ABSTRACT

The SE relates to the observation that for the potential generated when a pair of electrodes (e.g., reference electrode, RE, and glass electrode) is placed in a suspension, the measured cell voltage is different from that measured when they are both placed in the separate equilibrium solution (eqs). The SE is defined here as the sum of: (1) the difference between the mixed potential of the indicator electrode (IE) in a suspension and the IE potential placed in the separated eqs; and (2) the anomalous liquid junction potential of the RE placed in the suspension. It is not the consequence of a boundary potential between the sediment and its eqs in the suspension potentiometric cells as is stated in the current definition of the SE.