ABSTRACT

Graphene, a single-layer hexagonal lattice of carbon atoms, has

emerged recently as a fascinating system for fundamental studies

in condensed matter physics, as well as a promising candidate

material for future applications in carbon-based nanoelectronics

and molecular devices [1, 2]. Since the honeycomb crystal structure

of graphene consists of two nonequivalent sublattices, graphene has

a unique band structure for the itinerant π -electrons near the Fermi

energy. In particular, as we have seen in Chapter 2, the motion of

electrons in graphene near the Fermi energy is well described by

the massless Dirac equation. The valence and conduction bands

conically touch at two nonequivalent Dirac points, which are called

the K and K ′ points. Because of the peculiar linear energy spectrum, graphene provides an environment for highly unconventional and

fascinating two-dimensional (2D) electronic properties [3-5] such

as the half-integer quantum Hall effect [6, 7], the absence of

backward scattering [4, 8, 9], Klein tunneling [10], and the π -

phase shift of Shubnikov-de Haas oscillations [11]. Owing to its high

electronic mobility [12] and thermal conductivity [13], graphene is

recognized as one of the key materials for realizing next-generation

electronic devices.