ABSTRACT

PRZEMYS-fcAW KUBISA Center o f Molecular and Macromolecular Studies, Polish Academy of Sciences, Lodz, Poland

I. INTRODUCTION

This chapter deals with the cationic polymerization o f heterocyclic mono­ mers, i.e ., cyclic compounds containing one or more (identical or differ­ ent) heteroatoms within the ring. Polymerization proceeds by a ring-open­ ing reaction. Traditionally, this subject is discussed separately from the cationic polymerization of alkenyl monomers (vinyl polymerization) pro­ ceeding by opening of a double bond. This is justified, because both processes have their special features, making them distinctly different.