ABSTRACT
Mechanismsofinteractionsofnitrogenoxideswithpolymersofvariousclassesareconsidered.Specialattentionispaidtoanalysisofmechanismofgenerationofstablenitrogen-containing radicalsinreactionsofnitrogenoxideswithvariousfunctionalgroupsofmacromolecules.Itis shownthatindependenceonthenatureoffunctionalgroupsformationofstableradicalsisconditionedbyproceedingofbothfree-radicalandion-radicalreactions.Applicationofreactionsofnitrogenoxidesforreceptionofspin-markedmacromoleculesandinvestigationofstructureandmolecular-dynamicpropertiesofpolymermaterialsarediscussed.
