ABSTRACT
P/MPa T/K 400.93 421.04 431.10 441.31 451.42 471.87 /(g/cm3) _______________________________________________________________________________
110 1.0691 1.0591 1.0538 1.0486 1.0437 1.0336 120 1.0732 1.0631 1.0580 1.0529 1.0480 1.0382 130 1.0769 1.0671 1.0622 1.0571 1.0522 1.0425 140 1.0807 1.0710 1.0660 1.0610 1.0563 1.0469 150 1.0843 1.0747 1.0700 1.0649 1.0601 1.0510 160 1.0878 1.0783 1.0736 1.0687 1.0641 1.0549 170 1.0910 1.0820 1.0774 1.0725 1.0679 1.0590 180 1.0944 1.0854 1.0809 1.0761 1.0715 1.0628 190 1.0977 1.0889 1.0844 1.0797 1.0751 1.0666 200 1.1009 1.0921 1.0878 1.0832 1.0786 1.0702 _______________________________________________________________________________ Polymer (B): polyester (hyperbranched, aliphatic) 2006SEI Characterization: Mn/g.mol1 = 1620, Mw/g.mol1 = 2100, 16 OH groups per macromolecule, hydroxyl no. = 490-520 mg KOH/g, acid no. = 5-9 mg KOH/g, Boltorn H20, Perstorp Specialty Chemicals AB, Sweden
_______________________________________________________________________________
P/MPa T/K 343.15 383.15 423.15 ρ/kg m3 _______________________________________________________________________________
5 1241.6 1214.7 1188.3 10 1245.1 1217.6 1191.5 20 1249.2 1222.3 1197.0 35 1255.6 1229.4 1205.4 60 1265.2 1240.2 1216.2 _______________________________________________________________________________
_______________________________________________________________________________
P/MPa T/K 483.55 493.80 503.38 514.05 523.80 534.11 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.8783 0.8852 0.8908 0.8964 0.9034 0.9133 10 0.8744 0.8810 0.8863 0.8918 0.8987 0.9083 20 0.8706 0.8769 0.8818 0.8874 0.8940 0.9036 30 0.8671 0.8734 0.8783 0.8837 0.8901 0.8994 40 0.8640 0.8701 0.8749 0.8801 0.8865 0.8958 50 0.8609 0.8670 0.8718 0.8768 0.8831 0.8921 60 0.8581 0.8642 0.8686 0.8736 0.8799 0.8887 70 0.8551 0.8614 0.8659 0.8707 0.8768 0.8854 80 0.8523 0.8587 0.8629 0.8679 0.8738 0.8823 90 0.8492 0.8562 0.8604 0.8651 0.8709 0.8795 100 0.8463 0.8536 0.8577 0.8624 0.8681 0.8765 110 0.8433 0.8512 0.8552 0.8600 0.8655 0.8740 120 0.8404 0.8488 0.8528 0.8574 0.8628 0.8712 130 0.8374 0.8464 0.8505 0.8550 0.8604 0.8687 140 0.8341 0.8443 0.8482 0.8526 0.8581 0.8661 150 0.8313 0.8421 0.8461 0.8505 0.8556 0.8638 160 0.8284 0.8400 0.8439 0.8483 0.8534 0.8615 170 0.8258 0.8379 0.8418 0.8461 0.8513 0.8593 180 0.8234 0.8358 0.8398 0.8440 0.8491 0.8572 190 0.8208 0.8337 0.8379 0.8419 0.8470 0.8550 200 0.8185 0.8316 0.8360 0.8400 0.8451 0.8531 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FUN Characterization: 27 mol% ethene, ρ(293.15 K) = 1.1959 g/cm3, Tg/K = 339, Tm/K = 466, Kuraray Specialities, Japan
_______________________________________________________________________________
P/MPa T/K 466.52 477.39 487.28 497.68 508.00 518.11 528.90 539.09 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9234 0.9290 0.9340 0.9392 0.9453 0.9576 0.9702 0.9821 10 0.9189 0.9243 0.9292 0.9341 0.9402 0.9522 0.9641 0.9754 20 0.9146 0.9196 0.9244 0.9292 0.9352 0.9469 0.9584 0.9691 30 0.9109 0.9158 0.9204 0.9250 0.9309 0.9425 0.9534 0.9638
continued
________________________________________________________________________
continued
40 0.9075 0.9121 0.9167 0.9212 0.9271 0.9385 0.9488 0.9589 50 0.9042 0.9088 0.9132 0.9175 0.9235 0.9346 0.9445 0.9543 60 0.9010 0.9055 0.9098 0.9141 0.9200 0.9309 0.9405 0.9500 70 0.8981 0.9024 0.9066 0.9107 0.9167 0.9273 0.9366 0.9458 80 0.8951 0.8994 0.9035 0.9075 0.9136 0.9239 0.9330 0.9419 90 0.8924 0.8965 0.9006 0.9045 0.9105 0.9208 0.9295 0.9382 100 0.8897 0.8938 0.8977 0.9016 0.9076 0.9175 0.9260 0.9346 110 0.8872 0.8910 0.8949 0.8987 0.9048 0.9146 0.9228 0.9311 120 0.8846 0.8885 0.8923 0.8960 0.9020 0.9117 0.9197 0.9278 130 0.8821 0.8860 0.8897 0.8934 0.8994 0.9088 0.9166 0.9246 140 0.8798 0.8835 0.8871 0.8909 0.8968 0.9060 0.9137 0.9215 150 0.8772 0.8812 0.8847 0.8883 0.8944 0.9033 0.9109 0.9186 160 0.8746 0.8789 0.8824 0.8858 0.8919 0.9008 0.9081 0.9156 170 0.8717 0.8766 0.8801 0.8835 0.8895 0.8982 0.9055 0.9129 180 0.8685 0.8745 0.8779 0.8813 0.8873 0.8958 0.9028 0.9101 190 0.8650 0.8724 0.8757 0.8790 0.8850 0.8933 0.9003 0.9075 200 0.8616 0.8703 0.8736 0.8769 0.8828 0.8910 0.8978 0.9049 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FUN Characterization: 32 mol% ethene, ρ(293.15 K) = 1.1810 g/cm3, Tg/K = 335, Tm/K = 457, Kuraray Specialities, Japan
_______________________________________________________________________________
P/MPa T/K 467.46 477.59 488.37 498.75 508.97 519.72 529.57 539.30 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9363 0.9420 0.9479 0.9536 0.9599 0.9673 0.9753 0.9841 10 0.9318 0.9372 0.9428 0.9483 0.9543 0.9613 0.9691 0.9775 20 0.9273 0.9325 0.9378 0.9432 0.9488 0.9555 0.9632 0.9712 30 0.9235 0.9286 0.9335 0.9388 0.9444 0.9507 0.9582 0.9660 40 0.9200 0.9249 0.9297 0.9348 0.9401 0.9464 0.9536 0.9612 50 0.9164 0.9213 0.9260 0.9308 0.9361 0.9423 0.9493 0.9566 60 0.9132 0.9179 0.9225 0.9272 0.9323 0.9383 0.9451 0.9524 70 0.9100 0.9147 0.9190 0.9238 0.9287 0.9347 0.9413 0.9483 80 0.9070 0.9115 0.9159 0.9204 0.9253 0.9311 0.9375 0.9445 90 0.9042 0.9086 0.9128 0.9173 0.9220 0.9277 0.9340 0.9407 100 0.9014 0.9057 0.9098 0.9142 0.9190 0.9245 0.9306 0.9371 110 0.8988 0.9028 0.9069 0.9112 0.9158 0.9213 0.9274 0.9337 120 0.8962 0.9002 0.9042 0.9084 0.9129 0.9183 0.9242 0.9304 130 0.8936 0.8976 0.9015 0.9057 0.9100 0.9153 0.9212 0.9273 140 0.8911 0.8951 0.8989 0.9031 0.9073 0.9125 0.9182 0.9243 150 0.8888 0.8926 0.8964 0.9005 0.9047 0.9097 0.9154 0.9213
continued
________________________________________________________________________
continued
160 0.8866 0.8903 0.8940 0.8980 0.9021 0.9071 0.9126 0.9184 170 0.8842 0.8880 0.8916 0.8955 0.8996 0.9045 0.9099 0.9157 180 0.8820 0.8856 0.8893 0.8931 0.8972 0.9020 0.9073 0.9130 190 0.8799 0.8835 0.8871 0.8907 0.8947 0.8996 0.9047 0.9103 200 0.8778 0.8813 0.8849 0.8885 0.8925 0.8972 0.9023 0.9079 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FUN Characterization: 38 mol% ethene, ρ(293.15 K) = 1.1690 g/cm3, Tg/K = 332, Tm/K = 450, Kuraray Specialities, Japan
_______________________________________________________________________________
P/MPa T/K 467.82 477.75 488.37 499.04 509.02 519.75 529.66 539.20 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9530 0.9585 0.9643 0.9705 0.9769 0.9858 0.9963 1.0071 10 0.9482 0.9535 0.9590 0.9649 0.9711 0.9798 0.9899 1.0002 20 0.9434 0.9486 0.9539 0.9595 0.9656 0.9740 0.9837 0.9936 30 0.9394 0.9444 0.9495 0.9549 0.9608 0.9690 0.9784 0.9880 40 0.9355 0.9403 0.9452 0.9505 0.9563 0.9642 0.9733 0.9828 50 0.9318 0.9365 0.9413 0.9464 0.9521 0.9598 0.9686 0.9777 60 0.9283 0.9329 0.9376 0.9425 0.9481 0.9556 0.9642 0.9730 70 0.9250 0.9294 0.9339 0.9388 0.9443 0.9515 0.9600 0.9686 80 0.9218 0.9261 0.9305 0.9353 0.9406 0.9477 0.9560 0.9644 90 0.9187 0.9229 0.9272 0.9318 0.9372 0.9441 0.9521 0.9603 100 0.9156 0.9199 0.9241 0.9286 0.9337 0.9407 0.9485 0.9565 110 0.9128 0.9170 0.9211 0.9253 0.9306 0.9373 0.9449 0.9528 120 0.9100 0.9139 0.9181 0.9224 0.9275 0.9341 0.9416 0.9492 130 0.9073 0.9112 0.9152 0.9194 0.9244 0.9310 0.9383 0.9458 140 0.9047 0.9086 0.9125 0.9167 0.9216 0.9280 0.9353 0.9425 150 0.9021 0.9060 0.9099 0.9138 0.9188 0.9251 0.9322 0.9394 160 0.8998 0.9034 0.9073 0.9112 0.9160 0.9223 0.9292 0.9363 170 0.8974 0.9010 0.9047 0.9086 0.9133 0.9196 0.9263 0.9333 180 0.8951 0.8986 0.9023 0.9062 0.9108 0.9170 0.9236 0.9303 190 0.8927 0.8963 0.8999 0.9037 0.9083 0.9144 0.9209 0.9276 200 0.8906 0.8941 0.8977 0.9013 0.9058 0.9118 0.9183 0.9248 _______________________________________________________________________________
_______________________________________________________________________________
P/MPa T/K 450.10 460.43 471.16 481.64 492.41 502.47 512.67 523.20 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9751 0.9813 0.9879 0.9945 1.0012 1.0075 1.0141 1.0214 10 0.9702 0.9762 0.9825 0.9888 0.9952 1.0013 1.0077 1.0145 20 0.9655 0.9713 0.9774 0.9834 0.9895 0.9954 1.0015 1.0081 30 0.9613 0.9669 0.9727 0.9787 0.9845 0.9901 0.9961 1.0024 40 0.9574 0.9627 0.9684 0.9742 0.9798 0.9853 0.9910 0.9971 50 0.9535 0.9587 0.9643 0.9700 0.9752 0.9807 0.9863 0.9921 60 0.9499 0.9550 0.9603 0.9659 0.9711 0.9764 0.9817 0.9875 70 0.9465 0.9515 0.9566 0.9620 0.9671 0.9722 0.9774 0.9830 80 0.9431 0.9479 0.9530 0.9582 0.9632 0.9682 0.9733 0.9788 90 0.9400 0.9446 0.9497 0.9546 0.9596 0.9644 0.9694 0.9748 100 0.9369 0.9415 0.9464 0.9513 0.9560 0.9608 0.9656 0.9709 110 0.9339 0.9385 0.9432 0.9480 0.9526 0.9573 0.9621 0.9671 120 0.9310 0.9354 0.9401 0.9449 0.9493 0.9539 0.9585 0.9636 130 0.9282 0.9327 0.9373 0.9418 0.9462 0.9508 0.9553 0.9601 140 0.9256 0.9300 0.9344 0.9389 0.9433 0.9477 0.9521 0.9569 150 0.9231 0.9272 0.9316 0.9361 0.9403 0.9447 0.9489 0.9537 160 0.9204 0.9247 0.9290 0.9334 0.9375 0.9418 0.9459 0.9507 170 0.9180 0.9221 0.9264 0.9307 0.9347 0.9389 0.9432 0.9476 180 0.9155 0.9197 0.9238 0.9281 0.9321 0.9362 0.9403 0.9449 190 0.9128 0.9173 0.9215 0.9257 0.9295 0.9335 0.9376 0.9420 200 0.9096 0.9150 0.9191 0.9231 0.9269 0.9309 0.9349 0.9392 _______________________________________________________________________________
continued _______________________________________________________________________________
P/MPa T/K 533.89 543.95 Vspec/cm3g1 _______________________________________________________________________________
0.1 1.0293 1.0378 10 1.0220 1.0301 20 1.0153 1.0230 30 1.0093 1.0166 40 1.0037 1.0108 50 0.9985 1.0054 60 0.9937 1.0003 70 0.9891 0.9954 continued
________________________________________________________________________
continued
80 0.9846 0.9909 90 0.9804 0.9866 100 0.9764 0.9825 110 0.9726 0.9785 120 0.9689 0.9747 130 0.9654 0.9710 140 0.9620 0.9675 150 0.9588 0.9641 160 0.9556 0.9608 170 0.9525 0.9578 180 0.9495 0.9547 190 0.9467 0.9517 200 0.9438 0.9488 _______________________________________________________________________________ Polymer (B): poly(ethylene-co-vinyl alcohol) 2007FUN Characterization: 48 mol% ethene, ρ(293.15 K) = 1.1243 g/cm3, Tg/K = 321, Tm/K = 436, Kuraray Specialities, Japan _______________________________________________________________________________
P/MPa T/K 447.09 456.99 467.74 478.12 488.02 493.16 503.16 519.30 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9886 0.9947 1.0010 1.0072 1.0135 1.0199 1.0264 1.0336 10 0.9833 0.9891 0.9951 1.0011 1.0071 1.0132 1.0193 1.0260 20 0.9781 0.9838 0.9895 0.9954 1.0010 1.0067 1.0127 1.0188 30 0.9736 0.9791 0.9845 0.9902 0.9957 1.0013 1.0069 1.0128 40 0.9694 0.9748 0.9800 0.9854 0.9906 0.9961 1.0014 1.0070 50 0.9654 0.9704 0.9757 0.9809 0.9860 0.9912 0.9964 1.0018 60 0.9616 0.9665 0.9715 0.9767 0.9816 0.9866 0.9916 0.9969 70 0.9579 0.9628 0.9676 0.9726 0.9773 0.9824 0.9873 0.9922 80 0.9545 0.9592 0.9638 0.9687 0.9733 0.9781 0.9829 0.9877 90 0.9511 0.9556 0.9602 0.9649 0.9695 0.9742 0.9788 0.9836 100 0.9479 0.9522 0.9568 0.9615 0.9658 0.9705 0.9749 0.9796 110 0.9447 0.9491 0.9535 0.9580 0.9623 0.9667 0.9711 0.9757 120 0.9417 0.9460 0.9504 0.9547 0.9588 0.9632 0.9676 0.9721 130 0.9388 0.9429 0.9473 0.9516 0.9556 0.9599 0.9641 0.9685 140 0.9361 0.9402 0.9443 0.9485 0.9524 0.9567 0.9608 0.9651 150 0.9333 0.9373 0.9414 0.9456 0.9494 0.9535 0.9575 0.9618 160 0.9307 0.9346 0.9386 0.9427 0.9466 0.9505 0.9545 0.9586 170 0.9281 0.9321 0.9359 0.9399 0.9437 0.9476 0.9516 0.9556 180 0.9257 0.9295 0.9334 0.9373 0.9408 0.9448 0.9486 0.9525 190 0.9232 0.9270 0.9308 0.9346 0.9382 0.9421 0.9458 0.9498 200 0.9209 0.9246 0.9282 0.9322 0.9355 0.9394 0.9431 0.9468 _______________________________________________________________________________
continued
________________________________________________________________________
continued _______________________________________________________________________________
P/MPa T/K 528.86 539.38 Vspec/cm3g1 _______________________________________________________________________________
0.1 1.0406 1.0491 10 1.0328 1.0408 20 1.0254 1.0330 30 1.0191 1.0264 40 1.0134 1.0202 50 1.0078 1.0146 60 1.0029 1.0093 70 0.9979 1.0042 80 0.9935 0.9996 90 0.9891 0.9951 100 0.9849 0.9909 110 0.9810 0.9867 120 0.9772 0.9827 130 0.9735 0.9790 140 0.9700 0.9754 150 0.9666 0.9719 160 0.9633 0.9685 170 0.9601 0.9653 180 0.9571 0.9621 190 0.9541 0.9590 200 0.9512 0.9562 _______________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2006LEE Characterization: Mn/g.mol1 = 260, Mw/g.mol1 = 280 _______________________________________________________________________________
P/MPa T/K 298.15 318.15 348.15 Vspec/cm3g1 _______________________________________________________________________________
0.1 1.1200 1.1038 1.0802 10 1.1243 1.1087 1.0854 15 1.1264 1.1110 1.0880 20 1.1284 1.1134 1.0905 25 1.1303 1.1157 1.0929 30 1.1323 1.1179 1.0952 35 1.1342 1.1201 1.0975 40 1.1361 1.1222 1.0998 45 1.1379 1.1243 1.1019 50 1.1397 1.1263 1.1041 _______________________________________________________________________________
P/MPa = 0.1
T/K 283.16 285.65 288.15 290.65 293.15 295.65 298.14 300.65 303.15 /(g/cm3) 1.13465 1.13254 1.13045 1.12840 1.12635 1.12430 1.12224 1.12018 1.11813
