ABSTRACT

The present monograph is written for the purpose of forming new direction in theoretical researches and discussions on chemical physics of polymers, namely, in the branch of polymer science dealing with description of physical phenomena which determine kinetics and the mechanism of chemical reactions in polymeric non-crystalline phase. Firstly, the urgency of publishing such a monograph is stipulated by the crisis observed in traditional scientific ideas, used for description of chain reactions with participation of block polymer macromolecules. Secondly, the authors of the present monograph have clearly understood the specific features obtained by polymeric chains due to their packing in structurally organized spongy aggregates, which differentiate non-crystalline polymeric matrix (NCPM) from liquids.