ABSTRACT

Biodegradation is the chemical breakdown of organic contaminants into smaller compounds through metabolic or enzymatic processes of living organisms in the environment, primarily bacteria, yeast, and fungi. It differs from chemical and physical degradation processes (e.g., chlorine oxidation, reduction by metallic iron particles, hydrolysis, photolysis, and catalysis on reactive surfaces) in being caused by the action of living organisms. Some chemical structures are more susceptible to microbial breakdown than are others; vegetable oils, for example, will biodegrade more readily than petroleum oils, which, in turn, biodegrade more readily than polycyclic aromatic hydrocarbons (PAHs). Bioremediation* of soil and groundwater at

sites contaminated with total petroleum hydrocarbons (TPH) and benzene, toluene, ethylbenzene, and xylene (BTEX) is a well-established technology compared to sites contaminated with PAHs, chlorinated VOCs, pesticides and herbicides, and explosives, which are more difcult to biodegrade.