ABSTRACT

The activity of heterogeneous catalysts is known to be mainly

a surface property. It is therefore often possible to reduce the

amount of active components without affecting the overall activity

by increasing its surface-to-volume ratio, commonly referred to as

its dispersion [1]. In fact metal dispersion (D), namely the ratio between surface metal atoms (NS) and total metal atoms (NT), is a critical factor for several catalytic reactions and generally it has to

be as high as possible:

D = NS NT

(9.1)

Figure 9.1 Relationship between dispersion and particle size.