ABSTRACT
Water Solubility (g/m3 or mg/L at 25°C or as indicated and reported temperature dependence equations. Additional data at other temperatures designated * are compiled at the end of this section): 1850 (30°C, shake flask-interferometer, Gross & Saylor 1931) 1786 (shake flask-turbidimetric method, Stearns et al. 1947) 1402 (residue-volume method, Booth & Everson 1948) 1740 (shake flask-UV spec., Andrews & Keefer 1949) 1860 (shake flask-UV, Klevens 1950) 1790* (shake flask-UV, Bohon & Claussen 1951) 1755 (shake flask-UV, McDevit & Long 1952) 1718 (shake flask-UV, Morrison & Billett 1952) 1796 (Hayashi & Sasaki 1956; quoted, Keeley et al. 1988) 1780, 1823 (selected, calculated-molar volume, Lindenburg 1956; quoted, Horvath 1982) 1760 (Brady & Huff 1958) 1740* (shake flask-UV, measured range 0.4-45°C, Arnold et al. 1958) S/(wt.%) = 0.1806 – 0.001095·(t/°C) + 3.170 × 10-5·(t/°C)2; temp range 5-45°C (shake flask-UV, Arnold et al. 1958); or S/(wt.%) = 0.1784 – 0.0007436·(t/°C) + 1.1906 × 10-5·(t/°C)2 + 1.217 × 10-7·(t/°C)3; temp range 5-45°C (shake
flask-UV, Arnold et al. 1958) 1800* (24°C, shake flask-UV, measured range 0.8-64.5°C, Alexander 1959) 1890 (35°C, shake flask-UV spectrophotometry, Hine et al. 1962) 1742* (shake flask-UV, measured range 17-63°C, Franks et al. 1963)
2100* (20°C, polythermic method, measured range 20-79.5°C, Udovenko & Aleksandrova 1963) 1778 (calculated-group contribution, Irmann 1965; quoted, Horvath 1982) 2167 (vapor saturation-UV, Worley 1967) 1740 (21°C, extraction by nonpolar resins/elution, Chey & Calder 1972) 1765* (shake flask-GC, measured range 4-25°C, Leinonen 1972) 1830* (shake flask-UV spectroscopy, measured range 25-55°C, Bradley et al. 1973) 1755 (shake flask-GC, Polak & Lu 1973) 1755* (shake flask-GC, measured range 25-84.7°C, Price 1973) 1765 (shake flask-GC, Leinonen & Mackay 1973) 1760* (shake flask-UV, measured range 4.5-20.1°C, Brown & Wasik 1974) 1906 (shake flask-UV, Vesala 1974) 1769 (shake flask-GC, Mackay et al. 1975) 1780 (shake flask-GC, Mackay & Shiu 1975) 1740 (shake flask-GC, Price 1976) 1791* (generator column-HPLC/UV, May et al. 1978; May 1980) S/(µg/kg) = [1833 + 0.3166·(t/°C)2 – 0.6838·(t/°C)3] × 103; temp range 0.2-25.8°C (generator column-HPLC/UV,
May et al. 1978, 1980) log x = 424.544/(T/K)2 – 2955.82/(T/K) + 1.6606; temp range 0-55°C (Ueda et al. 1978) 1769 (shake flask-fluorescence spectrophotometry, Aquan-Yuen et al. 1979) 1734* (20°C, shake flask-UV, Ben-Naim & Wilf 1979) 1790* (20°C, shake flask-GC, Bittrich et al. 1979) 1820-1930 (elution chromatography-UV, Schwarz 1980) 1750 (shake flask-LSC, Banerjee et al. 1980) 1610* (vapor saturation-UV spec., measured range 5-45°C, Sanemasa et al. 1981) 1787 (shake flask-GC, Chiou et al. 1982; 1983) 1620* (vapor saturation-UV spec., measured range 5-45°C, Sanemasa et al. 1982) 1792* (generator column-HPLC/UV, May et al. 1983) 1789 (generator column-HPLC, Wasik et al. 1983) 1809 (HPLC-k′ correlation, converted from reported γW, Hafkenscheid & Tomlinson 1983a) 1617 (vapor saturation-UV spec., Sanemasa et al. 1984) 1810 (shake flask-radiometric method, Lo et al. 1986) 1695 (shake flask-GC, Keeley et al. 1988) 1650 (shake flask-GC, Coutant & Keigley 1988) 1770* (IUPAC recommended, temp range 0-70°C, Shaw 1989a) S/(g/100 g soln) = 5.5773 – 4.6067 × 10-2·(T/K) + 1.2504 × 10-4·(T/K)2 – 1.0489 × 10-7·(T/K)3; temp range 0-70°C