T/K 305.65 308.15 310.65 313.15 315.65 318.15 320.64 323.15 325.65 /(g/cm3) 1.11607 1.11402 1.11197 1.10992 1.10788 1.10583 1.10379 1.10175 1.09971
T/K 328.15 330.65 333.15 335.65 338.15 340.65 343.15 345.64 348.15 /(g/cm3) 1.09767 1.09564 1.09360 1.09157 1.08954 1.08751 1.08548 1.08345 1.08142
_______________________________________________________________________________
P/MPa T/K 298.15 318.15 348.15 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9223 0.9371 0.9596 10 0.9181 0.9321 0.9540 15 0.9159 0.9298 0.9512 20 0.9140 0.9276 0.9485 25 0.9120 0.9253 0.9459 30 0.9101 0.9233 0.9434 35 0.9083 0.9212 0.9410 40 0.9065 0.9192 0.9386 45 0.9046 0.9173 0.9363 50 0.9029 0.9153 0.9342 _______________________________________________________________________________
_______________________________________________________________________________
P/MPa T/K 343.15 383.15 423.15 ρ/kg m3 _______________________________________________________________________________
5 1263.5 1234.9 1211.8 10 1266.7 1238.8 1216.8 20 1270.5 1244.7 1222.4 35 1274.7 1250.4 1226.2 60 1282.4 1258.8 1235.9 _______________________________________________________________________________ Polymer (B): poly(propylene glycol) 2004BOL Characterization: Mn/g.mol1 = 425, Mw/Mn = 1.086, Merck, Darmstadt, Germany
_______________________________________________________________________________
P/MPa T/K 293.15 303.15 313.15 323.15 333.15 343.15 353.15 363.15 373.15 Vspez/cm3g1 _______________________________________________________________________________
0.1 0.9804 0.9881 0.9950 1.0040 1.0121 1.0215 1.0309 1.0395 1.0493 10 0.9747 0.9823 0.9891 0.9970 1.0050 1.0142 1.0225 1.0320 1.0406 20 0.9699 0.9766 0.9843 0.9911 0.9990 1.0070 1.0152 1.0235 1.0331 30 0.9653 0.9718 0.9785 0.9852 0.9921 1.0000 1.0081 1.0163 1.0246 40 0.9606 0.9671 0.9737 0.9794 0.9872 0.9940 1.0020 1.0101 1.0183 50 0.9560 0.9625 0.9690 0.9747 0.9814 0.9881 0.9960 1.0040 1.0121 60 0.9524 0.9588 0.9643 0.9699 0.9766 0.9833 0.9911 0.9990 1.0060 70 0.9488 0.9551 0.9606 0.9662 0.9728 0.9794 0.9862 0.9940 1.0010 80 0.9452 0.9515 0.9569 0.9625 0.9690 0.9756 0.9823 0.9891 0.9960 90 0.9425 0.9479 0.9533 0.9588 0.9653 0.9718 0.9785 0.9852 0.9921 100 0.9398 0.9452 0.9506 0.9560 0.9615 0.9681 0.9747 0.9814 0.9881 _______________________________________________________________________________
_______________________________________________________________________________
P/MPa T/K 298.15 318.15 348.15 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.9969 1.0130 1.0384 10 0.9910 1.0062 1.0302 15 0.9881 1.0030 1.0264 20 0.9853 0.9999 1.0227 25 0.9827 0.9969 1.0193 30 0.9801 0.9941 1.0158 35 0.9775 0.9913 1.0127 40 0.9752 0.9885 1.0095 45 0.9728 0.9861 1.0064 50 0.9705 0.9836 1.0036 _______________________________________________________________________________ Polymer (B): poly(vinyl alcohol) 2007FUN Characterization: Mw/g.mol1 = 195000, ρ(293.15 K) = 1.2906 g/cm3, Tg/K = 350, Tm/K = 493, Mowiol 56-98, Kuraray Specialities, Japan
_______________________________________________________________________________
P/MPa T/K 499.16 504.17 508.69 513.70 518.52 523.47 Vspec/cm3g1 _______________________________________________________________________________
0.1 0.8581 0.8611 0.8646 0.8679 0.8726 0.8782 10 0.8544 0.8573 0.8606 0.8640 0.8684 0.8738 20 0.8507 0.8536 0.8566 0.8601 0.8644 0.8697 30 0.8477 0.8504 0.8535 0.8568 0.8608 0.8659 40 0.8448 0.8475 0.8504 0.8535 0.8576 0.8628 50 0.8420 0.8446 0.8476 0.8505 0.8546 0.8596 60 0.8392 0.8419 0.8447 0.8476 0.8516 0.8567 70 0.8369 0.8392 0.8421 0.8450 0.8488 0.8539 80 0.8342 0.8367 0.8395 0.8424 0.8461 0.8512 90 0.8318 0.8343 0.8371 0.8399 0.8435 0.8486 100 0.8296 0.8319 0.8346 0.8375 0.8411 0.8460 110 0.8272 0.8296 0.8322 0.8350 0.8387 0.8436 120 0.8252 0.8274 0.8301 0.8327 0.8364 0.8410
continued
________________________________________________________________________
continued 130 0.8231 0.8253 0.8279 0.8306 0.8344 0.8388 140 0.8210 0.8232 0.8259 0.8284 0.8321 0.8366 150 0.8190 0.8212 0.8237 0.8265 0.8300 0.8345 160 0.8171 0.8194 0.8218 0.8245 0.8280 0.8324 170 0.8153 0.8175 0.8200 0.8226 0.8260 0.8304 180 0.8135 0.8156 0.8182 0.8207 0.8242 0.8285 190 0.8118 0.8139 0.8162 0.8188 0.8222 0.8265 200 0.8102 0.8123 0.8146 0.8171 0.8205 0.8248 _______________________________________________________________________________ Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2008SHI Characterization: Mw/g.mol1 = 55000, Aldrich Chem. Co., Inc., St. Louis, MO
_______________________________________________________________________________
P/MPa T/K 445.15 455.15 465.15 475.15 485.15 Vspec/cm3g1 _______________________________________________________________________________
10 0.7418 0.7445 0.7474 0.7503 0.7533 20 0.7397 0.7423 0.7450 0.7476 0.7506 30 0.7377 0.7400 0.7426 0.7452 0.7479 40 0.7358 0.7382 0.7405 0.7431 0.7455 50 0.7340 0.7364 0.7387 0.7410 0.7434 60 0.7325 0.7346 0.7369 0.7390 0.7413 70 0.7310 0.7330 0.7351 0.7371 0.7395 80 0.7295 0.7315 0.7335 0.7356 0.7377 90 0.7282 0.7300 0.7320 0.7340 0.7361 100 0.7269 0.7287 0.7305 0.7325 0.7343 110 0.7257 0.7274 0.7292 0.7310 0.7330 120 0.7244 0.7262 0.7279 0.7297 0.7315 130 0.7234 0.7249 0.7267 0.7284 0.7302 140 0.7224 0.7239 0.7257 0.7272 0.7290 150 0.7214 0.7229 0.7244 0.7262 0.7277 160 0.7205 0.7219 0.7234 0.7249 0.7267 170 0.7197 0.7209 0.7224 0.7239 0.7254 180 0.7187 0.7202 0.7217 0.7229 0.7244 190 0.7180 0.7195 0.7207 0.7222 0.7234 200 0.7173 0.7185 0.7200 0.7212 0.7227 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2003KIM Characterization: −
_______________________________________________________________________________
P/MPa T/K 439.85 449.45 458.95 467.95 476.35 485.95 495.05 504.55 513.35 Vspec/cm3g1 _______________________________________________________________________________
0.1 1.0035 1.0088 1.0137 1.0191 1.0239 1.0291 1.0343 1.0396 1.0453 10 0.9989 1.0039 1.0087 1.0137 1.0183 1.0234 1.0283 1.0333 1.0385 20 0.9945 0.9993 1.0038 1.0086 1.0130 1.0178 1.0225 1.0271 1.0319 30 0.9905 0.9952 0.9996 1.0041 1.0083 1.0131 1.0176 1.0220 1.0265 40 0.9868 0.9913 0.9955 1.0000 1.0041 1.0087 1.0130 1.0172 1.0216 50 0.9832 0.9875 0.9918 0.9960 1.0001 1.0046 1.0088 1.0127 1.0169 60 0.9799 0.9840 0.9881 0.9923 0.9963 1.0005 1.0046 1.0085 1.0127 70 0.9768 0.9806 0.9845 1.0000 0.9927 0.9969 1.0009 1.0044 1.0084 80 0.9737 0.9774 0.9812 0.9852 1.0000 0.9931 0.9970 1.0006 1.0050 90 0.9709 0.9743 0.9781 0.9819 0.9857 0.9898 0.9936 0.9970 1.0008 100 0.9682 0.9713 0.9750 0.9788 0.9826 0.9864 0.9901 0.9935 0.9972 _______________________________________________________________________________
________________________________________________________________________ 6.2. Excess volumes and/or densities of aqueous polymer solutions Polymer (B): chitosan 2005WAL Characterization: medium molecular weight sample, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 308.15
wB 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99698 0.99707 0.99240 0.99733 0.99753 Polymer (B): chitosan 2006MUT Characterization: Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99816 0.99881 0.99947 1.00012 1.00078 1.00143 1.00209 1.00274
wB 0.9 1.0 /(g/cm3) 1.00339 1.00405
T/K = 308.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99514 0.99579 0.99643 0.99708 0.99772 0.99836 0.99901 0.99965
wB 0.9 1.0 /(g/cm3) 1.00030 1.00094
T/K = 318.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99072 0.99142 0.99212 0.99281 0.99352 0.99421 0.99491 0.99561
wB 0.9 1.0 /(g/cm3) 0.99631 0.99701
T/K = 328.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.98399 0.98488 0.98576 0.98664 0.98752 0.98841 0.98929 0.99017
wB 0.9 1.0 /(g/cm3) 0.99106 0.99194
continued
________________________________________________________________________
continued
T/K = 338.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.97401 0.97512 0.97622 0.97732 0.97843 0.97953 0.98064 0.98174
wB 0.9 1.0 /(g/cm3) 0.98284 0.98395 Polymer (B): guar gum 2006MUT Characterization: S.D. Fine Chemicals, Mumbai, India Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99788 0.99811 0.99842 0.99887 0.99925 0.99973 1.00014 1.00057
wB 0.9 1.0 /(g/cm3) 1.00122 1.00141
T/K = 308.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99484 0.99508 0.99541 0.99587 0.99623 0.99671 0.99713 0.99754
wB 0.9 1.0 /(g/cm3) 0.99820 0.99837
T/K = 318.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99093 0.99098 0.99140 0.99199 0.99240 0.99285 0.99327 0.99369
wB 0.9 1.0 /(g/cm3) 0.99436 0.99452
T/K = 328.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.98203 0.98224 0.98359 0.98691 0.98784 0.98812 0.98854 0.98914
wB 0.9 1.0 /(g/cm3) 0.98980 0.98996
T/K = 338.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.97160 0.97191 0.97303 0.97603 0.97785 0.97830 0.98176 0.98302
wB 0.9 1.0 /(g/cm3) 0.98447 0.98560
________________________________________________________________________ Polymer (B): hydroxyethylcellulose 2006MUT Characterization: Loba Chemicals, Mumbai, India Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99789 0.99829 0.99869 0.99909 0.99949 0.99989 1.00029 1.00068
wB 0.9 1.0 /(g/cm3) 1.00108 1.00148
T/K = 308.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99489 0.99529 0.99568 0.99607 0.99646 0.99686 0.99725 0.99764
wB 0.9 1.0 /(g/cm3) 0.99804 0.99843
T/K = 318.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99046 0.99091 0.99135 0.99180 0.99223 0.99268 0.99312 0.99356
wB 0.9 1.0 /(g/cm3) 0.99401 0.99445
T/K = 328.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.98373 0.98435 0.98497 0.98559 0.98621 0.98683 0.98745 0.98807
wB 0.9 1.0 /(g/cm3) 0.98869 0.98931
T/K = 338.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.97412 0.97533 0.97654 0.97775 0.97897 0.98018 0.98139 0.98261
wB 0.9 1.0 /(g/cm3) 0.98381 0.98502 Polymer (B): hydroxyethylcellulose 2005WAL Characterization: low-viscosity-grade sample, Polysciences, Mumbai, India Solvent (A): water H2O 7732-18-5
T/K = 308.15
wB 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99692 0.99701 0.99713 0.99725 0.99738
________________________________________________________________________ Polymer (B): hydroxyethylcellulose 2005WAL Characterization: low-viscosity-grade sample, Polysciences, Mumbai, India Solvent (A): water H2O 7732-18-5 Polymer (C): chitosan Characterization: medium molecular weight sample, Aldrich Chem. Co., Inc., Milwaukee, WI
T/K = 308.15
wC/wB = 20/80 was kept constant
wB+C 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99693 0.99702 0.99715 0.99727 0.99740
wC/wB = 40/60 was kept constant
wB+C 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99694 0.99703 0.99716 0.99729 0.99743
wC/wB = 50/50 was kept constant
wB+C 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99694 0.99704 0.99717 0.99729 0.99744
wC/wB = 60/40 was kept constant
wB+C 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99696 0.99705 0.99719 0.99730 0.99747
wC/wB = 80/20 was kept constant
wB+C 0.0005 0.0010 0.0015 0.0020 0.0025 /(g/cm3) 0.99697 0.99706 0.99721 0.99732 0.99750 Polymer (B): hydroxypropyl(methyl)cellulose 2006MUT Characterization: Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99770 0.99803 0.99831 0.99854 0.99878 0.99905 0.99934 0.99957
wB 0.9 1.0 /(g/cm3) 0.99999 1.00018
T/K = 308.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99470 0.99502 0.99529 0.99551 0.99576 0.99603 0.99632 0.99657
wB 0.9 1.0 /(g/cm3) 0.99696 0.99715
continued
________________________________________________________________________
continued
T/K = 318.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.99088 0.99l77 0.99146 0.99167 0.99193 0.99220 0.99247 0.99271
wB 0.9 1.0 /(g/cm3) 0.99310 0.99326
T/K = 328.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.98633 0.98662 0.98691 0.98713 0.98738 0.98761 0.98793 0.98812
wB 0.9 1.0 /(g/cm3) 0.98852 0.98870
T/K = 338.15
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 /(g/cm3) 0.98060 0.98082 0.98160 0.98179 0.98196 0.98211 0.98262 0.98299
wB 0.9 1.0 /(g/cm3) 0.98322 0.98343 Polymer (B): maltodextrin 2005NIN Characterization: Mn/g.mol1 = 1140, Mw/g.mol1 = 8285, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0500 0.0995 0.1416 0.1988 0.2506 0.2878 0.3489 0.3980 /(g/cm3) 1.01591 1.03525 1.05224 1.07614 1.09869 1.11537 1.14380 1.16776
wB 0.4507 0.4938 0.5392 0.5941 /(g/cm3) 1.19390 1.21650 1.24056 1.27196 Polymer (B): maltodextrin 2005NIN Characterization: Mn/g.mol1 = 1475, Mw/g.mol1 = 13710, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0499 0.0999 0.1487 0.2004 0.2497 0.2996 0.3512 0.4025 /(g/cm3) 1.01573 1.03516 1.05472 1.07628 1.09761 1.11995 1.14387 1.16867
wB 0.4992 0.5491 /(g/cm3) 1.21786 1.24457
________________________________________________________________________ Polymer (B): poly(acrylic acid) 2006SAR Characterization: Mn/g.mol1 = 2100, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 293.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9982 1.0148 1.0309 1.0492 1.0669 1.0856 1.1020 1.1201 1.1412
wB 0.45 0.50 /(g/cm3) 1.1572 1.1751
