ABSTRACT

Polymers are invariably used in the processing of ceramic systems for dispersion of suspensions or controlled aggregation. While adsorption density of the polymer on the particles is an important criterion in this regard, equally important is the conformation and orientation of the adsorbed polymer. In this chapter, methods to monitor the conformation and orientation of polymers on particles in situ are described along with the effect of variables such as solids concentration that are clearly relevant in ceramic systems. Desired dispersion/aggregation of particles can be obtained in ceramic systems by first establishing the optimal conformation of the adsorbed species for the given purpose.