ABSTRACT

Abstract .................................................................................................................212 16.1 Introduction ................................................................................................212 16.2 Georgian Regional Natural Secondary Resources of Arsenic Industry ......214 16.3 Novel Bioactive Hybrid Coordination Compounds of Some Tertiary

Arsines with Mercury (II) Halides ..............................................................224 16.4 Coordination Compounds of Mercury (II) Nitrate with Triaryl-and

Diaryl-Alkylarsineoxides ...........................................................................227 16.5 Coordination Compounds of Some D-Metal Tetrathioarsenates (V)

with Pyridine ..............................................................................................232 16.6 Synthesis and Study of [(I-Pr)2(Et)4As2(Ph)][Co(Ncs)4] Using

X-Ray Diffraction and Ir Spectroscopy Analyses .......................................239 16.7 Stibum-Containing Bioactive Complex Compounds Based on D-Metals

and Some Nitrogen-Containing Ligands: Synthesis, Structure, and Properties ....................................................................................................244

16.8 Obtaining and Study of Arsenic-Containing Borates Based on Transformation Products of Industrial Waste .............................................262

Keywords ..............................................................................................................268 References .............................................................................................................268

Based on arsenic compounds obtained by transformation of arsenic industrial waste and natural resources, [arsenic(III) oxide, arsenic(III) chlorides, alkoxides, stibium(III) oxide], we obtained and studied new coordination compounds, “white arsenic,” hyperpure metallic arsenic and various materials with specific properties.