T/K = 298.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9970 1.0136 1.0297 1.0478 1.0659 1.0827 1.0984 1.1178 1.1382
wB 0.45 0.50 /(g/cm3) 1.1545 1.1717
T/K = 303.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9956 1.0113 1.0289 1.0464 1.0642 1.0802 1.0987 1.1168 1.1362
wB 0.45 0.50 /(g/cm3) 1.1526 1.1690
T/K = 308.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9940 1.0099 1.0273 1.0453 1.0619 1.0784 1.0981 1.1140 1.1319
wB 0.45 0.50 /(g/cm3) 1.1492 1.1667
T/K = 313.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9921 1.0104 1.0268 1.0450 1.0607 1.0774 1.0966 1.1116 1.1293
wB 0.45 0.50 /(g/cm3) 1.1468 1.1632
T/K = 318.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9901 1.0084 1.0249 1.0422 1.0580 1.0755 1.0915 1.1082 1.1265
wB 0.45 0.50 /(g/cm3) 1.1447 1.1611
T/K = 323.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.9880 1.0056 1.0209 1.0386 1.0548 1.0702 1.0844 1.1035 1.1199
wB 0.45 0.50 /(g/cm3) 1.1359 1.1524
________________________________________________________________________ Polymer (B): poly(acrylic acid) 2010MOL Characterization: Mη/g.mol1 = 450000, Aldrich Chem. Co., Inc., Milwaukee, WI Solvent (A): water H2O 7732-18-5
T/K = 298.15
cB/(mol/kg) 0.0000 0.0101 0.0179 0.0300 0.0399 0.0490 0.0601 0.0699 /(g/cm3) 0.99704 0.99737 0.99752 0.99808 0.99807 0.99831 0.99859 0.99884
cB/(mol/kg) 0.0800 0.0901 0.0998 0.1093 0.1200 0.1293 0.1398 0.1502 /(g/cm3) 0.99909 0.99934 0.99958 0.99980 1.00010 1.00032 1.00059 1.00086
cB/(mol/kg) 0.1586 0.1699 0.1808 0.1901 0.1998 /(g/cm3) 1.00108 1.00133 1.00162 1.00184 1.00208
Comments: Molality is calculated using 72.064 g/mol for the repetitive unit. Polymer (B): poly(ethylene glycol) 2010TRI Characterization: Mw/g.mol1 = 200, Central Drug House, New Delhi, India Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9997 1.0158 1.0331 1.0510 1.0691 1.0865 1.1031 1.1147 1.1242
wB 0.90 1.00 /(g/cm3) 1.1298 1.1327
T/K = 293.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9982 1.0136 1.0299 1.0468 1.0638 1.0802 1.0961 1.1070 1.1163
wB 0.90 1.00 /(g/cm3) 1.1218 1.1246
T/K = 303.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9957 1.0106 1.0262 1.0422 1.0583 1.0737 1.0888 1.0995 1.1084
wB 0.90 1.00 /(g/cm3) 1.1138 1.1166
T/K = 313.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9923 1.0066 1.0217 1.0370 1.0522 1.0667 1.0814 1.0918 1.1005
wB 0.90 1.00 /(g/cm3) 1.1059 1.1086
continued
________________________________________________________________________
continued
T/K = 323.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9880 1.0018 1.0164 1.0311 1.0457 1.0599 1.0738 1.0838 1.0925
wB 0.90 1.00 /(g/cm3) 1.0979 1.1006
T/K = 333.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9831 0.9989 1.0114 1.0261 1.0406 1.0546 1.0686 1.0785 1.0872
wB 0.90 1.00 /(g/cm3) 1.0925 1.0953
T/K = 343.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9776 0.9914 1.0058 1.0204 1.0348 1.0489 1.0627 1.0725 1.0811
wB 0.90 1.00 /(g/cm3) 1.0865 1.0892
T/K = 353.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9716 0.9852 0.9995 1.0140 1.0284 1.0424 1.0561 1.0658 1.0744
wB 0.90 1.00 /(g/cm3) 1.0797 1.0824
T/K = 363.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9651 0.9784 0.9926 1.0070 1.0213 1.0351 1.0488 1.0585 1.0669
wB 0.90 1.00 /(g/cm3) 1.0722 1.0749 Polymer (B): poly(ethylene glycol) 2008DHO Characterization: Mn/g.mol1 = 200, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 275.15
xB 0.0000 0.0018 0.0037 0.0057 0.0078 0.0099 0.0181 0.0299 0.0492 /(g/cm3) 0.9999 1.0035 1.0066 1.0099 1.0130 1.0166 1.0289 1.0453 1.0662
xB 0.0782 0.0956 /(g/cm3) 1.0888 1.0974
continued
________________________________________________________________________
continued
T/K = 277.15
xB 0.0000 0.0018 0.0037 0.0057 0.0078 0.0099 0.0181 0.0299 0.0492 /(g/cm3) 1.0000 1.0036 1.0065 1.0098 1.0129 1.0164 1.0286 1.0448 1.0653
xB 0.0782 0.0956 /(g/cm3) 1.0873 1.0963
T/K = 279.15
xB 0.0000 0.0018 0.0037 0.0057 0.0078 0.0099 0.0181 0.0299 0.0492 /(g/cm3) 0.9999 1.0035 1.0065 1.0096 1.0127 1.0161 1.0282 1.0444 1.0645
xB 0.0782 0.0956 /(g/cm3) 1.0869 1.0949
T/K = 281.15
xB 0.0000 0.0018 0.0037 0.0057 0.0078 0.0099 0.0181 0.0299 0.0492 /(g/cm3) 0.9999 1.0033 1.0063 1.0094 1.0125 1.0158 1.0279 1.0436 1.0637
xB 0.0782 0.0956 /(g/cm3) 1.0853 1.0937
T/K = 283.15
xB 0.0000 0.0018 0.0037 0.0057 0.0078 0.0099 0.0181 0.0299 0.0492 /(g/cm3) 0.9997 1.0031 1.0062 1.0092 1.0123 1.0155 1.0275 1.0428 1.0628
xB 0.0782 0.0956 /(g/cm3) 1.0842 1.0927 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 200, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0082 0.0519 0.1034 0.1506 0.2157 0.3055 0.3493 0.3970 /(g/cm3) 0.999343 1.000640 1.002146 1.003581 1.005493 1.008044 1.009225 1.010576
T/K = 298.15
cB/(mol/kg) 0.0082 0.0519 0.1034 0.1506 0.2157 0.3055 0.3493 0.3970 /(g/cm3) 0.997279 0.998531 0.999977 1.001357 1.003189 1.005639 1.006765 1.008606
T/K = 308.15
cB/(mol/kg) 0.0082 0.0519 0.1034 0.1506 0.2157 0.3055 0.3493 0.3970 /(g/cm3) 0.994258 0.995472 0.996870 0.998203 0.999975 1.002331 1.003422 1.004669
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2005ELI Characterization: Mn/g.mol1 = 200, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0999 0.2003 0.2996 0.3998 0.4998 0.6000 0.7002 0.8000 0.8997 /(g/cm3) 1.0186 1.0347 1.0508 1.0659 1.0805 1.0984 1.1069 1.1190 1.1231
wB 1.0000 /(g/cm3) 1.1256
T/K = 308.15
wB 0.0999 0.2003 0.2996 0.3998 0.4998 0.6000 0.7002 0.8000 0.8997 /(g/cm3) 1.0152 1.0325 1.0466 1.0624 1.0769 1.0910 1.1039 1.1122 1.1179
wB 1.0000 /(g/cm3) 1.1196
T/K = 318.15
wB 0.0999 0.2003 0.2996 0.3998 0.4998 0.6000 0.7002 0.8000 0.8997 /(g/cm3) 1.0111 1.0280 1.0411 1.0547 1.0707 1.0843 1.0964 1.1054 1.1102
wB 1.0000 /(g/cm3) 1.1122
T/K = 328.15
wB 0.0999 0.2003 0.2996 0.3998 0.4998 0.6000 0.7002 0.8000 0.8997 /(g/cm3) 1.0037 1.0220 1.0356 1.0486 1.0640 1.0766 1.0888 1.0966 1.1022
wB 1.0000 /(g/cm3) 1.1044
T/K = 338.15
wB 0.0999 0.2003 0.2996 0.3998 0.4998 0.6000 0.7002 0.8000 0.8997 /(g/cm3) 1.0005 1.0155 1.0288 1.0378 1.0560 1.0682 1.0800 1.0889 1.0934
wB 1.0000 /(g/cm3) 1.0964 Polymer (B): poly(ethylene glycol) 2003RAH Characterization: Mn/g.mol1 = 200, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 313.15
wB 0.8991 0.8011 0.7120 0.6411 0.5197 0.4481 0.2220 0.1473 /(g/cm3) 1.1049 1.1018 1.0925 1.0811 1.0707 1.0613 1.0260 1.0032
continued
________________________________________________________________________
continued
T/K = 333.15
wB 0.8375 0.7328 0.5586 0.4670 0.3828 0.2329 0.1493 /(g/cm3) 1.0852 1.0800 1.0572 1.0499 1.0437 1.0167 1.0063
T/K = 338.15
wB 0.3552 0.2931 0.1974 0.1913 0.1076 0.0982 0.0793 0.0601 0.0399 /(g/cm3) 1.0364 1.0260 1.0094 1.0073 0.9938 0.9917 0.9845 0.9814 0.9782 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 300, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0500 0.0993 0.1490 0.1975 0.2498 0.2973 0.3411 0.3983 /(g/cm3) 1.001442 1.003698 1.005935 1.008055 1.010339 1.012351 1.014186 1.016524
T/K = 298.15
cB/(mol/kg) 0.0500 0.0993 0.1490 0.1975 0.2498 0.2973 0.3411 0.3983 /(g/cm3) 0.999297 1.001464 1.003606 1.005637 1.007824 1.009746 1.001150 1.013731
T/K = 308.15
cB/(mol/kg) 0.0500 0.0993 0.1490 0.1975 0.2498 0.2973 0.3411 0.3983 /(g/cm3) 1.001442 1.003698 1.005935 1.008055 1.010339 1.012351 1.014186 1.016524 Polymer (B): poly(ethylene glycol) 2005ELI Characterization: Mn/g.mol1 = 300, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0998 0.2002 0.3002 0.4001 0.4997 0.6000 0.7000 0.8007 0.9000 /(g/cm3) 1.0231 1.0363 1.0553 1.0682 1.0821 1.1019 1.1096 1.1226 1.1269
wB 1.0000 /(g/cm3) 1.1304
T/K = 308.15
wB 0.0998 0.2002 0.3002 0.4001 0.4997 0.6000 0.7000 0.8007 0.9000 /(g/cm3) 1.0208 1.0332 1.0534 1.0653 1.0804 1.0960 1.1066 1.1152 1.1205
wB 1.0000 /(g/cm3) 1.1224
continued
________________________________________________________________________
continued
T/K = 318.15
wB 0.0998 0.2002 0.3002 0.4001 0.4997 0.6000 0.7000 0.8007 0.9000 /(g/cm3) 1.0169 1.0275 1.0471 1.0572 1.0704 1.0870 1.0984 1.1065 1.1120
wB 1.0000 /(g/cm3) 1.1156
T/K = 328.15
wB 0.0998 0.2002 0.3002 0.4001 0.4997 0.6000 0.7000 0.8007 0.9000 /(g/cm3) 1.0112 1.0202 1.0424 1.0531 1.0612 1.0776 1.0882 1.0988 1.1043
wB 1.0000 /(g/cm3) 1.1080
T/K = 338.15
wB 0.0998 0.2002 0.3002 0.4001 0.4997 0.6000 0.7000 0.8007 0.9000 /(g/cm3) 1.0067 1.0150 1.0348 1.0447 1.0563 1.0701 1.0786 1.0895 1.0962
wB 1.0000 /(g/cm3) 1.1000 Polymer (B): poly(ethylene glycol) 2003RAH Characterization: Mn/g.mol1 = 300, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 308.15
wB 0.3926 0.2987 0.2500 0.1998 0.1080 /(g/cm3) 1.0561 1.0416 1.0317 1.0219 1.0104
T/K = 318.15
wB 0.3926 0.2987 0.2500 0.1998 0.1080 /(g/cm3) 1.0447 1.0323 1.0251 1.0177 1.0053
T/K = 328.15
wB 0.3926 0.2987 0.2500 0.1998 0.1080 /(g/cm3) 1.0385 1.0271 1.0199 1.0125 1.0021
T/K = 338.15
wB 0.3926 0.2987 0.2500 0.1998 0.1080 /(g/cm3) 1.0333 1.0198 1.0146 1.0084 0.9897
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008HAN Characterization: Mn/g.mol1 = 380-420, Beijing Reagent Company, China Solvent (A): water H2O 7732-18-5
T/K = 298.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9970 1.0126 1.0468 1.0645 1.0814 1.0965 1.1082 1.1158 VE/(cm3/g) 0.000 0.085 0.357 0.553 0.774 1.013 1.223 1.345
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.1200 1.1207 1.1213 1.1215 1.1217 1.1217 1.1218 1.1218 VE/(cm3/g) 1.288 1.196 1.066 0.913 0.606 0.377 0.216 0.000
T/K = 303.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9957 1.0114 1.0448 1.0616 1.0781 1.0931 1.1041 1.1118 VE/(cm3/g) 0.000 0.093 0.359 0.538 0.753 0.994 1.179 1.305
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.1160 1.1168 1.1173 1.1176 1.1178 1.1179 1.1180 1.1180 VE/(cm3/g) 1.246 1.164 1.020 0.881 0.574 0.371 0.213 0.000
T/K = 308.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9941 1.0095 1.0421 1.0586 1.0746 1.0892 1.1007 1.1081 VE/(cm3/g) 0.000 0.089 0.346 0.522 0.728 0.958 1.168 1.285
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.1119 1.1127 1.1132 1.1134 1.1136 1.1141 1.1142 1.1142 VE/(cm3/g) 1.230 1.152 1.015 0.864 0.563 0.361 0.210 0.000
T/K = 313.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9922 1.0075 1.0394 1.0557 1.0710 1.0850 1.0964 1.1035 VE/(cm3/g) 0.000 0.093 0.346 0.524 0.717 0.935 1.147 1.255
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.1077 1.1085 1.1090 1.1092 1.1095 1.1096 1.1097 1.1097 VE/(cm3/g) 1.209 1.134 0.999 0.851 0.577 0.359 0.207 0.000
T/K = 318.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9902 1.0049 1.0361 1.0518 1.0673 1.0809 1.0918 1.0993 VE/(cm3/g) 0.000 0.084 0.330 0.497 0.700 0.909 1.102 1.231
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.1036 1.1043 1.1049 1.1050 1.1052 1.1056 1.1057 1.1057 VE/(cm3/g) 1.200 1.116 0.999 0.839 0.547 0.354 0.205 0.000
continued
________________________________________________________________________
continued
T/K = 323.15
xB 0.0000 0.0050 0.0190 0.0291 0.0431 0.0634 0.0951 0.1504 /(g/cm3) 0.9880 1.0025 1.0332 1.0486 1.0635 1.0768 1.0877 1.0954 VE/(cm3/g) 0.000 0.083 0.326 0.489 0.678 0.879 1.073 1.214
xB 0.2719 0.3403 0.4330 0.5199 0.6873 0.7996 0.8923 1.0000 /(g/cm3) 1.0995 1.1004 1.1009 1.1011 1.1013 1.1015 1.1016 1.1017 VE/(cm3/g) 1.166 1.104 0.974 0.830 0.541 0.350 0.202 0.000 Polymer (B): poly(ethylene glycol) 2010TRI Characterization: Mw/g.mol1 = 400, Central Drug House, New Delhi, India Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9997 1.0170 1.0353 1.0540 1.0733 1.0919 1.1087 1.1210 1.1272
wB 0.90 1.00 /(g/cm3) 1.1335 1.1351
T/K = 293.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9982 1.0147 1.0321 1.0497 1.0678 1.0853 1.1012 1.1129 1.1191
wB 0.90 1.00 /(g/cm3) 1.1251 1.1265
T/K = 303.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9957 1.0114 1.0280 1.0447 1.0618 1.0784 1.0934 1.1047 1.1108
wB 0.90 1.00 /(g/cm3) 1.1167 1.1181
T/K = 313.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9923 1.0075 1.0234 1.0393 1.0555 1.0712 1.0856 1.0964 1.1025
wB 0.90 1.00 /(g/cm3) 1.1083 1.1098
T/K = 323.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9880 1.0025 1.0181 1.0333 1.0489 1.0638 1.0776 1.0881 1.0941
wB 0.90 1.00 /(g/cm3) 1.1001 1.1015
continued
________________________________________________________________________
continued
T/K = 333.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9831 0.9977 1.0132 1.0279 1.0437 1.0585 1.0719 1.0814 1.0888
wB 0.90 1.00 /(g/cm3) 1.0947 1.0962
T/K = 343.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9776 0.9922 1.0075 1.0223 1.0379 1.0526 1.0659 1.0754 1.0828
wB 0.90 1.00 /(g/cm3) 1.0887 1.0901
T/K = 353.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9716 0.9860 1.0013 1.0159 1.0315 1.0461 1.0593 1.0686 1.0760
wB 0.90 1.00 /(g/cm3) 1.0819 1.0833
T/K = 363.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9651 0.9791 0.9943 1.0088 1.0243 1.0388 1.0519 1.0612 1.0686
wB 0.90 1.00 /(g/cm3) 1.0744 1.0758 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 400, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0500 0.0985 0.1360 0.2161 0.3006 0.3500 0.4001 /(g/cm3) 1.00228 1.00528 1.00754 1.01219 1.01687 1.01961 1.02221
