Some functional macromolecules as exciton converters. I. The problem of initial macromolecular cell selection

Abstract. The m odel o f functional m acrom olecule with undirect triplet exciton current is examined. The necessary properties o f the first link o f m odel macrom olecules are discussed. It was shown that the couple o f nonconjugated rc-electron systems could play the role o f the triplet exciton’s generator in proposed functional macrom olecule. As one variant o f such couple, the specially synthesized m olecule 4phthalimidonaphthylmethacrylate (PH T IN M A ) is proposed. Phthalimide (PH TI) and 4-succinimidonaphthylmethacrylate (SIN M A ) were exam ined as analogs o f ir-electron system from which PH T IN M A consisted of. The specially synthesized com pound m ethyltetrahydronaphtylmethacrylate(M THNM A) for im itation o f conjugation’s breakdown in one o f couple’s unit was used.