ABSTRACT
Table 5.1 C-F BDEs
BDEs (boldface =
recommended data; The broken bonds
references in parentheses) Methods
(boldface = (references in dissociated atom) kcal/mol kJ/mol parentheses) References
cyanogen fluoride F-CN
tetrafluoromethane F-CF3
trifluoromethane F-CHF2
difluoromethane F-CH2F
chlorofluoromethane F-CF2Cl
dichlorofluoromethane F-CFCl2
112.3±1.2
129.6±1.0
(1) 127 (2) 127.6±1.4
118.6±2.1
117±6
110± 6
469.9±5.0
542.2±4.2
531.4 533.9±5.9
496.2±8.8
489.5±25.1
460.2±25.1
AE
Recommend.
