ABSTRACT

Electrochemical capacitors (ECs) store electric charges at electrode-

electrolyte interface. The performances of ECs depend greatly on

many factors such as electrode (material derived, pore distribution,

surface functionality, and so on), electrolyte (kind of cation and

anion, solvent), and additives for the electrode and electrolyte,

interfacial conditions between electrode and electrolytic solution,

separator, and so on.1-7 As for the electrodes, activated carbons

(ACs) have been widely used as electrode material because of its

high specific surface area (1000-2000m2/g), immediate availability,

and low cost.8-12 For electrolytes, nonaqueous electrolytes con-

sisting of acetonitrile (AN) or propylene carbonate (PC) solutions

with tetraethylammonium tetrafluoroborate (Et4NBF4) are used

in commercial ECs because they permit wide operating voltage

(2.5-2.7 V).13