ABSTRACT
F 2 N C ( N 0 2 ) 3 Gas 110-175 38.5 16.0 3 • IO - 7 0.3 44.9 F 2 N C ( N 0 2 ) 3 Liquid 80-90 38.7 16.4 5 • 10~7 1.3 - F C ( N 0 2 ) 2 - Gas 170-220 43.0 16.2 1 • IO"9 1.4 47.7 N F 2 C H 3 C - Gas 170-190 40.2 16.0 3 • 10~8 4.3 49.7 ( N 0 2 ) 2 N F 2 C H 3 C - Liquid 120-140 40.2 16.0 3 • 10"8 3.0 - ( N 0 2 ) 2 N F 2 [ N F 2 ( N 0 2 ) 2 C C H 2 Liquid 130-180 39.5 15.4 2-IO"8 1.2 - - 0 ] 2 C H 2 3
lw is the ratio of the rate constants of R C ( N 0 2 ) 2 N F 2 decomposition and corresponding polynitrocompounds R C ( N 0 2 ) 3 . 2 D is the energy of dissociation of the C — N F 2 bond [10.2].