T/K = 298.15
cB/(mol/kg) 0.0500 0.0985 0.1360 0.2161 0.3006 0.3500 0.4001 /(g/cm3) 1.00010 1.00297 1.00514 1.00958 1.01405 1.01666 1.01914
T/K = 308.15
cB/(mol/kg) 0.0500 0.0985 0.1360 0.2161 0.3006 0.3500 0.4001 /(g/cm3) 0.99698 0.99975 1.00183 1.00612 1.01041 1.01291 1.01526
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008DHO Characterization: Mn/g.mol1 = 400, Qualigens Fine Chemicals, Mumbai, India Solvent (A): water H2O 7732-18-5
T/K = 275.15
xB 0.0000 0.0023 0.0047 0.0073 0.0108 0.0143 0.0186 0.0267 0.0346 /(g/cm3) 0.9999 1.0087 1.0168 1.0254 1.0361 1.0489 1.0614 1.0740 1.0856
xB 0.0616 0.0867 /(g/cm3) 1.1119 1.1243
T/K = 277.15
xB 0.0000 0.0023 0.0047 0.0073 0.0108 0.0143 0.0186 0.0267 0.0346 /(g/cm3) 1.0000 1.0086 1.0166 1.0251 1.0357 1.0484 1.0604 1.0740 1.0844
xB 0.0616 0.0867 /(g/cm3) 1.1102 1.1228
T/K = 279.15
xB 0.0000 0.0023 0.0047 0.0073 0.0108 0.0143 0.0186 0.0267 0.0346 /(g/cm3) 0.9999 1.0085 1.0163 1.0247 1.0350 1.0478 1.0601 1.0719 1.0840
xB 0.0616 0.0867 /(g/cm3) 1.1073 1.1190
T/K = 281.15
xB 0.0000 0.0023 0.0047 0.0073 0.0108 0.0143 0.0186 0.0267 0.0346 /(g/cm3) 0.9999 1.0083 1.0160 1.0243 1.0346 1.0472 1.0590 1.0710 1.0824
xB 0.0616 0.0867 /(g/cm3) 1.1075 1.1194
T/K = 283.15
xB 0.0000 0.0023 0.0047 0.0073 0.0108 0.0143 0.0186 0.0267 0.0346 /(g/cm3) 0.9997 1.0080 1.0157 1.0238 1.0341 1.0466 1.0580 1.0700 1.0811
xB 0.0616 0.0867 /(g/cm3) 1.1073 1.1811 Polymer (B): poly(ethylene glycol) 2007KUS Characterization: Mn/g.mol1 = 400, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
cB/(mol/kg) 0.00000 0.04106 0.08692 0.13264 0.18218 0.22888 0.28080 0.33438 /(g/cm3) 0.99705 0.99958 1.00235 1.00502 1.00785 1.01084 1.01318 1.01696
cB/(mol/kg) 0.38898 0.44096 0.49970 /(g/cm3) 1.01893 1.02148 1.02412
T/K = 278.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 1.01322 1.02461 1.03967 1.05342 1.06513 1.08817 1.09491 1.10446 VE/(cm3/mol) −0.070 −0.142 −0.255 −0.379 −0.500 −0.788 −0.886 −1.038
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.12581 1.13238 1.13729 1.13876 1.13859 VE/(cm3/mol) −1.436 −1.553 −1.465 −0.716 −0.963
T/K = 288.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 1.01167 1.02242 1.03659 1.04947 1.06044 1.08206 1.08841 1.09743 VE/(cm3/mol) −0.064 −0.130 −0.234 −0.346 −0.456 −0.719 −0.809 −0.948
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.11786 1.12431 1.12899 1.13020 1.13034 VE/(cm3/mol) −1.315 −1.421 −1.276 −0.659 −0.358
T/K = 298.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 1.00907 1.01933 1.03276 1.04494 1.05529 1.07566 1.08166 1.09020 VE/(cm3/mol) −0.062 −0.124 −0.222 −0.326 −0.429 −0.674 −0.759 −0.890
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.10979 1.11613 1.12086 1.12202 1.12215 VE/(cm3/mol) −1.242 −1.350 −1.228 −0.640 −0.350
T/K = 308.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 1.00561 1.01545 1.02829 1.03987 1.04968 1.06898 1.07466 1.08278 VE/(cm3/mol) −0.060 −0.120 −0.213 −0.312 −0.408 −0.638 −0.717 −0.840
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.10161 1.10786 1.11267 1.11383 1.11395 VE/(cm3/mol) −1.178 −1.287 −1.185 −0.624 −0.342
T/K = 318.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 1.00141 1.01090 1.02321 1.03429 1.04364 1.06199 1.06740 1.07514 VE/(cm3/mol) −0.058 −0.117 −0.205 −0.299 −0.390 −0.606 −0.681 −0.797
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.09333 1.09953 1.10445 1.10565 1.10577 VE/(cm3/mol) −1.120 −1.229 −1.145 −0.607 −0.335
continued
________________________________________________________________________
continued
T/K = 328.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 0.99656 1.00573 1.01760 1.02822 1.03718 1.05471 1.05989 1.06730 VE/(cm3/mol) −0.057 −0.114 −0.199 −0.288 −0.374 −0.577 −0.647 −0.757
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.08494 1.09111 1.09619 1.09747 1.09760 VE/(cm3/mol) −1.066 −1.175 −1.105 −0.589 −0.326
T/K = 338.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 0.99112 1.00001 1.01148 1.02172 1.03032 1.04714 1.05211 1.05925 VE/(cm3/mol) −0.056 −0.110 −0.192 −0.277 −0.358 −0.550 −0.616 −0.719
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.07644 1.08262 1.08789 1.08929 1.08945 VE/(cm3/mol) −1.014 −1.122 −1.064 −0.569 −0.314
T/K = 348.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 0.98514 0.99378 1.00489 1.01478 1.02307 1.03928 1.04407 1.05098 VE/(cm3/mol) −0.054 −0.107 −0.185 −0.266 −0.343 −0.523 −0.585 −0.682
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.06781 1.07403 1.07954 1.08113 1.08131 VE/(cm3/mol) −0.964 −1.070 −1.022 −0.552 −0.304
T/K = 358.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) 0.97866 0.98707 0.99786 1.00744 1.01546 1.03114 1.03578 1.04249 VE/(cm3/mol) −0.052 −0.103 −0.178 −0.254 −0.327 −0.496 −0.554 −0.646
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.05904 1.06533 1.07115 1.07295 1.07317 VE/(cm3/mol) −0.914 −1.018 −0.978 −0.530 −0.292
T/K = 363.15
xA 0.9963 0.9928 0.9876 0.9822 0.9768 0.9627 0.9571 0.9472 /(g/cm3) − 0.98354 0.99418 1.00362 1.01152 1.02696 1.03153 1.03816 VE/(cm3/mol) − −0.101 −0.173 −0.248 −0.318 −0.482 −0.539 −0.627
xA 0.9007 0.8536 0.6867 0.3411 0.1852 /(g/cm3) 1.05461 1.06095 1.06692 − − VE/(cm3/mol) −0.888 −0.991 −0.954 − −
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 550, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0500 0.1058 0.1498 0.2001 0.2492 0.2996 0.3492 0.4032 /(g/cm3) 1.00358 1.00834 1.01197 1.01597 1.01973 1.02338 1.02683 1.03054
T/K = 298.15
cB/(mol/kg) 0.0500 0.1058 0.1498 0.2001 0.2492 0.2996 0.3492 0.4032 /(g/cm3) 1.00134 1.00590 1.00937 1.01319 1.01617 1.02025 1.02352 1.02705
T/K = 308.15
cB/(mol/kg) 0.0500 0.1058 0.1498 0.2001 0.2492 0.2996 0.3492 0.4032 /(g/cm3) 0.99818 1.00256 1.00590 1.00957 1.01300 1.01640 1.01950 1.02290 Polymer (B): poly(ethylene glycol) 2011ZHA Characterization: Mn/g.mol1 = 600, Beijing Reagent Company, China Solvent (A): water H2O 7732-18-5
T/K = 298.15
xB 0.0000 0.0075 0.0196 0.0431 0.1001 0.1998 0.3001 0.3994 /(g/cm3) 0.9970 1.0309 1.0662 1.0995 1.1156 1.1217 1.1225 1.1226 VE/(cm3/mol) 0.000 −0.230 −0.585 1.107 −1.349 −1.436 −1.269 −1.047
xB 0.4983 0.6977 0.8849 1.0000 /(g/cm3) 1.1228 1.1230 1.1232 1.1233 VE/(cm3/mol) −0.907 −0.490 −0.149 0.000
T/K = 303.15
xB 0.0000 0.0075 0.0196 0.0431 0.1001 0.1998 0.3001 0.3994 /(g/cm3) 0.9957 1.0287 1.0629 1.0951 1.1120 1.1179 1.1187 1.1189 VE/(cm3/mol) 0.000 −0.223 −0.562 −1.056 −1.340 −1.422 −1.274 −1.072
xB 0.4983 0.6977 0.8849 1.0000 /(g/cm3) 1.1190 1.1192 1.1194 1.1195 VE/(cm3/mol) −1.874 −0.503 −0.183 0.000
T/K = 308.15
xB 0.0000 0.0075 0.0196 0.0431 0.1001 0.1998 0.3001 0.3994 /(g/cm3) 0.9940 1.0259 1.0598 1.0906 1.1070 1.1133 1.1139 1.1140 VE/(cm3/mol) 0.000 −0.210 −0.555 −1.024 −1.291 −1.412 −1.259 −1.046
xB 0.4983 0.6977 0.8849 1.0000 /(g/cm3) 1.1141 1.1144 1.1145 1.1147 VE/(cm3/mol) −0.852 −0.497 −0.161 0.000
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2010TRI Characterization: Mw/g.mol1 = 600, Central Drug House, New Delhi, India Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9997 1.0170 1.0354 1.0547 1.0743 1.0933 1.1100 1.1226 1.1306
wB 0.90 /(g/cm3) 1.1344
T/K = 293.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9982 1.0148 1.0322 1.0504 1.0688 1.0866 1.1023 1.1143 1.1221
wB 0.90 1.00 /(g/cm3) 1.1259 1.1271
T/K = 303.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9957 1.0115 1.0281 1.0454 1.0627 1.0796 1.0945 1.1060 1.1136
wB 0.90 1.00 /(g/cm3) 1.1176 1.1186
T/K = 313.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9923 1.0076 1.0234 1.0399 1.0564 1.0724 1.0865 1.0977 1.1052
wB 0.90 1.00 /(g/cm3) 1.1090 1.1102
T/K = 323.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9880 1.0029 1.0182 1.0340 1.0487 1.0649 1.0784 1.0892 1.0966
wB 0.90 1.00 /(g/cm3) 1.1006 1.1019
T/K = 333.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9831 0.9980 1.0133 1.0291 1.0447 1.0598 1.0734 1.0840 1.0913
wB 0.90 1.00 /(g/cm3) 1.0952 1.0965
continued
________________________________________________________________________
continued
T/K = 343.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9776 0.9924 1.0077 1.0234 1.0390 1.0539 1.0674 1.0780 1.0852
wB 0.90 1.00 /(g/cm3) 1.0892 1.0904
T/K = 353.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9716 0.9863 1.0014 1.0170 1.0324 1.0474 1.0608 1.0712 1.0785
wB 0.90 1.00 /(g/cm3) 1.0824 1.0836
T/K = 363.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9651 0.9794 0.9945 1.0099 1.0253 1.0401 1.0534 1.0638 1.0710
wB 0.90 1.00 /(g/cm3) 1.0749 1.0761 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 600, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0499 0.1499 0.1984 0.2348 0.2925 0.3500 0.4013 /(g/cm3) 1.00420 1.01330 1.01728 1.02013 1.02464 1.02900 1.03253
T/K = 298.15
cB/(mol/kg) 0.0499 0.1499 0.1984 0.2348 0.2925 0.3500 0.4013 /(g/cm3) 1.00199 1.01061 1.01448 1.01717 1.02144 1.02563 1.02890
T/K = 308.15
cB/(mol/kg) 0.0499 0.1499 0.1984 0.2348 0.2925 0.3500 0.4013 /(g/cm3) 0.99881 1.00708 1.01076 1.01339 1.01747 1.02143 1.02462 Polymer (B): poly(ethylene glycol) 2005ELI Characterization: Mn/g.mol1 = 600, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.1117 0.2008 0.3006 0.4027 0.5015 0.6026 0.7007 0.8007 0.9004 /(g/cm3) 1.0144 1.0304 1.0473 1.0642 1.0809 1.0953 1.1068 1.1169 1.1212
wB 1.0000 /(g/cm3) 1.1225 continued
________________________________________________________________________
continued
T/K = 308.15
wB 0.1117 0.2008 0.3006 0.4027 0.5015 0.6026 0.7007 0.8007 0.9004 /(g/cm3) 1.0094 1.0249 1.0417 1.0580 1.0743 1.0883 1.0995 1.1080 1.1137
wB 1.0000 /(g/cm3) 1.1151
T/K = 318.15
wB 0.1117 0.2008 0.3006 0.4027 0.5015 0.6026 0.7007 0.8007 0.9004 /(g/cm3) 1.0058 1.0205 1.0371 1.0527 1.0683 1.0817 1.0932 1.1018 1.1057
wB 1.0000 /(g/cm3) 1.1065
T/K = 328.15
wB 0.1117 0.2008 0.3006 0.4027 0.5015 0.6026 0.7007 0.8007 0.9004 /(g/cm3) 1.0022 1.0167 1.0317 1.0476 1.0621 1.0746 1.0851 1.0935 1.0984
wB 1.0000 /(g/cm3) 1.0992
T/K = 338.15
wB 0.1117 0.2008 0.3006 0.4027 0.5015 0.6026 0.7007 0.8007 0.9004 /(g/cm3) 0.9975 1.0119 1.0272 1.0427 1.0581 1.0709 1.0814 1.0904 1.0949
wB 1.0000 /(g/cm3) 1.0965 Polymer (B): poly(ethylene glycol) 2005MOH Characterization: Mn/g.mol1 = 950-1050, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0169 1.0250 1.0329 1.0428 1.0510 1.0585 1.0680 1.0785 1.0868
T/K = 303.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0149 1.0237 1.0321 1.0407 1.0505 1.0576 1.0672 1.0778 1.0864
T/K = 308.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0140 1.0221 1.0306 1.0400 1.0484 1.0557 1.0650 1.0742 1.0843
continued
________________________________________________________________________
continued
T/K = 313.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0110 1.0192 1.0294 1.0380 1.0454 1.0529 1.0610 1.0702 1.0800
T/K = 318.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0092 1.0175 1.0270 1.0345 1.0421 1.0500 1.0591 1.0662 1.0749
T/K = 323.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0080 1.0149 1.0225 1.0304 1.0395 1.0473 1.0550 1.0645 1.0719
T/K = 328.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0047 1.0128 1.0211 1.0281 1.0351 1.0442 1.0521 1.0606 1.0681 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 1000, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0498 0.0990 0.1501 0.1996 0.2493 0.2995 0.3489 0.3998 /(g/cm3) 1.00730 1.01479 1.02204 1.02863 1.03468 1.04039 1.04591 1.05104
T/K = 298.15
cB/(mol/kg) 0.0498 0.0990 0.1501 0.1996 0.2493 0.2995 0.3489 0.3998 /(g/cm3) 1.00489 1.01206 1.01896 1.02523 1.03097 1.03649 1.04162 1.04647
T/K = 308.15
cB/(mol/kg) 0.0498 0.0990 0.1501 0.1996 0.2493 0.2995 0.3489 0.3998 /(g/cm3) 1.00150 1.00841 1.01500 1.02101 1.02659 1.03179 1.03674 1.04135 Polymer (B): poly(ethylene glycol) 2007KUS Characterization: Mn/g.mol1 = 1000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
cB/(mol/kg) 0.00000 0.03667 0.07503 0.11528 0.15830 0.20642 0.25416 0.31263 /(g/cm3) 0.99705 1.00275 1.00836 1.01401 1.01967 1.02557 1.03106 1.03745
cB/(mol/kg) 0.37010 0.43100 0.50037 /(g/cm3) 1.04310 1.04871 1.05468
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 1450, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0500 0.0996 0.1487 0.1994 0.2501 0.2983 0.3509 0.3988 /(g/cm3) 1.01149 1.02235 1.03219 1.04123 1.04926 1.05649 1.06319 1.06868
T/K = 298.15
cB/(mol/kg) 0.0500 0.0996 0.1487 0.1994 0.2501 0.2983 0.3509 0.3988 /(g/cm3) 1.00890 1.01926 1.02863 1.03722 1.04484 1.05171 1.05805 1.06327
T/K = 308.15
cB/(mol/kg) 0.0500 0.0996 0.1487 0.1994 0.2501 0.2983 0.3509 0.3988 /(g/cm3) 1.00543 1.01538 1.02436 1.03257 1.03985 1.04640 1.05245 1.05742 Polymer (B): poly(ethylene glycol) 2010TRI Characterization: Mw/g.mol1 = 1500, Central Drug House, New Delhi, India Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 /(g/cm3) 0.9997 1.0173 1.0359 1.0557 1.0752 1.0952 1.1112 1.1249
T/K = 293.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9982 1.0149 1.0326 1.0511 1.0694 1.0882 1.1032 1.1161 1.1200
T/K = 303.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9957 1.0118 1.0284 1.0462 1.0635 1.0811 1.0953 1.1077 1.1130
