ABSTRACT

Petroleum exhibits a wide range of physical properties and several relationships can be made between various physical properties. Whereas the properties such as viscosity, density, boiling point, and color of petroleum may vary widely, the ultimate or elemental analysis varies (pg. 305), over a narrow range for a large number of petroleum samples. The carbon content is relatively constant, while the hydrogen and heteroatom contents are the major variants in the elemental composition of petroleum. The nitrogen, oxygen, and sulfur can be present in only trace amounts in some petroleum, which as a result consists primarily of hydrocarbons. On the other hand, a petroleum containing 9.5% heteroatoms may contain essentially no true hydrocarbon constituents insofar as the constituents contain at least one or more nitrogen, oxygen, and/ or sulfur atoms within the molecular structures. Coupled with the changes brought about to the feedstock constituents by refinery operations, it is not surprising that petroleum characterization is a monumental task.