ABSTRACT
Polymerization and Its Application to Surfaces........................280 12.2Surface-Initiated Iniferter-Mediated Polymerization as a
Potential Technology Platform .................................................................283 12.2.1Stimuli-Responsive Polymer Brushes .........................................283 12.2.2Biofunctional Surfaces...................................................................285 12.2.3Molecularly Imprinted Polymers for Molecular
Recognition-Based Separations................................................... 287 12.3Kinetics of Surface-Initiated Iniferter-Mediated Polymerization ....... 288
12.3.1Kinetic Analysis of Termination Mechanisms during Chain Growth................................................................................. 292
12.3.2Suppressing Irreversible Termination Reactions via Preaddition of a Source of Persistent Radicals .......................... 294
12.3.3Application of a Comprehensive Kinetic Model for Simulating SI-IMP.......................................................................... 297
12.3.4Application of a Comprehensive Model for Understanding Reinitiation Ability........................................................................ 301
12.4Summary and Outlook .............................................................................303 Acknowledgments ..............................................................................................304 References .............................................................................................................305