T/K = 313.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9923 1.0078 1.0237 1.0407 1.0571 1.0738 1.0873 1.0991 1.1064
wB 0.90 /(g/cm3) 1.1094
T/K = 323.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9880 1.0030 1.0183 1.0346 1.0501 1.0660 1.0789 1.0902 1.0976
wB 0.90 1.00 /(g/cm3) 1.1008 1.1067
continued
________________________________________________________________________
continued
T/K = 333.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9831 0.9981 1.0134 1.0295 1.0450 1.0608 1.0736 1.0849 1.0923
wB 0.90 1.00 /(g/cm3) 1.0954 1.1040
T/K = 343.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9776 0.9926 1.0078 1.0238 1.0392 1.0549 1.0677 1.0789 1.0862
wB 0.90 1.00 /(g/cm3) 1.0894 1.0920
T/K = 353.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9716 0.9864 1.0015 1.0174 1.0328 1.0483 1.0610 1.0722 1.0795
wB 0.90 1.00 /(g/cm3) 1.0826 1.0852
T/K = 363.15
wB 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 /(g/cm3) 0.9651 0.9795 0.9945 1.0104 1.0256 1.0412 1.0537 1.0648 1.0720
wB 0.90 1.00 /(g/cm3) 1.0751 1.0774 Polymer (B): poly(ethylene glycol) 2005ELI Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0547 0.1002 0.1515 0.2055 0.2513 0.3071 0.3512 0.4039 0.4522 /(g/cm3) 1.0131 1.0216 1.0306 1.0389 1.0478 1.0563 1.0651 1.0736 1.0820
wB 0.5004 /(g/cm3) 1.0906
T/K = 308.15
wB 0.0547 0.1002 0.1515 0.2055 0.2513 0.3071 0.3512 0.4039 0.4522 /(g/cm3) 1.0054 1.0162 1.0251 1.0343 1.0429 1.0516 1.0599 1.0689 1.0781
wB 0.5004 /(g/cm3) 1.0861
continued
________________________________________________________________________
continued
T/K = 318.15
wB 0.0547 0.1002 0.1515 0.2055 0.2513 0.3071 0.3512 0.4039 0.4522 /(g/cm3) 0.9942 1.0078 1.0187 1.0279 1.0372 1.0460 1.0546 1.0634 1.0719
wB 0.5004 /(g/cm3) 1.0803
T/K = 328.15
wB 0.0547 0.1002 0.1515 0.2055 0.2513 0.3071 0.3512 0.4039 0.4522 /(g/cm3) 0.9889 1.0026 1.0134 1.0228 1.0323 1.0407 1.0493 1.0580 1.0671
wB 0.5004 /(g/cm3) 1.0751
T/K = 338.15
wB 0.0547 0.1002 0.1515 0.2055 0.2513 0.3071 0.3512 0.4039 0.4522 /(g/cm3) 0.9865 1.0003 1.0107 1.0205 1.0301 1.0391 1.0468 1.0556 1.0649
wB 0.5004 /(g/cm3) 1.0726 Polymer (B): poly(ethylene glycol) 2004GRA Characterization: Mn/g.mol1 = 2000, Mw/g.mol1 = 2080, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium carbonate Na2CO3 497-19-8
T/K = 293.15
wB 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.10000 0.10001 wC 0.00999 0.02000 0.03000 0.04000 0.05000 0.06000 0.07000 0.01000 0.02000 /(g/cm3) 1.00866 1.01919 1.02943 1.03991 1.05028 1.06085 1.07135 1.02665 1.03703
wB 0.10000 0.10000 0.09999 0.09997 0.19999 0.20000 0.20000 0.30000 0.29999 wC 0.03001 0.04003 0.05007 0.06001 0.01001 0.02000 0.03000 0.01001 0.02002 /(g/cm3) 1.04756 1.05755 1.06788 1.07833 1.04386 1.05401 1.06521 1.06195 1.07295
wB 0.40000 0.10000 0.19999 0.29999 0.40003 wC 0.01001 0.00000 0.00000 0.00000 0.00000 /(g/cm3) 1.08124 1.01565 1.03342 1.05126 1.07076
T/K = 298.15
wB 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.10000 0.10001 wC 0.00999 0.02000 0.03000 0.04000 0.05000 0.06000 0.07000 0.01000 0.02000 /(g/cm3) 1.00738 1.01803 1.02794 1.03848 1.04862 1.05929 1.06952 1.02413 1.03456
wB 0.10000 0.10000 0.09999 0.09997 0.19999 0.20000 0.20000 0.30000 0.29999 wC 0.03001 0.04003 0.05007 0.06001 0.01001 0.02000 0.03000 0.01001 0.02002 /(g/cm3) 1.04526 1.05539 1.06594 1.07631 1.04177 1.05185 1.06309 1.05949 1.07031
continued
________________________________________________________________________
continued
wB 0.40000 0.10000 0.19999 0.29999 0.40003 wC 0.01001 0.00000 0.00000 0.00000 0.00000 /(g/cm3) 1.07813 1.01362 1.03117 1.04889 1.06771
T/K = 303.15
wB 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.10000 0.10001 wC 0.00999 0.02000 0.03000 0.04000 0.05000 0.06000 0.07000 0.01000 0.02000 /(g/cm3) 1.00589 1.01629 1.02628 1.03665 1.04679 1.05718 1.06757 1.02229 1.03263
wB 0.10000 0.10000 0.09999 0.09997 0.19999 0.20000 0.20000 0.30000 0.29999 wC 0.03001 0.04003 0.05007 0.06001 0.01001 0.02000 0.03000 0.01001 0.02002 /(g/cm3) 1.04303 1.05346 1.06376 1.07407 1.03986 1.04957 1.06022 1.05678 1.06756
wB 0.40000 0.10000 0.19999 0.29999 0.40003 wC 0.01001 0.00000 0.00000 0.00000 0.00000 /(g/cm3) 1.07495 1.01189 1.02887 1.04627 1.06460
T/K = 308.15
wB 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.10000 0.10001 wC 0.00999 0.02000 0.03000 0.04000 0.05000 0.06000 0.07000 0.01000 0.02000 /(g/cm3) 1.00421 1.01453 1.02446 1.03477 1.04483 1.05523 1.06549 1.02030 1.03052
wB 0.10000 0.10000 0.09999 0.09997 0.19999 0.20000 0.20000 0.30000 0.29999 wC 0.03001 0.04003 0.05007 0.06001 0.01001 0.02000 0.03000 0.01001 0.02002 /(g/cm3) 1.04090 1.05107 1.06146 1.07173 1.03702 1.04735 1.05774 1.05398 1.06474
wB 0.40000 0.10000 0.19999 0.29999 0.40003 wC 0.01001 0.00000 0.00000 0.00000 0.00000 /(g/cm3) 1.07162 1.00998 1.02647 1.04356 1.06138 Polymer (B): poly(ethylene glycol) 2005MUR Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99700 1.00487 1.01327 1.02219 1.03160 1.04037 1.04924 1.05854 1.06756
wB 0.45 0.50 /(g/cm3) 1.07612 1.08394
T/K = 303.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99560 1.00314 1.01168 1.02082 1.02976 1.03830 1.04754 1.05638 1.06562
wB 0.45 0.50 /(g/cm3) 1.07446 1.08250
continued
________________________________________________________________________
continued
T/K = 308.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99400 1.00135 1.00939 1.01787 1.02673 1.03501 1.04412 1.05284 1.06209
wB 0.45 0.50 /(g/cm3) 1.07097 1.07789
T/K = 313.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99220 0.99926 1.00732 1.01488 1.02344 1.03250 1.04056 1.04962 1.05868
wB 0.45 0.50 /(g/cm3) 1.06674 1.07380
T/K = 318.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99020 0.99728 1.00466 1.01190 1.02025 1.02882 1.03766 1.04640 1.05431
wB 0.45 0.50 /(g/cm3) 1.06248 1.07048 Polymer (B): poly(ethylene glycol) 2005MUR Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium citrate Na3C6H5O7 68-04-2
T/K = 298.15
wB 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.08221 1.07330 1.06371 1.05506 1.04665 1.03650 1.02712 1.01810 1.01060
wB 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0.25 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.08400 1.07445 1.06524 1.05644 1.04720 1.03800 1.02903 1.02141 1.07904
wB 0.20 0.15 0.10 0.05 0.00 0.20 0.15 0.10 0.05 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.06960 1.06004 1.05148 1.04186 1.03314 1.08219 1.07365 1.06436 1.05549
wB 0.00 0.15 0.10 0.05 0.00 wC 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.04682 1.08621 1.07755 1.06912 1.06070
T/K = 308.15
wB 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.07840 1.06950 1.06135 1.05190 1.04200 1.03330 1.02370 1.01435 1.00479
continued
________________________________________________________________________
continued
wB 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0.25 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.08110 1.07160 1.06300 1.05304 1.04418 1.03498 1.02650 1.01657 1.07570
wB 0.20 0.15 0.10 0.05 0.00 0.20 0.15 0.10 0.05 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.06650 1.05801 1.04800 1.03940 1.02970 1.07910 1.06950 1.06060 1.05196
wB 0.00 0.15 0.10 0.05 0.00 wC 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.04201 1.08266 1.07364 1.06548 1.05769
T/K = 318.15
wB 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.06857 1.06134 1.05358 1.04600 1.03800 1.02890 1.01944 1.01083 1.00089
wB 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0.25 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.07202 1.06560 1.05803 1.04930 1.04110 1.03189 1.02292 1.01330 1.07100
wB 0.20 0.15 0.10 0.05 0.00 0.20 0.15 0.10 0.05 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.06222 1.05363 1.04365 1.03436 1.02523 1.07510 1.06647 1.05660 1.04720
wB 0.00 0.15 0.10 0.05 0.00 wC 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.03840 1.07923 1.07059 1.06216 1.05356 Polymer (B): poly(ethylene glycol) 2004TEN Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 293.15
cB/(mol/kg) 0.05054 0.10009 0.15051 0.20054 0.25050 0.30131 0.40157 0.50198 /(g/cm3) 1.01322 1.02642 1.03817 1.04875 1.05730 1.06531 1.07766 1.08846
T/K = 298.15
cB/(mol/kg) 0.05054 0.10009 0.15051 0.20054 0.25050 0.30131 0.40157 0.50198 /(g/cm3) 1.01195 1.02491 1.03634 1.04610 1.05497 1.06305 1.07542 1.08531
T/K = 303.15
cB/(mol/kg) 0.05054 0.10009 0.15051 0.20054 0.25050 0.30131 0.40157 0.50198 /(g/cm3) 1.01028 1.02320 1.03425 1.04381 1.05225 1.05990 1.07254 1.08147
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2004TEN Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium nitrate NaNO3 7631-99-4
T/K = 293.15
cB/(mol/kg) 0.015 0.015 0.066 0.070 0.150 0.151 0.251 0.251 cC/(mol/kg) 0.493 0.993 0.375 0.797 0.297 0.793 0.197 0.698 /(g/cm3) 1.02961 1.05529 1.03612 1.05670 1.0S063 1.07053 1.06432 1.08135
cB/(mol/kg) 0.351 cC/(mol/kg) 0.199 /(g/cm3) 1.07789
T/K = 298.15
cB/(mol/kg) 0.015 0.015 0.066 0.070 0.150 0.151 0.251 0.251 cC/(mol/kg) 0.493 0.993 0.375 0.797 0.297 0.793 0.197 0.698 /(g/cm3) 1.02769 1.0S327 1.03429 1.05484 1.04865 1.06807 1.06141 1.07814
cB/(mol/kg) 0.351 cC/(mol/kg) 0.199 /(g/cm3) 1.07513
T/K = 303.15
cB/(mol/kg) 0.015 0.015 0.066 0.070 0.150 0.151 0.251 0.251 cC/(mol/kg) 0.493 0.993 0.375 0.797 0.297 0.793 0.197 0.698 /(g/cm3) 1.02679 1.05148 1.03253 1.05269 1.04631 1.06592 1.05912 1.07604
cB/(mol/kg) 0.351 cC/(mol/kg) 0.199 /(g/cm3) 1.07234 Polymer (B): poly(ethylene glycol) 2004TEN Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Component (C): sucrose C12H22O11 57-50-1
T/K = 293.15
cB/(mol/kg) 0.015 0.015 0.070 0.070 0.151 0.151 0.252 0.351 cC/(mol/kg) 0.201 0.200 0.201 0.201 0.201 0.352 0.201 0.050 /(g/cm3) 1.02809 1.06098 1.04130 1.07089 1.05760 1.07100 1.07396 1.07632
cB/(mol/kg) 0.352 cC/(mol/kg) 0.126 /(g/cm3) 1.08154
continued
________________________________________________________________________
continued
T/K = 298.15
cB/(mol/kg) 0.015 0.015 0.070 0.070 0.151 0.151 0.252 0.351 cC/(mol/kg) 0.201 0.200 0.201 0.201 0.201 0.352 0.201 0.050 /(g/cm3) 1.02647 1.05903 1.03931 1.05530 1.05530 1.06866 1.07118 1.07305
cB/(mol/kg) 0.352 cC/(mol/kg) 0.126 /(g/cm3) 1.07832
T/K = 303.15
cB/(mol/kg) 0.015 0.015 0.070 0.070 0.151 0.151 0.252 0.351 cC/(mol/kg) 0.201 0.200 0.201 0.201 0.201 0.352 0.201 0.050 /(g/cm3) 1.02447 1.05717 1.03739 1.06678 1.05282 1.06607 1.06823 1.06971
cB/(mol/kg) 0.352 cC/(mol/kg) 0.126 /(g/cm3) 1.07486 Polymer (B): poly(ethylene glycol) 2004TEN Characterization: Mn/g.mol1 = 2000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Component (C): sucrose C12H22O11 57-50-1 Salt (D): sodium chloride NaCl 7647-14-5
T/K = 293.15
cB/(mol/kg) 0.015 0.015 0.050 0.050 0.100 0.100 0.201 0.201 cC/(mol/kg) 0.200 0.201 0.200 0.200 0.301 0.301 0.201 0.201 cD/(mol/kg) 0.497 0.998 0.499 1.005 0.509 1.005 0.203 0.503 /(g/cm3) 1.04605 1.06389 1.05361 1.07051 1.07303 1.08773 1.07170 1.07964
cB/(mol/kg) 0.251 0.250 0.301 cC/(mol/kg) 0.100 0.100 0.100 cD/(mol/kg) 0.103 0.300 0.100 /(g/cm3) 1.06862 1.07360 1.07559
T/K = 298.15
cB/(mol/kg) 0.015 0.015 0.050 0.050 0.100 0.100 0.201 0.201 cC/(mol/kg) 0.200 0.201 0.200 0.200 0.301 0.301 0.201 0.201 cD/(mol/kg) 0.497 0.998 0.499 1.005 0.509 1.005 0.203 0.503 /(g/cm3) 1.04444 1.06198 1.05186 1.06829 1.07076 1.08530 1.06896 1.07693
cB/(mol/kg) 0.251 0.250 0.301 cC/(mol/kg) 0.100 0.100 0.100 cD/(mol/kg) 0.103 0.300 0.100 /(g/cm3) 1.06573 1.07047 1.07245
continued
________________________________________________________________________
continued
T/K = 303.15
cB/(mol/kg) 0.015 0.015 0.050 0.050 0.100 0.100 0.201 0.201 cC/(mol/kg) 0.200 0.201 0.200 0.200 0.301 0.301 0.201 0.201 cD/(mol/kg) 0.497 0.998 0.499 1.005 0.509 1.005 0.203 0.503 /(g/cm3) 1.04248 1.05994 1.04981 1.06617 1.06836 1.08290 1.06631 1.07420
cB/(mol/kg) 0.251 0.250 0.301 cC/(mol/kg) 0.100 0.100 0.100 cD/(mol/kg) 0.103 0.300 0.100 /(g/cm3) 1.06296 1.06781 1.06935 Polymer (B): poly(ethylene glycol) 2010SAL Characterization: Mn/g.mol1 = 3000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.000 0.005 0.010 0.015 0.020 0.025 0.030 0.035 0.040 /(g/cm3) 0.99704 0.99782 0.99859 0.99937 1.00016 1.00093 1.00174 1.00253 1.00334
wB 0.045 0.050 /(g/cm3) 1.00417 1.00497
T/K = 308.15
wB 0.000 0.005 0.010 0.015 0.020 0.025 0.030 0.035 0.040 /(g/cm3) 0.99406 0.99478 0.99553 0.99633 0.99714 0.99789 0.99871 0.99951 1.00033
wB 0.045 0.050 /(g/cm3) 1.00113 1.00199
T/K = 318.15
wB 0.000 0.005 0.010 0.015 0.020 0.025 0.030 0.035 0.040 /(g/cm3) 0.99024 0.99077 0.99137 0.99206 0.99278 0.99359 0.99426 0.99497 0.99573
wB 0.045 0.050 /(g/cm3) 0.99655 0.99731 Polymer (B): poly(ethylene glycol) 2009CRU Characterization: Mn/g.mol1 = 3000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00903 1.01824 1.02737 1.03769 1.04789 1.05714 1.06792 1.07721 1.08724
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.09117 1.09689 1.10060 1.10551 1.10914 1.11409
continued
________________________________________________________________________
continued
