chapter  7
10 Pages

SECOND VIRIAL COEFFICIENTS (A[sub(2)]) OF AQUEOUS POLYMER SOLUTIONS

Acrylamide/maleic anhydride copolymer (50 mol% acrylamide) in 0.6 M NaNO3 aqueous solution 24400 298.15 3.0 1983ION ____________________________________________________________________________________

Acrylamide/sodium acrylate copolymer in 0.1 M Na2SO4 aqueous solution (3.7 mol% acrylamide) 6500000 298.15 2.8 1985KUL (5.6 mol% acrylamide) 6160000 298.15 6.8 1985KUL (9.4 mol% acrylamide) 6450000 298.15 7.7 1985KUL (36 mol% acrylamide) 6110000 298.15 9.7 1985KUL (55 mol% acrylamide) 5960000 298.15 8.4 1985KUL (70 mol% acrylamide) 5520000 298.15 4.8 1985KUL (83 mol% acrylamide) 5200000 298.15 3.8 1985KUL ____________________________________________________________________________________

Acrylamide/sodium 3-methylacrylamido3-methylbutanoate copolymer (31.7 mol% acrylamide) 2000000 298.15 3.2 1986MCC (42.7 mol% acrylamide) 4200000 298.15 3.3 1986MCC (58.1 mol% acrylamide) 6600000 298.15 3.5 1986MCC (70.4 mol% acrylamide) 6900000 298.15 3.1 1986MCC (87.9 mol% acrylamide) 7200000 298.15 3.2 1986MCC ____________________________________________________________________________________

Dextran 618 310.15 −40.5 1971GEK 618 333.15 −53.9 1971GEK

1220 310.15 − 5.36 1971GEK 1220 333.15 −18.8 1971GEK 1460 310.15 + 2.17 1971GEK 1460 333.15 − 6.19 1971GEK 2040 310.15 10.9 1971GEK 2040 333.15 12.0 1971GEK 4930 310.15 7.66 1971GEK 4930 333.15 9.36 1971GEK 8980 310.15 6.42 1971GEK

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____________________________________________________________________________________

Dextran 8980 333.15 8.60 1971GEK 9900 298.15 13.8 1993WUC

10100 298.15 8.2 1993HAY 39700 298.15 9.2 1993WUC

23600 40000 293.15 13.1 1993GAU 23600 40000 313.15 12.4 1993GAU 23600 40000 333.15 9.3 1993GAU

43400 298.15 5.0 1993HAY 65000 298.15 7.7 1993WUC 68100 298.15 4.0 1993HAY

29630 74540 298.15 8.5 1989HAY 46300 70000 293.15 9.9 1993GAU 46300 70000 313.15 9.4 1993GAU 46300 70000 333.15 7.2 1993GAU

80000 288.15 8.85 1993NOR 80000 298.15 7.14 1993NOR 80000 313.15 6.59 1993NOR 80000 323.15 5.54 1993NOR 80000 333.15 4.57 1993NOR

64800 110000 293.15 6.5 1993GAU 64800 110000 313.15 5.6 1993GAU 64800 110000 333.15 4.5 1993GAU

400000 288.15 3.56 1993NOR 400000 298.15 1.88 1993NOR 400000 313.15 1.81 1993NOR 400000 323.15 1.42 1993NOR 400000 333.15 1.12 1993NOR

101000 500000 293.15 6.4 1993GAU 101000 500000 313.15 5.7 1993GAU 101000 500000 333.15 3.9 1993GAU

481000 298.15 3.9 1993WUC 249000 485000 293.15 4.6 1993BES 249000 485000 293.15 4.6 1994TIN 167000 509000 298.15 3.2 1989HAY

508900 298.15 1.3 1993HAY 1000000 303.15 0.85 1991STA 1000000 343.15 2.1 1991STA 1000000 373.15 1.8 1991STA 2000000 288.15 1.22 1993NOR 2000000 298.15 0.74 1993NOR 2000000 313.15 0.43 1993NOR 2000000 323.15 0.39 1993NOR 2000000 333.15 0.24 1993NOR 2270000 298.15 0.90 1993WUC 3250000 298.15 0.70 1993WUC 7400000 303.15 0.099 1991STA 7400000 343.15 0.064 1991STA

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____________________________________________________________________________________

Dextran 7400000 373.15 0.078 1991STA 7400000 288.15 0.47 1993NOR 7400000 298.15 0.29 1993NOR 7400000 313.15 0.17 1993NOR 7400000 323.15 0.13 1993NOR 7400000 333.15 0.0576 1993NOR

