ABSTRACT

Up to this point, our study of quantum mechanics has concerned itself with the behaviour of particles that inhabit a Galilean spacetime. For many purposes, in atomic, molecular and condensed matter physics, this theory is quite adequate. We saw in earlier chapters, however, that our actual spacetime has a structure which is much closer to that of the Minkowski spacetime of special relativity and that more general structures must be considered when gravitational phenomena are significant. From a purely theoretical point of view, it is therefore important to formulate quantum theory in a way which is consistent with these more general spacetimes. The benefits of constructing a relativistic quantum theory actually go far beyond the aesthetic satisfaction of making our geometrical and quantummechanical reasoning compatible. For one thing, we shall discover that the relativistic theory provides a deeper understanding of spin and the distinction between fermions and bosons, which in the non-relativistic theory appear simply as facts of life that we must strive to accommodate. Also, of course, there are many situations in which relativistic effects become observable, for which nonrelativistic theory provides no explanation. The most obvious are high-energy scattering experiments, in which particles acquire kinetic energies comparable with or greater than their rest energies mc2, and the correct 4-momentum (3.34) must be used. There are, however, more subtle effects, such as the spin-orbit coupling that is essential for interpreting atomic spectra, which are also of relativistic origin.