T/K = 288.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00819 1.01716 1.02604 1.03606 1.04592 1.05492 1.06536 1.07436 1.08407
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.08788 1.09344 1.09707 1.10180 1.10524 1.11008
T/K = 293.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00708 1.01584 1.02449 1.03425 1.04382 1.05256 1.06269 1.07141 1.08084
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.08452 1.08992 1.09343 1.09803 1.10141 1.10602
T/K = 298.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00573 1.01429 1.02275 1.03226 1.04158 1.05007 1.05990 1.06836 1.07752
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.08110 1.08633 1.08974 1.09423 1.09752 1.10203
T/K = 303.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00417 1.01254 1.02081 1.03009 1.03919 1.04745 1.05700 1.06523 1.07412
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.07759 1.08268 1.08601 1.09037 1.09358 1.09800
T/K = 308.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00240 1.01060 1.01870 1.02778 1.03665 1.04470 1.05400 1.06200 1.07065
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.07402 1.07898 1.08221 1.08647 1.08960 1.09392
T/K = 313.15
mB/mA 0.0546 0.1119 0.1784 0.2544 0.3418 0.4322 0.5516 0.6657 0.8200 /(g/cm3) 1.00044 1.00846 1.01643 1.02531 1.03396 1.04182 1.05089 1.05868 1.06710
mB/mA 0.8988 0.9982 1.1035 1.2201 1.3519 1.4932 /(g/cm3) 1.07038 1.07520 1.07837 1.08252 1.08557 1.08981
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 3350, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0100 0.0500 0.1000 0.1436 0.1946 0.2502 0.2992 0.3500 /(g/cm3) 1.00480 1.02487 1.04510 1.05938 1.07303 1.08424 1.09242 1.09926
cB/(mol/kg) 0.4004 /(g/cm3) 1.10487
T/K = 298.15
cB/(mol/kg) 0.0100 0.0500 0.1000 0.1436 0.1946 0.2502 0.2992 0.3500 /(g/cm3) 1.00248 1.02165 1.04095 1.05500 1.06711 1.07767 1.08538 1.09185
cB/(mol/kg) 0.4004 /(g/cm3) 1.09715
T/K = 308.15
cB/(mol/kg) 0.0100 0.0500 0.1000 0.1436 0.1946 0.2502 0.2992 0.3500 /(g/cm3) 0.99925 1.01766 1.03604 1.04903 1.06112 1.07079 1.07807 1.08421
cB/(mol/kg) 0.4004 /(g/cm3) 1.08924 Polymer (B): poly(ethylene glycol) 2009RE1 Characterization: Mn/g.mol1 = 3500-4500, PEG 4000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9970 1.0049 1.0136 1.0223 1.0313 1.0407 1.0492 1.0591 1.0684
wB 0.4500 0.5000 /(g/cm3) 1.0778 1.0856
T/K = 303.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9956 1.0035 1.0123 1.0212 1.0297 1.0387 1.0474 1.0565 1.0656
wB 0.4500 0.5000 /(g/cm3) 1.0745 1.0833
T/K = 308.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9940 1.0019 1.0103 1.0184 1.0270 1.0357 1.0448 1.0533 1.0627
wB 0.4500 0.5000 /(g/cm3) 1.0709 1.0791 continued
________________________________________________________________________
continued
T/K = 313.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9922 0.9996 1.0081 1.0164 1.0247 1.0333 1.0419 1.0511 1.0597
wB 0.4500 0.5000 /(g/cm3) 1.0684 1.0760
T/K = 318.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9902 0.9977 1.0057 1.0138 1.0225 1.0305 1.0389 1.0471 1.0557
wB 0.4500 0.5000 /(g/cm3) 1.0638 1.0711 Polymer (B): poly(ethylene glycol) 2009RE1 Characterization: Mn/g.mol1 = 3500-4500, PEG 4000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5 Salt (C): diammonium phosphate (NH4)2HPO4 7783-28-0
T/K = 298.15
wB 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0500 wC 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 /(g/cm3) 1.0111 1.0202 1.0282 1.0373 1.0463 1.0555 1.0647 1.0738 1.0180
wB 0.1000 0.1500 0.2000 0.2500 0.3000 0.0500 0.1000 0.1500 0.2000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 /(g/cm3) 1.0258 1.0348 1.0435 1.0492 1.0619 1.0239 1.0322 1.0415 1.0498
wB 0.2500 0.0500 0.1000 0.1500 0.2000 0.0500 0.1000 0.1500 0.0500 wC 0.0300 0.0400 0.0400 0.0400 0.0400 0.0500 0.0500 0.0500 0.0600 /(g/cm3) 1.0571 1.0310 1.0385 1.0467 1.0562 1.0371 1.0447 1.0541 1.0414
wB 0.1000 0.0500 0.0500 wC 0.0600 0.0700 0.0800 /(g/cm3) 1.0506 1.0493 1.0545
T/K = 303.15
wB 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0500 wC 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 /(g/cm3) 1.0105 1.0186 1.0272 1.0358 1.0442 1.0537 1.0619 1.0707 1.0166
wB 0.1000 0.1500 0.2000 0.2500 0.3000 0.0500 0.1000 0.1500 0.2000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 /(g/cm3) 1.0252 1.0340 1.0428 1.0516 1.0599 1.0227 1.0307 1.0399 1.0480
wB 0.2500 0.0500 0.1000 0.1500 0.2000 0.0500 0.1000 0.1500 0.0500 wC 0.0300 0.0400 0.0400 0.0400 0.0400 0.0500 0.0500 0.0500 0.0600 /(g/cm3) 1.0564 1.0292 1.0375 1.0570 1.0549 1.0351 1.0429 1.0519 1.0411
continued
________________________________________________________________________
continued
wB 0.1000 0.0500 0.0500 wC 0.0600 0.0700 0.0800 /(g/cm3) 1.0498 1.0469 1.0533
T/K = 308.15
wB 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0500 wC 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 /(g/cm3) 1.0080 1.0163 1.0245 1.0334 1.0415 1.0502 1.0587 1.0674 1.0145
wB 0.1000 0.1500 0.2000 0.2500 0.3000 0.0500 0.1000 0.1500 0.2000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 /(g/cm3) 1.0226 1.0312 1.0397 1.0482 1.0570 1.0202 1.0283 1.0370 1.0449
wB 0.2500 0.0500 0.1000 0.1500 0.2000 0.0500 0.1000 0.1500 0.0500 wC 0.0300 0.0400 0.0400 0.0400 0.0400 0.0500 0.0500 0.0500 0.0600 /(g/cm3) 1.0538 1.0266 1.0348 1.0539 1.0518 1.0322 1.0404 1.0490 1.0390
wB 0.1000 0.0500 0.0500 wC 0.0600 0.0700 0.0800 /(g/cm3) 1.0470 1.0443 1.0509
T/K = 313.15
wB 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0500 wC 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 /(g/cm3) 1.0063 1.0138 1.0222 1.0308 1.0390 1.0479 1.0564 1.0663 1.0126
wB 0.1000 0.1500 0.2000 0.2500 0.3000 0.0500 0.1000 0.1500 0.2000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 /(g/cm3) 1.0206 1.0286 1.0367 1.0449 1.0536 1.0190 1.0263 1.0352 1.0429
wB 0.2500 0.0500 0.1000 0.1500 0.2000 0.0500 0.1000 0.1500 0.0500 wC 0.0300 0.0400 0.0400 0.0400 0.0400 0.0500 0.0500 0.0500 0.0600 /(g/cm3) 1.0498 1.0257 1.0325 1.0402 1.0491 1.0314 1.0386 1.0476 1.0359
wB 0.1000 0.0500 0.0500 wC 0.0600 0.0700 0.0800 /(g/cm3) 1.0446 1.0437 1.0491
T/K = 318.15
wB 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0500 wC 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 /(g/cm3) 1.0036 1.0119 1.0204 1.0283 1.0364 1.0441 1.0528 1.0609 1.0100
wB 0.1000 0.1500 0.2000 0.2500 0.3000 0.0500 0.1000 0.1500 0.2000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 /(g/cm3) 1.0177 1.0267 1.0339 1.0419 1.0502 1.0167 1.0241 1.0322 1.0398
continued
________________________________________________________________________
continued
wB 0.2500 0.0500 0.1000 0.1500 0.2000 0.0500 0.1000 0.1500 0.0500 wC 0.0300 0.0400 0.0400 0.0400 0.0400 0.0500 0.0500 0.0500 0.0600 /(g/cm3) 1.0461 1.0232 1.0304 1.0383 1.0470 1.0282 1.0356 1.0454 1.0330
wB 0.1000 0.0500 0.0500 wC 0.0600 0.0700 0.0800 /(g/cm3) 1.0425 1.0405 1.0458 Polymer (B): poly(ethylene glycol) 2009PER Characterization: Mn/g.mol1 = 4000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99700 1.00487 1.01327 1.02219 1.03160 1.04037 1.04924 1.05854 1.06756
wB 0.45 0.50 /(g/cm3) 1.07612 1.08394
T/K = 308.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99560 1.00314 1.01168 1.02082 1.02976 1.03830 1.04754 1.05638 1.06562
wB 0.45 0.50 /(g/cm3) 1.07446 1.08250
T/K = 318.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 /(g/cm3) 0.99400 1.00135 1.00939 1.01787 1.02673 1.03501 1.04412 1.05284 1.06209
wB 0.45 0.50 /(g/cm3) 1.07097 1.07789 Polymer (B): poly(ethylene glycol) 2009PER Characterization: Mn/g.mol1 = 4000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium citrate Na3C6H5O7 68-04-2
T/K = 298.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.01117 1.01933 1.02835 1.03751 1.04588 1.05629 1.06494 1.07236 1.08344
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.00 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.02264 1.03026 1.04071 1.04843 1.05767 1.06647 1.07568 1.08422 1.03437
continued
________________________________________________________________________
continued
wB 0.05 0.10 0.15 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.04309 1.05271 1.06127 1.07083 1.08027 1.04805 1.05672 1.06559 1.07488
wB 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.08 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.08342 1.08985 1.06193 1.07035 1.07878 1.08744
T/K = 308.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.00682 1.01558 1.02493 1.03484 1.04364 1.05213 1.06158 1.06970 1.07802
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.00 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.01818 1.02882 1.03621 1.04541 1.05427 1.06423 1.07152 1.08148 1.03093
wB 0.05 0.10 0.15 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.03958 1.04923 1.05924 1.06773 1.07612 1.04324 1.05319 1.06321 1.07239
wB 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.08 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.08033 1.08705 1.05892 1.06671 1.07487 1.08389
T/K = 318.15
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 /(g/cm3) 1.00282 1.01206 1.02067 1.02911 1.03775 1.04621 1.05481 1.06257 1.06980
wB 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.00 wC 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.06 /(g/cm3) 1.01415 1.02415 1.03312 1.04073 1.04863 1.05926 1.06576 1.07325 1.02646
wB 0.05 0.10 0.15 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.06 0.06 0.06 0.06 0.06 0.08 0.08 0.08 0.08 /(g/cm3) 1.03559 1.04488 1.05486 1.06345 1.07078 1.03968 1.04726 1.05783 1.06770
wB 0.20 0.25 0.00 0.05 0.10 0.15 wC 0.08 0.08 0.10 0.10 0.10 0.10 /(g/cm3) 1.07543 1.08146 1.05467 1.06339 1.07182 1.08046 Polymer (B): poly(ethylene glycol) 2007KUS Characterization: Mn/g.mol1 = 4000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
cB/(mol/kg) 0.00000 0.02749 0.05906 0.09871 0.14892 0.21606 /(g/cm3) 0.997047 1.013559 1.029182 1.045862 1.062210 1.078940
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2009SIN Characterization: Mw/g.mol1 = 4000, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
wB = 0.10 was kept constant
T/K 308 313 318 323 324 325 326 327 328 /(kg/m3) 1015.76 1013.94 1010.31 1005.81 1004.92 1003.13 1002.24 1001.36 1000.47
T/K 329 333 338 /(kg/m3) 998.70 995.18 991.69 Polymer (B): poly(ethylene glycol) 2007SIL Characterization: Mw/g.mol1 = 4000, Isofar, Rio de Janeiro, Brazil Solvent (A): water H2O 7732-18-5
T/K = 278.15
wB 0.05 0.10 0.20 0.30 /(g/cm3) 1.00738 1.01633 1.03372 1.05228
T/K = 298.15
wB 0.05 0.10 0.20 0.30 /(g/cm3) 1.00689 1.01466 1.03820 1.05272
T/K = 308.15
wB 0.05 0.10 0.20 0.30 /(g/cm3) 1.00377 1.01097 1.02861 1.04423
T/K = 318.15
wB 0.05 0.10 0.20 0.30 /(g/cm3) 0.99955 1.00681 1.02654 1.04162 Polymer (B): poly(ethylene glycol) 2005TAB Characterization: Mw/g.mol1 = 4000, Mw/Mn = 1.1, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): potassium chloride KCl 7447-40-7
T/K = 333.15
wB 0.0000 0.0446 0.0955 0.1273 0.1880 0.2120 0.2211 0.3005 0.3129 wC 0.2667 0.2443 0.2227 0.2067 0.1852 0.1803 0.1774 0.1514 0.1474 /(g/cm3) 1.17720 1.17064 1.16816 1.16606 1.16052 1.16046 1.15798 1.15475 1.15422
wB 0.4018 0.4528 0.4932 0.5271 wC 0.1226 0.1080 0.0995 0.0885 /(g/cm3) 1.15277 1.15262 1.15280 1.15211
T/K = 333.15
wB 0.0000 0.0446 0.0713 0.1272 0.1856 0.2120 0.2747 0.3597 0.3852 wC 0.2628 0.2530 0.2402 0.2202 0.1957 0.1919 0.1646 0.1407 0.1337 /(g/cm3) 1.19778 1.19276 1.19000 1.18484 1.17990 1.17811 1.17328 1.16735 1.16789
wB 0.4430 0.4735 0.4866 wC 0.1172 0.1086 0.1047 /(g/cm3) 1.16570 1.16448 1.16369 Polymer (B): poly(ethylene glycol) 2005ZAF Characterization: Mn/g.mol1 = 5890, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
cB/(mol/kg) 0.0036 0.0186 0.0408 0.0557 0.0881 /(g/cm3) 1.000477 1.013575 1.030120 1.039721 1.057243
T/K = 308.15
cB/(mol/kg) 0.0036 0.0186 0.0408 0.0557 0.0881 /(g/cm3) 0.997353 1.009922 1.025751 1.034919 1.051547
T/K = 318.15
cB/(mol/kg) 0.0036 0.0186 0.0408 0.0557 0.0881 /(g/cm3) 0.993436 1.005571 1.020756 1.029526 1.045141 Polymer (B): poly(ethylene glycol) 2005ZAF Characterization: Mn/g.mol1 = 5890, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): disodium succinate C4H4Na2O4 150-90-3
T/K = 298.15
cB/(mol/kg) 0.0022 0.0064 0.1250 0.0173 0.0332 0.0409 0.0463 0.0829 cC/(mol/kg) 0.7921 0.7288 0.6916 0.7052 0.5402 0.3293 0.4886 0.3909 /(g/cm3) 1.07407 1.07086 1.07089 1.07447 1.06928 1.05692 1.07168 1.08040
cB/(mol/kg) 0.1015 cC/(mol/kg) 0.3399 /(g/cm3) 1.08389
continued
________________________________________________________________________
continued
T/K = 308.15
cB/(mol/kg) 0.0022 0.0064 0.1250 0.0173 0.0332 0.0409 0.0463 0.0829 cC/(mol/kg) 0.7921 0.7288 0.6916 0.7052 0.5402 0.3293 0.4886 0.3909 /(g/cm3) 1.07003 1.06676 1.06668 1.07011 1.06461 1.05222 1.06673 1.07460
cB/(mol/kg) 0.1015 cC/(mol/kg) 0.3399 /(g/cm3) 1.07771
T/K = 318.15
cB/(mol/kg) 0.0022 0.0064 0.1250 0.0173 0.0332 0.0409 0.0463 0.0829 cC/(mol/kg) 0.7921 0.7288 0.6916 0.7052 0.5402 0.3293 0.4886 0.3909 /(g/cm3) 1.06552 1.06216 1.06196 1.06528 1.05948 1.04702 1.06127 1.06839
