ABSTRACT

Gold has been attracting growing interest owing to the unique

physicochemical properties generated by nanostructures and to

its potential applications in wide areas of science and technology,

for example, surface plasmonic effects leading to better electronic

and photonic devices, catalysts for air and water purification and

for green chemistry, and biomedicines for imaging, diagnosis, and

disease treatment [1]. In particular, heterogeneous catalysis by gold

nanoparticles (NPs) and clusters has already been launched to the

stage of commercial applications. Accordingly, durability of gold NP

catalysts has become one of the most important concerns. At the

same time, the catalytic mechanism of gold NPs should be clarified

under a variety of conditions, which leads to the improvement of

catalytic performance by gold.