ABSTRACT

The capability to control and manipulate semiconductor materials

at the nanoscale has opened up new frontiers in the promising

fields of nanoelectronics and nanophotonics. However, the strict requirements set by advanced quantum technologies keep spurring

the search for smart fabrication methods, offering the means to

precisely control the position and electronic properties of individual

nanostructures. This chapter describes an original nanofabrication

approach based on the spatially selective hydrogenation of dilute nitride semiconductors. The strong N-H interaction in dilute

nitrides turns H diffusion into a multiple trapping process, resulting

in the formation of extremely sharp heterointerfaces between H-

free and H-containing regions. This finding-combined with the

striking effects of hydrogen on the electronic, optical, electrical, and

structural properties of dilute nitrides-allows for the fabrication

of a novel class of site-controlled micro-and nanostructures, whose

properties meet a wide set of technological applications, ranging

from nanophotonics to integrated optical and electrical circuits. A

number of examples are described in the following sections, and

future directions are discussed.