cB/(mol/kg) 0.1015 cC/(mol/kg) 0.3399 /(g/cm3) 1.07123 Polymer (B): poly(ethylene glycol) 2005ZAF Characterization: Mn/g.mol1 = 5890, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium formate CHNaO2 141-53-7
T/K = 298.15
cB/(mol/kg) 0.0021 0.0067 0.0128 0.0169 0.0218 0.0331 0.0471 0.0575 cC/(mol/kg) 3.0622 2.9567 2.6354 2.5645 2.3062 2.2243 2.1152 1.1330 /(g/cm3) 1.10872 1.10690 1.09910 1.09845 1.09247 1.09422 1.09612 1.07354
cB/(mol/kg) 0.0642 0.0841 cC/(mol/kg) 1.9323 2.1382 /(g/cm3) 1.09694 1.10733
T/K = 308.15
cB/(mol/kg) 0.0021 0.0067 0.0128 0.0169 0.0218 0.0331 0.0471 0.0575 cC/(mol/kg) 3.0622 2.9567 2.6354 2.5645 2.3062 2.2243 2.1152 1.1330 /(g/cm3) 1.10398 1.10220 1.09434 1.09358 1.08764 1.08916 1.09076 1.06819
cB/(mol/kg) 0.0642 0.0841 cC/(mol/kg) 1.9323 2.1382 /(g/cm3) 1.09130 1.10118
T/K = 318.15
cB/(mol/kg) 0.0021 0.0067 0.0128 0.0169 0.0218 0.0331 0.0471 0.0575 cC/(mol/kg) 3.0622 2.9567 2.6354 2.5645 2.3062 2.2243 2.1152 1.1330 /(g/cm3) 1.09889 1.09700 1.08917 1.08831 1.08237 1.08369 1.08503 1.06254
cB/(mol/kg) 0.0642 0.0841 cC/(mol/kg) 1.9323 2.1382 /(g/cm3) 1.08524 1.09481
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2003RAH Characterization: Mn/g.mol1 = 6000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 308.15
wB 0.3552 0.2931 0.1974 0.1913 0.1076 0.0982 0.0793 0.0601 0.0399 /(g/cm3) 1.0530 1.0447 1.0281 1.0260 1.0115 1.0084 1.0042 0.9990 0.9960
T/K = 318.15
wB 0.3552 0.2931 0.1974 0.1913 0.1076 0.0982 0.0793 0.0601 0.0399 /(g/cm3) 1.0478 1.0343 1.0230 1.0208 1.0053 1.0021 0.9980 0.9938 0.9897
T/K = 328.15
wB 0.3552 0.2931 0.1974 0.1913 0.1076 0.0982 0.0793 0.0601 0.0399 /(g/cm3) 1.0416 1.0314 1.0150 1.0146 1.0000 0.9959 0.9928 0.9897 0.9866 Polymer (B): poly(ethylene glycol) 2009RE2 Characterization: Mn/g.mol1 = 6000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9970 1.0051 1.0137 1.0217 1.0311 1.0397 1.0487 1.0584 1.0679
wB 0.4500 0.5000 /(g/cm3) 1.0766 1.0856
T/K = 303.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9956 1.0047 1.0125 1.0213 1.0297 1.0386 1.0474 1.0566 1.0656
wB 0.4500 0.5000 /(g/cm3) 1.0742 1.0833
T/K = 308.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9940 1.0022 1.0105 1.0190 1.0273 1.0358 1.0448 1.0539 1.0628
wB 0.4500 0.5000 /(g/cm3) 1.0714 1.0799
T/K = 313.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9922 1.0006 1.0088 1.0167 1.0248 1.0339 1.0428 1.0512 1.0597
wB 0.4500 0.5000 /(g/cm3) 1.0694 1.0779
continued
________________________________________________________________________
continued
T/K = 318.15
wB 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 /(g/cm3) 0.9902 0.9977 1.0060 1.0135 1.0222 1.0305 1.0390 1.0470 1.0559
wB 0.4500 0.5000 /(g/cm3) 1.0638 1.0716 Polymer (B): poly(ethylene glycol) 2009RE2 Characterization: Mn/g.mol1 = 6000, Merck-Schuchardt, Hohenbrunn, Germany Solvent (A): water H2O 7732-18-5 Salt (C): ammonium citrate (NH4)3C6H5O7 3458-72-8
T/K = 298.15
wB 0.5000 0.4500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 /(g/cm3) 1.0948 1.0862 1.0767 1.0680 1.0590 1.0498 1.0412 1.0319 1.0230
wB 0.0500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 0.0500 wC 0.0200 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 /(g/cm3) 1.0148 1.0859 1.0771 1.0683 1.0588 1.0502 1.0409 1.0322 1.0238
wB 0.2500 0.2000 0.1500 0.1000 0.0500 0.2000 0.1500 0.1000 0.0500 wC 0.0600 0.0600 0.0600 0.0600 0.0600 0.0800 0.0800 0.0800 0.0800 /(g/cm3) 1.0676 1.0589 1.0498 1.0412 1.0323 1.0678 1.0589 1.0502 1.0410
wB 0.1000 0.0500 wC 0.1000 0.1000 /(g/cm3) 1.0592 1.0502
T/K = 303.15
wB 0.5000 0.4500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 /(g/cm3) 1.0929 1.0846 1.0750 1.0662 1.0575 1.0483 1.0386 1.0307 1.0213
wB 0.0500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 0.0500 wC 0.0200 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 /(g/cm3) 1.0129 1.0838 1.0755 1.0668 1.0577 1.0478 1.0382 1.0299 1.0213
wB 0.2500 0.2000 0.1500 0.1000 0.0500 0.2000 0.1500 0.1000 0.0500 wC 0.0600 0.0600 0.0600 0.0600 0.0600 0.0800 0.0800 0.0800 0.0800 /(g/cm3) 1.0666 1.0570 1.0487 1.0402 1.0320 1.0668 1.0579 1.0491 1.0402
wB 0.1000 0.0500 wC 0.1000 0.1000 /(g/cm3) 1.0584 1.0492
continued
________________________________________________________________________
continued
T/K = 308.15
wB 0.5000 0.4500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 /(g/cm3) 1.0875 1.0798 1.0710 1.0624 1.0532 1.0447 1.0354 1.0278 1.0180
wB 0.0500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 0.0500 wC 0.0200 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 /(g/cm3) 1.0097 1.0795 1.0710 1.0629 1.0535 1.0449 1.0351 1.0282 1.0189
wB 0.2500 0.2000 0.1500 0.1000 0.0500 0.2000 0.1500 0.1000 0.0500 wC 0.0600 0.0600 0.0600 0.0600 0.0600 0.0800 0.0800 0.0800 0.0800 /(g/cm3) 1.0632 1.0540 1.0456 1.0367 1.0290 1.0632 1.0545 1.0461 1.0370
wB 0.1000 0.0500 wC 0.1000 0.1000 /(g/cm3) 1.0550 1.0467
T/K = 313.15
wB 0.5000 0.4500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 /(g/cm3) 1.0835 1.0759 1.0669 1.0591 1.0497 1.0419 1.0329 1.0254 1.0165
wB 0.0500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 0.0500 wC 0.0200 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 /(g/cm3) 1.0094 1.0757 1.0679 1.0585 1.0508 1.0408 1.0339 1.0252 1.0179
wB 0.2500 0.2000 0.1500 0.1000 0.0500 0.2000 0.1500 0.1000 0.0500 wC 0.0600 0.0600 0.0600 0.0600 0.0600 0.0800 0.0800 0.0800 0.0800 /(g/cm3) 1.0597 1.0501 1.0432 1.0336 1.0263 1.0592 1.0515 1.0420 1.0347
wB 0.1000 0.0500 wC 0.1000 0.1000 /(g/cm3) 1.0514 1.0436
T/K = 318.15
wB 0.5000 0.4500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 wC 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 /(g/cm3) 1.0805 1.0718 1.0643 1.0567 1.0483 1.0398 1.0306 1.0231 1.0149
wB 0.0500 0.4000 0.3500 0.3000 0.2500 0.2000 0.1500 0.1000 0.0500 wC 0.0200 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 /(g/cm3) 1.0064 1.0732 1.0642 1.0562 1.0472 1.0398 1.0323 1.0244 1.0160
wB 0.2500 0.2000 0.1500 0.1000 0.0500 0.2000 0.1500 0.1000 0.0500 wC 0.0600 0.0600 0.0600 0.0600 0.0600 0.0800 0.0800 0.0800 0.0800 /(g/cm3) 1.0562 1.0492 1.0408 1.0326 1.0235 1.0566 1.0491 1.0409 1.0333
wB 0.1000 0.0500 wC 0.1000 0.1000 /(g/cm3) 1.0491 1.0412
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2004CRU Characterization: Mw/g.mol1 = 6000, Isofar, Rio de Janeiro, Brazil Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00794 1.01633 1.02352 1.03010 1.03700 1.04312 1.04766 1.05381 1.05921
wB 0.5031 0.5493 /(g/cm3) 1.06387 1.06799
T/K = 288.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00714 1.01532 1.02231 1.02872 1.03542 1.04135 1.04576 1.05173 1.05696
wB 0.5031 0.5493 /(g/cm3) 1.06150 1.06548
T/K = 293.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00606 1.01405 1.02087 1.02710 1.03363 1.03940 1.04368 1.04948 1.05455
wB 0.5031 0.5493 /(g/cm3) 1.05897 1.06281
T/K = 298.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00474 1.01252 1.01921 1.02530 1.03166 1.03727 1.04144 1.04708 1.05201
wB 0.5031 0.5493 /(g/cm3) 1.05631 1.06006
T/K = 303.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00319 1.01084 1.01736 1.02330 1.02952 1.03500 1.03905 1.04455 1.04936
wB 0.5031 0.5493 /(g/cm3) 1.05353 1.05718
T/K = 308.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 1.00144 1.00894 1.01533 1.02115 1.02723 1.03257 1.03653 1.04189 1.04657
wB 0.5031 0.5493 /(g/cm3) 1.05064 1.05419
T/K = 313.15
wB 0.0483 0.1009 0.1494 0.1976 0.2500 0.3018 0.3412 0.3981 0.4525 /(g/cm3) 0.99949 1.00679 1.01312 1.01882 1.02477 1.02999 1.03387 1.03911 1.04368
wB 0.5031 0.5493 /(g/cm3) 1.04764 1.05108
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2009CRU Characterization: Mn/g.mol1 = 6000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00872 1.01832 1.02812 1.03744 1.04792 1.05722 1.06849 1.07761 1.08222
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.08736 1.09181 1.09696 1.10129 1.10608 1.10980 1.11390
T/K = 288.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00789 1.01724 1.02677 1.03582 1.04600 1.05500 1.06594 1.07473 1.07923
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.08418 1.08843 1.09344 1.09763 1.10229 1.10590 1.10990
T/K = 293.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00679 1.01591 1.02520 1.03401 1.04391 1.05264 1.06324 1.07178 1.07614
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.08096 1.08507 1.08986 1.09393 1.09846 1.10198 1.10588
T/K = 298.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00545 1.01437 1.02344 1.03202 1.04167 1.05014 1.06045 1.06873 1.07296
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.07766 1.08164 1.08624 1.09018 1.09460 1.09801 1.10181
T/K = 303.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00388 1.01261 1.02148 1.02987 1.03928 1.04752 1.05754 1.06559 1.06969
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.07425 1.07813 1.08262 1.08641 1.09066 1.09400 1.09772
T/K = 308.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00212 1.01068 1.01935 1.02756 1.03675 1.04476 1.05454 1.06237 1.06636
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.07079 1.07456 1.07893 1.08262 1.08676 1.08994 1.09358
T/K = 313.15
mB/mA 0.0553 0.1128 0.1786 0.2525 0.3344 0.4299 0.5407 0.6689 0.7412 /(g/cm3) 1.00016 1.00855 1.01706 1.02509 1.03409 1.04190 1.05141 1.05903 1.06294
mB/mA 0.8201 0.9026 1.0014 1.1056 1.2190 1.3521 1.4986 /(g/cm3) 1.06725 1.07092 1.07518 1.07878 1.08281 1.08589 1.08940
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2010SA2 Characterization: Mn/g.mol1 = 6000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium 1-pentanesulfonate C5H11NaO3S 22767-49-3
wB = 0.02 was kept constant
T/K = 288.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 1.00427 1.01011 1.01898 1.02629 1.03668 1.04649 1.06055 1.07181
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.08828 1.10046 1.11787
T/K = 293.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 1.00327 1.00901 1.01772 1.02491 1.03511 1.04473 1.05849 1.06955
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.08581 1.09784 1.11506
T/K = 298.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 1.00201 1.00766 1.01624 1.02331 1.03334 1.04278 1.05629 1.06716
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.08322 1.09514 1.11217
T/K = 303.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 1.00052 1.00610 1.01455 1.02152 1.03139 1.04067 1.05395 1.06466
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.08055 1.09234 1.10922
T/K = 308.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 0.99883 1.00433 1.01268 1.01955 1.02927 1.03841 1.05147 1.06205
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.07778 1.08947 1.10619
T/K = 313.15
cC/(mol/kg) 0.0297 0.1318 0.2930 0.4322 0.6394 0.8485 1.1688 1.4643 /(g/cm3) 0.99694 1.00238 1.01062 1.01740 1.02699 1.03600 1.04887 1.05932
cC/(mol/kg) 1.9705 2.4025 3.0987 /(g/cm3) 1.07492 1.08652 1.10310
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2010SA1 Characterization: Mn/g.mol1 = 6000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): sodium tungstate Na2WO4 13472-45-2
wB = 0.02 was kept constant
T/K = 288.15
cC/(mol/kg) 0.0000 0.0118 0.0906 0.1227 0.1907 0.2575 0.3282 0.4393 /(g/cm3) 1.00245 1.00559 1.02642 1.03493 1.05271 1.06990 1.08806 1.11657
cC/(mol/kg) 0.4811 0.5588 0.6967 0.9125 0.9733 /(g/cm3) 1.12716 1.14637 1.18039 1.23265 1.24740
T/K = 293.15
cC/(mol/kg) 0.0000 0.0118 0.0906 0.1227 0.1907 0.2575 0.3282 0.4393 /(g/cm3) 1.00148 1.00460 1.02533 1.03379 1.05149 1.06860 1.08668 1.11508
cC/(mol/kg) 0.4811 0.5588 0.6967 0.9125 0.9733 /(g/cm3) 1.12562 1.14476 1.17864 1.23073 1.24543
T/K = 298.15
cC/(mol/kg) 0.0000 0.0118 0.0906 0.1227 0.1907 0.2575 0.3282 0.4393 /(g/cm3) 1.00025 1.00335 1.02400 1.03242 1.05005 1.06709 1.08510 1.11339
cC/(mol/kg) 0.4811 0.5588 0.6967 0.9125 0.9733 /(g/cm3) 1.12389 1.14296 1.17673 1.22865 1.24330
T/K = 303.15
cC/(mol/kg) 0.0000 0.0118 0.0906 0.1227 0.1907 0.2575 0.3282 0.4393 /(g/cm3) 0.99878 1.00188 1.02245 1.03084 1.04840 1.06538 1.08332 1.11152
cC/(mol/kg) 0.4811 0.5588 0.6967 0.9125 0.9733 /(g/cm3) 1.12199 1.14100 1.17466 1.22643 1.24104
T/K = 308.15
cC/(mol/kg) 0.0000 0.0118 0.0906 0.1227 0.1907 0.2575 0.3282 0.4393 /(g/cm3) 0.99711 1.00020 1.02069 1.02906 1.04656 1.06349 1.08137 1.10948
cC/(mol/kg) 0.4811 0.5588 0.6967 0.9125 0.9733 /(g/cm3) 1.11992 1.13887 1.17244 1.22407 1.23875 Polymer (B): poly(ethylene glycol) 2010MIN Characterization: Mw/g.mol1 = 6000, Isofar, Rio de Janeiro, Brazil Solvent (A): water H2O 7732-18-5
T/K = 288.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1007.3 1011.1 1014.4 1018.0 1021.5 continued
________________________________________________________________________
continued
T/K = 293.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1004.4 1008.4 1011.6 1015.4 1018.8
T/K = 298.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1004.1 1006.8 1010.5 1013.1 1017.5
T/K = 303.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1000.6 1005.0 1008.4 1010.9 1014.3
T/K = 308.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 999.6 1004.3 1007.0 1010.4 1012.8
T/K = 313.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 998.2 1001.2 1004.5 1007.6 1010.1