(summary of literature data, Shaw 1989a) 1732* (20°C, activity coefficient-GC, Cooling et al. 1992) 1840* (30°C, equilibrium flow cell-GC, measured range 30-100°C, Chen & Wagner 1994a) ln (1/x) = –6.191 + 14.03·[(T/K)/562.2]–1 – 3.511·[(T/K)/562.2]–2; temp range 303.15-373.15 K (equilibrium flow
cell-GC, Chen & Wagner 1994a) ln x = 6.191 – 14.03·(Tr/K)–1 + 3.511·(Tr/K)–2, Tr = T/Tc, the reduced temp, system temp T divided by critical
temp Tc (Chen & Wagner 1994c) 1760 (dialysis tubing equilibration-GC. Etzweiler et al. 1995) ln x = –15.544647 – 1442.4276/(T/K) – 3.283 × 10-5·(T/K)2, temp range 5-50°C (regression eq. of literature data,
Shiu & Ma 2000) ln x = –180.368 + 7524.83/(T/K) + 25.8585·ln (T/K); temp range 290-400 K (eq. derived from literature calo-
rimetric and solubility data, Tsonopoulos 1999)
Vapor Pressure (Pa at 25°C or as indicated and reported temperature dependence equations. Additional data at other temperatures designated * are compiled at the end of this section): 12654 (Hg manometer, Hovorka & Dreisbach 1934) 9960* (20°C, manometer, measured range 0-50°C, Stuckey & Saylor 1940) log (P/mmHg) = 7.12491 – 1323.06/(T/K – 41.23); temp range 0-75°C (manometer, Stuckey & Saylor 1940)
log (P/mmHg) = 6.89324 – 1203.835/(219.924 + t/°C); temp range 14.5-80.9°C (ebulliometry-manometer,
Antoine eq. from exptl. data, Willingham et al. 1945) 13332* (26.1°C, summary of literature data, Stull 1947) 11720* (23.27°C, ebulliometry, measured range 10.9-80.9°C, Forziati et al. 1949) log (P/mmHg) = 6.91210 – 1214.645/(221.205 + t/°C); temp range 10.9-80.9°C (ebulliometry-manometer,
Antoine eq. from exptl. data, Forziati et al. 1949) 12690 (interpolated-Antoine eq., Dreisbach 1955) log (P/mmHg) = 6.90565 – 1211.033/(220.79 + t/°C); temp range 0-160°C (Antoine eq. for liquid state, Dreis-
bach 1955) 23450* (39.093°C, summary of literature data, temp range 7.565-260°C, Bond & Thodos 1960) 545800* (146.85°C, ebulliometry, measured range 146.85-286.85°C, Ambrose et al. 1967) 32045* (46.85°C, summary of literature data, temp range 46.85-286.85°C, Ambrose et al.1970) 12700* (extrapolated-Antoine eq., Zwolinski & Wilhoit, 1971) log (P/mmHg) = 6.90565 – 1211.033/(220.790 + t/°C); temp range –11.6 to 103.92°C (Antoine eq., Zwolinski
& Wilhoit 1971) 12680 (extrapolated, Antoine eq., Boublik et al. 1973; 1984) log (P/mmHg) = [–0.2185 × 10254.2/(T/K)] + 9.5560; temp range –58 to –30°C (Antoine eq., Weast 1972-73) log (P/mmHg) = [–0.2185 × 8146.5/(T/K)] + 7.833714; temp range –36.7 to 290.3°C (Antoine eq., Weast
1972-73) 12339* (24.396°C, ebulliometry, measured range 19.071-32.467°C, Osborn & Scott 1978) 19933* (32.182°C, ebulliometry, measured range 32.182-115.697°C, Scott & Osborn 1979) 12640* (average, ebulliometry-bubble cap boilers, measured range 290-378 K, Ambrose 1981) 12100 (gas saturation-GC, Politzki et al. 1982) log (P/atm) = (1 – 353.214/T) × 10^(0.832632 – 6.72598 × 104·T + 6.38324 × 107·T2); T in K, temp range
280.0-562.6 K (Cox vapor pressure eq., Chao et al. 1983) 12690, 12680 (interpolated-Antoine equations, Boublik et al. 1984) log (P/kPa) = 6.01905 – 1204.637/(220.069 + t/°C); temp range 21.2-105°C (Antoine eq. from reported exptl.