17500000 303.15 0.013 1991STA 17500000 323.15 0.018 1991STA 17500000 343.15 0.014 1991STA 17500000 373.15 0.011 1991STA 17500000 288.15 0.30 1993NOR 17500000 298.15 0.17 1993NOR 17500000 313.15 0.0965 1993NOR 17500000 323.15 0.0623 1993NOR 17500000 333.15 0.0189 1993NOR 21100000 303.15 0.017 1991STA 21100000 323.15 0.015 1991STA 21100000 343.15 0.015 1991STA 21100000 373.15 0.0045 1991STA 33000000 288.15 0.21 1993NOR 33000000 298.15 0.12 1993NOR 33000000 313.15 0.0621 1993NOR 33000000 323.15 0.0337 1993NOR 33000000 333.15 0.0024 1993NOR

100000000 288.15 0.0768 1993NOR 100000000 298.15 0.0429 1993NOR 100000000 313.15 0.0178 1993NOR 100000000 323.15 0.0108 1993NOR 100000000 333.15 0.00011 1993NOR

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Ethylene oxide/propylene oxide copolymer (72.4 mol% ethylene oxide) 36000 298.15 6.0 1991LOU (79.5 mol% ethylene oxide) 30800 298.15 10.5 1991LOU

32500 298.15 12.5 1991LOU (86.6 mol% ethylene oxide) 30100 298.15 21.5 1991LOU ____________________________________________________________________________________

N-Isopropylacrylamide/acrylamide copolymer (15 mol% acrylamide) 3100000 298.15 3.01 1994MUM (30 mol% acrylamide) 4500000 298.15 3.31 1994MUM (45 mol% acrylamide) 3900000 298.15 3.46 1994MUM (60 mol% acrylamide) 2200000 298.15 3.62 1994MUM ____________________________________________________________________________________

Poly(allylamine hydrochloride) in 0.05 − 3 M NaCl aqueous solution 180000 298.15 33.7 – 2.4 1985OCH ____________________________________________________________________________________

____________________________________________________________________________________ Poly(acrylamide) 390000 293.15 42.9 1957SIL

390000 303.15 48.7 1957SIL 390000 313.15 54.1 1957SIL 390000 323.15 59.1 1957SIL 390000 333.15 63.9 1957SIL

1200000 298.15 4.9 1982STE 5000000 298.15 3.7 1985KUL 8900000 298.15 3.5 1986MCC

560000 1400000 298.15 1.8 1982LECH in 0.1 M NaCl aqueous solution 33000 277.15 3.3 1985KAN

33000 282.65 4.5 1985KAN 33000 291.15 5.2 1985KAN 33000 298.15 6.1 1985KAN 33000 301.15 6.0 1985KAN 33000 312.15 6.5 1985KAN 33000 322.15 6.8 1985KAN 33000 333.15 6.8 1985KAN

129000 220000 277.65 2.0 1985KAN 129000 220000 287.15 2.4 1985KAN 129000 220000 297.65 3.0 1985KAN 129000 220000 298.15 2.8 1985KAN 129000 220000 307.65 3.0 1985KAN 129000 220000 317.15 3.1 1985KAN 129000 220000 328.65 3.2 1985KAN

3045000 6700000 275.65 0.3 1985KAN 3045000 6700000 279.65 0.5 1985KAN 3045000 6700000 283.15 0.7 1985KAN 3045000 6700000 291.65 1.1 1985KAN 3045000 6700000 299.55 1.3 1985KAN 3045000 6700000 306.15 1.8 1985KAN

in 0.2 M NaCl aqueous solution 255000 293.15 3.06 1982AMI 616000 293.15 3.31 1982AMI

1010000 293.15 3.12 1982AMI 2430000 293.15 2.90 1982AMI 2750000 293.15 2.81 1982AMI

in 0.1 M Na2SO4 aqueous solution 5000000 298.15 2.4 1985KUL ____________________________________________________________________________________ Poly(acrylic acid) in 0.01 M HCl aqueous solution 500000 298.15 88.0 1980HAR in 0.1 M HCl aqueous solution 500000 298.15 13.0 1980HAR in 0.2 M HCl aqueous solution 1100000 293.15 1.0 1957SIL

1100000 303.15 2.6 1957SIL in 0.2 M HCl aqueous solution 1100000 313.15 4.1 1957SIL

1100000 323.15 5.6 1957SIL 1100000 333.15 6.9 1957SIL 1100000 343.15 8.1 1957SIL

in 1.0 M HCl aqueous solution 500000 298.15 2.8 1980HAR ____________________________________________________________________________________