T/K = 318.15
wB 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 996.6 999.8 1002.6 1005.3 1007.2 Polymer (B): poly(ethylene glycol) 2010MIN Characterization: Mw/g.mol1 = 6000, Isofar, Rio de Janeiro, Brazil Solvent (A): water H2O 7732-18-5 Polymer (C): poly(sodium acrylate) Characterization: Mw/g.mol1 = 8000, Aldrich Chem. Co., Inc., Milwaukee, WI
T/K = 288.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1021.8 1031.1 1039.4 1046.8 1056.1 1023.6 1032.3 1040.2 1049.6
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1056.5 1024.5 1034.7 1042.8 1050.3 1059.2 1027.5 1035.3 1043.6
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1052.6 1061.4 1029.0 1037.8 1045.9 1054.2 1062.7
continued
________________________________________________________________________
continued
T/K = 293.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1019.0 1027.8 1036.5 1044.2 1052.6 1020.5 1029.1 1037.8 1046.6
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1053.7 1022.6 1031.0 1039.2 1048.1 1056.1 1024.8 1033.3 1041.6
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1049.9 1058.6 1026.4 1034.5 1043.9 1051.2 1059.8
T/K = 298.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1017.0 1026.7 1034.4 1042.3 1050.9 1018.6 1026.5 1035.5 1044.8
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1052.2 1020.8 1029.8 1037.1 1045.1 1053.3 1022.7 1030.6 1038.8
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1047.7 1055.5 1023.7 1032.1 1040.9 1048.8 1057.3
T/K = 303.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1015.0 1024.1 1031.6 1040.0 1048.3 1017.0 1024.9 1033.4 1042.3
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1049.5 1019.0 1027.0 1034.6 1043.0 1051.2 1020.3 1028.1 1036.1
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1044.1 1053.6 1022.6 1029.7 1038.2 1046.3 1054.8
T/K = 308.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1013.6 1022.3 1030.4 1038.6 1046.5 1017.3 1023.2 1031.7 1040.0
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1048.2 1018.7 1025.3 1032.6 1041.2 1049.4 1021.0 1026.5 1034.6
continued
________________________________________________________________________
continued
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1042.9 1051.4 1022.2 1028.2 1036.0 1044.7 1052.9
T/K = 313.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1010.4 1019.8 1027.8 1036.2 1044.6 1014.1 1021.4 1029.6 1037.8
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1045.1 1016.3 1023.5 1030.7 1038.2 1047.1 1018.0 1024.0 1032.0
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1040.6 1048.7 1018.9 1025.6 1034.2 1042.7 1050.7
T/K = 318.15
wB 0.04 0.04 0.04 0.04 0.04 0.06 0.06 0.06 0.06 wC 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 0.10 /(kg/m3) 1008.7 1017.0 1024.7 1032.6 1040.3 1012.6 1017.8 1026.2 1033.0
wB 0.06 0.08 0.08 0.08 0.08 0.08 0.10 0.10 0.10 wC 0.12 0.04 0.06 0.08 0.10 0.12 0.04 0.06 0.08 /(kg/m3) 1040.5 1013.1 1019.3 1026.3 1034.0 1041.4 1016.3 1021.3 1028.9
wB 0.10 0.10 0.12 0.12 0.12 0.12 0.12 wC 0.10 0.12 0.04 0.06 0.08 0.10 0.12 /(kg/m3) 1036.7 1044.5 1017.8 1027.3 1029.8 1037.9 1045.1 Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 8000, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0250 0.0493 0.0740 0.0998 /(g/cm3) 1.00047 1.00575 1.01200 1.02870 1.05090 1.06838 1.08260
T/K = 298.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0250 0.0493 0.0740 0.0998 /(g/cm3) 0.99835 1.00339 1.00931 1.02532 1.04640 1.06278 1.07600
T/K = 308.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0250 0.0493 0.0740 0.0998 /(g/cm3) 0.99530 1.00017 1.00592 1.02118 1.04117 1.05671 1.06930
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2009CRU Characterization: Mn/g.mol1 = 10000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00918 1.01829 1.02864 1.03722 1.04758 1.05722 1.06771 1.07745 1.08749
mB/mA 0.9997 1.2241 /(g/cm3) 1.09756 1.10602
T/K = 288.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00836 1.01721 1.02729 1.03561 1.04567 1.05501 1.06521 1.07454 1.08429
mB/mA 0.9997 1.2241 /(g/cm3) 1.09405 1.10219
T/K = 293.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00725 1.01589 1.02570 1.03381 1.04359 1.05266 1.06257 1.07161 1.08101
mB/mA 0.9997 1.2241 /(g/cm3) 1.09048 1.09839
T/K = 298.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00590 1.01434 1.02393 1.03182 1.04136 1.05017 1.05980 1.06858 1.07765
mB/mA 0.9997 1.2241 /(g/cm3) 1.08683 1.09452
T/K = 303.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00433 1.01260 1.02393 1.02968 1.03898 1.04755 1.05692 1.06547 1.07421
mB/mA 0.9997 1.2241 /(g/cm3) 1.08314 1.09063
T/K = 308.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00254 1.01066 1.01982 1.02737 1.03645 1.04481 1.05394 1.06226 1.07075
mB/mA 0.9997 1.2241 /(g/cm3) 1.07939 1.08668
T/K = 313.15
mB/mA 0.0552 0.1134 0.1865 0.2444 0.3385 0.4361 0.5454 0.6646 0.8184 /(g/cm3) 1.00056 1.00854 1.01752 1.02491 1.03379 1.04195 1.05083 1.05894 1.06724
mB/mA 0.9997 1.2241 /(g/cm3) 1.07556 1.08269
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2008AYR Characterization: Mw/g.mol1 = 10000, Sigma Chemical Co., St. Louis, MO Solvent (A): water H2O 7732-18-5
T/K = 288.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0200 0.0299 0.0399 0.0500 /(g/cm3) 1.00077 1.00733 1.01497 1.02870 1.04080 1.05142 1.06078
T/K = 298.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0200 0.0299 0.0399 0.0500 /(g/cm3) 0.99864 1.00492 1.01221 1.02529 1.03676 1.04679 1.05565
T/K = 308.15
cB/(mol/kg) 0.0010 0.0050 0.0100 0.0200 0.0299 0.0399 0.0500 /(g/cm3) 0.99557 1.00160 1.00860 1.02112 1.03207 1.04161 1.05001 Polymer (B): poly(ethylene glycol) 2005MOH Characterization: Mn/g.mol1 = 9000-11250, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 298.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0186 1.0278 1.0384 1.0466 1.0549 1.0655 1.0737 1.0839 1.0935
T/K = 303.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0159 1.0271 1.0369 1.0447 1.0538 1.0627 1.0732 1.0811 1.0895
T/K = 308.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0150 1.0254 1.0350 1.0438 1.0505 1.0606 1.0698 1.0780 1.0860
T/K = 313.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0143 1.0244 1.0317 1.0407 1.0490 1.0570 1.0677 1.0761 1.0826
T/K = 318.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0120 1.0200 1.0291 1.0373 1.0460 1.0552 1.0639 1.0720 1.0804
T/K = 323.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0102 1.0197 1.0268 1.0344 1.0425 1.0510 1.0612 1.0683 1.0746
T/K = 328.15
wB 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 /(g/cm3) 1.0069 1.0168 1.0232 1.0313 1.0399 1.0484 1.0570 1.0647 1.0711
________________________________________________________________________ Polymer (B): poly(ethylene glycol) 2009CRU Characterization: Mn/g.mol1 = 20000, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00913 1.01884 1.02951 1.03836 1.04810 1.05712 1.06740 1.07807 1.08319
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.08962 1.09305 1.09877 1.10208 1.10712
T/K = 288.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00828 1.01775 1.02812 1.03673 1.04619 1.05487 1.06485 1.07516 1.08013
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.08636 1.08951 1.09504 1.09832 1.10329
T/K = 293.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00718 1.01641 1.02652 1.03491 1.04410 1.05254 1.06217 1.07218 1.07699
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.08303 1.08594 1.09132 1.09444 1.09937
T/K = 298.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00583 1.01485 1.02472 1.03290 1.04185 1.05008 1.05937 1.06909 1.07377
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.07963 1.08245 1.08767 1.09053 1.09538
T/K = 303.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00426 1.01309 1.02274 1.03073 1.03946 1.04749 1.05908 1.06592 1.07047
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.07617 1.07890 1.08398 1.08675 1.09133
T/K = 308.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00248 1.01114 1.02059 1.02841 1.03693 1.04476 1.05345 1.06266 1.06708
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.07263 1.07528 1.08022 1.08291 1.08723
T/K = 313.15
mB/mA 0.0530 0.1138 0.1860 0.2554 0.3345 0.4292 0.5405 0.6684 0.7440 /(g/cm3) 1.00052 1.00902 1.01827 1.02592 1.03425 1.04190 1.05038 1.05929 1.06361
mB/mA 0.8219 0.9078 1.0034 1.1013 1.2264 /(g/cm3) 1.06901 1.07160 1.07641 1.07903 1.08313
________________________________________________________________________ Polymer (B): poly(ethylene glycol) dimethyl ether 2011SA2 Characterization: Mn/g.mol1 = 366, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99970 1.00024 1.00078 1.00186 1.00408 1.00636 1.01108 1.01353 1.01849
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.02374 1.03436 1.04490 1.05341 1.06142 1.06714 1.06876 1.06748 1.06299
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.05752 1.05276 1.04857
T/K = 288.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99910 0.99962 1.00013 1.00118 1.00331 1.00549 1.01002 1.01236 1.01708
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.02206 1.03212 1.04207 1.05009 1.05762 1.06294 1.06437 1.06301 1.05849
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.05300 1.04822 1.04402
T/K = 293.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99820 0.99870 0.99920 1.00021 1.00226 1.00436 1.00870 1.01095 1.01546
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.02019 1.02973 1.03914 1.04669 1.05376 1.05871 1.05995 1.05853 1.05398
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.04848 1.04368 1.03948
T/K = 298.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99704 0.99752 0.99801 0.99898 1.00096 1.00299 1.00717 1.00932 1.01363
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.01815 1.02721 1.03611 1.04322 1.04985 1.05445 1.05551 1.05403 1.04946
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.04395 1.03914 1.03496
T/K = 303.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99564 0.99611 0.99658 0.99752 0.99944 1.00140 1.00542 1.00749 1.01162
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.01594 1.02456 1.03297 1.03967 1.04589 1.05014 1.05104 1.04950 1.04493
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.03941 1.03461 1.03044 continued
________________________________________________________________________
continued
T/K = 308.15
wB 0.0000 0.0050 0.0101 0.0200 0.0400 0.0599 0.0999 0.1198 0.1594 /(g/cm3) 0.99403 0.99448 0.99494 0.99585 0.99771 0.99960 1.00348 1.00547 1.00944
wB 0.2001 0.2798 0.3599 0.4298 0.5098 0.5992 0.6790 0.7505 0.8388 /(g/cm3) 1.01357 1.02177 1.02974 1.03605 1.04187 1.04581 1.04655 1.04496 1.04038
wB 0.9093 0.9596 1.0000 /(g/cm3) 1.03487 1.03008 1.02594 Polymer (B): poly(ethylene glycol) dimethyl ether 2011SA2 Characterization: Mn/g.mol1 = 698, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5
T/K = 283.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 1.00038 1.00108 1.00245 1.00527 1.00815 1.01396 1.01703 1.02321 1.02937
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.04235 1.05544 1.06641 1.07795 1.08770 1.09278 1.09452 1.09352 1.09075
wB 0.9601 1.0000 /(g/cm3) 1.08874 solid
T/K = 288.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 0.99976 1.00043 1.00176 1.00450 1.00728 1.01290 1.01585 1.02181 1.02774
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.04018 1.05271 1.06321 1.07424 1.08359 1.08847 1.09014 1.08912 1.08636
wB 0.9601 1.0000 /(g/cm3) 1.08425 solid
T/K = 293.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 0.99885 0.99950 1.00079 1.00344 1.00614 1.01159 1.01445 1.02020 1.02590
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.03787 1.04987 1.05992 1.07048 1.07944 1.08413 1.08573 1.08470 1.08196
wB 0.9601 1.0000 /(g/cm3) 1.07953 1.07660
T/K = 298.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 0.99767 0.99830 0.99956 1.00214 1.00477 1.01005 1.01282 1.01839 1.02390
continued
________________________________________________________________________
continued
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.03541 1.04693 1.05655 1.06667 1.07525 1.07977 1.08131 1.08027 1.07755
wB 0.9601 1.0000 /(g/cm3) 1.07480 1.07209
T/K = 303.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 0.99625 0.99687 0.99810 1.00062 1.00318 1.00831 1.01100 1.01639 1.02172
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.03282 1.04389 1.05311 1.06280 1.07103 1.07547 1.07687 1.07584 1.07313
wB 0.9601 1.0000 /(g/cm3) 1.07016 1.06771
T/K = 308.15
wB 0.0050 0.0100 0.0199 0.0400 0.0600 0.0999 0.1200 0.1602 0.1998 /(g/cm3) 0.99462 0.99523 0.99643 0.99888 1.00138 1.00637 1.00899 1.01422 1.01938
wB 0.2797 0.3597 0.4290 0.5098 0.6000 0.6793 0.7510 0.8376 0.9082 /(g/cm3) 1.03009 1.04074 1.04959 1.05888 1.06677 1.07097 1.07241 1.07140 1.06872
wB 0.9601 1.0000 /(g/cm3) 1.06576 1.06337 Polymer (B): poly(ethylene glycol) dimethyl ether 2011SA2 Characterization: Mn/g.mol1 = 698, Merck, Darmstadt, Germany Solvent (A): water H2O 7732-18-5 Salt (C): diammonium phosphate (NH4)2HPO4 7783-28-0
Comments: The concentration of the salt is 0.5 mol/kg (NH4)2HPO4 in water.
