ABSTRACT

I. Introduction and Scope ......................................................................................................... 396 II.Thermodynamic Aspects ...................................................................................................... 396

A.Expression of Potentials ................................................................................................ 396 B.Normal versus Inverted Ordering of E1/2 Potentials ..................................................... 397 C.Free Energy Factors ...................................................................................................... 398 D.Intrinsic versus Extrinsic Factors Affecting ∆E1/2 Values ............................................ 399 E.CV Images for Different ∆E1/2 Values ..........................................................................400 F.Examples of Calculated EE Processes ..........................................................................400