ABSTRACT

I. Introduction 565 II. Experimental 569

A. Materials 569 B. Experimental setup 570

III. Theoretical Framework 571 A. Direct current measurements 572 B. Alternating current measurements 573

IV. Results and Discussion 579 A. Direct current results 579 B. Alternating current results 581 References 589

I. INTRODUCTION

While organic polymer films or membranes have enjoyed over two decades of commercial success, inorganic films are just making their inroads into a growing number of commer­ cial applications. Most of these inorganic membranes are ceramic mixed oxides or metallic films that typically exhibit stabilities at high temperatures and extreme pH conditions [1 ,2 ]. Organoinorganic polymer films are also advantageous when compared to their organic counterparts.