ABSTRACT

Since magnetic separation was rst described for separating iron minerals by William Fullarton, it has aroused a continuously increasing worldwide concern in areas ranging from adsorption to biotechnology [1-5]. In an effort to combat the problem of water pollution, the processes based on magnetic nanomaterials (MNMs) have been considered promising options for reducing contaminants owing to their rapid, low-cost, and highly efcient

CONTENTS

14.1 Introduction ........................................................................................................................ 265 14.2 Synthesis of Iron-Based MNMs ....................................................................................... 266

14.2.1 Simple Nanocrystals .............................................................................................. 267 14.2.1.1 Spherical Nanoparticles ......................................................................... 268 14.2.1.2 Octahedral, Dodecahedron, and Cubic Nanoparticles ..................... 268

14.2.2 Structurally Functionalized MNMs ................................................................... 270 14.2.2.1 One-Dimensional and Two-Dimensional Fe3O4 Nanomaterials...... 270 14.2.2.2 Hierarchical Superstructures ................................................................ 272

14.2.3 Chemical-Functionalized MNMs ........................................................................ 273 14.2.3.1 Monomeric Coating ................................................................................ 273 14.2.3.2 Inorganic Materials ................................................................................. 273 14.2.3.3 Polymer Stabilizers ................................................................................. 275 14.2.3.4 Other Strategies ....................................................................................... 276

14.3 Iron-Based MNMs in Water Treatment .......................................................................... 276 14.3.1 Adsorption Technologies ......................................................................................277