ABSTRACT

Systematic quantitative investigations of radical polymerization reaction of wide range of ionogenic monomers showed that these processes were characterized by specific kinetic particularities and mechanism of proceeding in comparison with non-ionogenic monomers that first of all was connected with the ability of initial monomers to form charged particles [2, 3]. Found differences and effects were characterized by the wide spectrum of additional influences the consideration and purposeful use of which opened practically analogously broad possibilities of reactions control as in the case of ion polymerization.