1.0083 1.0131 1.0176 1.0220 1.0265 40 0.9868 0.9913 0.9955 1.0000 1.0041 1.0087 1.0130 1.0172 1.0216 50 0.9832 0.9875 0.9918 0.9960 1.0001 1.0046 1.0088 1.0127 1.0169 60 0.9799 0.9840 0.9881 0.9923 0.9963 1.0005 1.0046 1.0085 1.0127 70 0.9768 0.9806 0.9845 1.0000 0.9927 0.9969 1.0009 1.0044 1.0084 80 0.9737 0.9774 0.9812 0.9852 1.0000 0.9931 0.9970 1.0006 1.0050 90 0.9709 0.9743 0.9781 0.9819 0.9857 0.9898 0.9936 0.9970 1.0008 100 0.9682 0.9713 0.9750 0.9788 0.9826 0.9864 0.9901 0.9935 0.9972 _______________________________________________________________________________

_______________________________________________________________________________ 5.2. PVT data of polymer solutions 5.2.1. Binary polymer solutions Polymer (B): poly(ε-caprolactone) 2007LIU Characterization: Mn/g.mol1 = 6100/g.mol1, Mw/g.mol1 = 14300, Tm/K = 339, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 2-propanone C3H6O 67-64-1

wB 0.05 was kept constant

T/K 323.4 323.5 323.5 323.5 323.5 323.5 323.4 348.9 348.9 P/MPa 6.9 14.0 20.9 27.8 34.8 41.8 48.5 7.3 14.2 /(g/cm3) 0.8802 0.8893 0.8981 0.9062 0.9140 0.9204 0.9266 0.8495 0.8609

T/K 348.5 348.8 348.9 348.8 348.8 373.3 373.1 373.1 373.1 P/MPa 20.9 27.9 34.8 41.7 48.5 7.1 14.1 21.0 27.9 /(g/cm3) 0.8704 0.8799 0.8889 0.8965 0.9039 0.8191 0.8324 0.8444 0.8546

T/K 373.2 373.2 373.0 398.3 398.3 398.3 398.2 398.4 398.4 P/MPa 35.1 42.0 48.6 7.5 14.1 21.2 28.0 35.0 41.8 /(g/cm3) 0.8645 0.8735 0.8817 0.7890 0.8020 0.8162 0.8285 0.8397 0.8491

T/K 398.4 P/MPa 48.6 /(g/cm3) 0.8581 Polymer (B): poly(ε-caprolactone) 2006LI2 Characterization: Mn/g.mol1 = 6100/g.mol1, Mw/g.mol1 = 14300, Tm/K = 339, Scientific Polymer Products, Inc., Ontario, NY Solvent (A): 2-propanone C3H6O 67-64-1

T/K = 323.15

wB 0.05 was kept constant P/MPa 7.74 14.39 21.52 28.07 35.24 /(g/cm3) 0.8607 0.8681 0.8764 0.8826 0.8901

T/K = 348.15

wB 0.05 was kept constant P/MPa 7.71 14.39 21.26 28.31 33.99 /(g/cm3) 0.8490 0.8596 0.8678 0.8754 0.8802

continued

_______________________________________________________________________________

continued

T/K = 373.15

wB 0.05 was kept constant P/MPa 7.63 14.86 21.16 28.13 35.31 /(g/cm3) 0.8185 0.8300 0.8392 0.8489 0.8581

continued

T/K = 398.15

wB 0.05 was kept constant P/MPa 7.91 14.70 21.61 28.55 34.97 /(g/cm3) 0.7868 0.8000 0.8132 0.8231 0.8331 Polymer (B): polyethylene 2007FU1 Characterization: Mw/g.mol1 = 4000/g.mol1, Tm/K = 372.35, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): carbon dioxide CO2 124-38-9

T/K = 453.1

P/MPa 0.0 4.1 5.5 8.0 11.0 12.0 13.0 14.0 15.0 /(g/cm3) 0.7418 0.7460 0.7444 0.7493 0.7511 0.7505 0.7510 0.7694 0.7717

Comments: Densities are measured at saturated sorption conditions.