____________________________________________________________________________________

Poly(dimethyldiallylammonium chloride) in 1.0 M NaCl aqueous solution

89000 296.15 0.278 1987BUR 114000 296.15 0.247 1987BUR 281000 296.15 0.150 1987BUR 352000 296.15 0.122 1987BUR 418000 296.15 0.127 1987BUR 473000 296.15 0.222 1987BUR

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Poly(ethylene glycol) 200 293.15 71.6 1993GAU 200 313.15 56.4 1993GAU 200 333.15 48.9 1993GAU 595 293.15 42.6 1993GAU 595 313.15 29.9 1993GAU 595 333.15 29.2 1993GAU

1450 1550 293.15 31.0 1993GAU 1450 1550 313.15 24.2 1993GAU 1450 1550 333.15 14.6 1993GAU 2840 3000 293.15 27.2 1993GAU 2840 3000 313.15 23.7 1993GAU 2840 3000 333.15 12.0 1993GAU 3790 3860 298.15 36.4 1989HAY 3790 3860 298.15 43.2 1989HAY

3860 298.15 36.3 1993HAY 5750 6000 293.15 26.0 1993GAU 5750 6000 313.15 22.5 1993GAU 5750 6000 333.15 15.3 1993GAU 6230 6480 278.15 24.8 1995HAS 6230 6480 298.15 19.0 1995HAS 6230 6480 313.15 12.4 1995HAS

11700 298.15 30.3 1993HAY 9037 11800 298.15 30.5 1989HAY 9037 11800 298.15 41.7 1989HAY

20000 20500 298.15 16.7 1995HAS 20000 20500 313.15 9.7 1995HAS 34400 35700 278.15 25.7 1995HAS 34400 35700 298.15 18.0 1995HAS 34400 35700 313.15 14.4 1995HAS

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Poly(ethylene oxide) 20000 298.15 24.0 1987VEN

263000 274000 298.15 20.8 1984KAM 481000 505000 298.15 27.7 1984KAM

1161000 1300000 298.15 35.6 1984KAM ____________________________________________________________________________________

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Poly(ethylene oxide)-b-poly(propylene oxide)- b-poly(ethylene oxide) triblock copolymer 3600 277.15 −190 1998CRO (70 mol% ethylene oxide) 3600 281.25 −210 1998CRO

3600 282.55 −230 1998CRO 3600 283.55 −240 1998CRO 3600 284.65 −170 1998CRO 3600 286.75 −220 1998CRO 3600 288.65 −180 1998CRO

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Polyethylenimine 47500 90400 308.15 3.15 1996PAR

117000 258000 308.15 1.75 1996PAR 246000 443000 308.15 1.34 1996PAR 236000 581000 308.15 1.22 1996PAR

1100000 2420000 308.15 0.583 1996PAR 2530000 5320000 308.15 0.316 1996PAR

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Poly(L-glutamic acid) in 0.02 − 0.5 M NaCl aqueous solution 112000 298.15 88 − 42 1984KID ____________________________________________________________________________________

Poly(N-isopropylmethacrylamide) 130000 293.15 3.6 1990KUB 422000 293.15 2.0 1990KUB 875000 293.15 1.8 1990KUB 944000 293.15 1.7 1990KUB 993000 293.15 1.7 1990KUB

1110000 293.15 1.7 1990KUB 1150000 293.15 2.0 1990KUB 1240000 293.15 1.7 1990KUB 1840000 293.15 1.4 1990KUB 1870000 293.15 2.1 1990KUB 2520000 293.15 1.6 1990KUB

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Poly(methacrylamide) 320000 293.15 0.21 1957SIL 320000 303.15 0.35 1957SIL 320000 313.15 0.49 1957SIL 320000 323.15 0.61 1957SIL 320000 333.15 0.73 1957SIL

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Poly(methacrylic acid) in 0.1 M HCl aqueous solution 146000 298.15 2.02 1955ARN

540000 298.15 1.61 1955ARN 682000 298.15 1.65 1955ARN

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____________________________________________________________________________________

Poly(methacrylic acid) in 0.114 M HCl aqueous solution 200000 298.15 8.80 1955ARN

256000 298.15 24.0 1955ARN 329000 298.15 22.9 1955ARN 346000 298.15 13.8 1955ARN 427000 298.15 15.4 1955ARN

in 0.2 M HCl aqueous solution 590000 288.15 3.6 1957SIL 590000 293.15 1.8 1957SIL 590000 303.15 1.3 1957SIL 590000 314.15 0.7 1957SIL

in 1.0 M HCl aqueous solution 84000 298.15 −2.0 1955ARN 89000 298.15 13.2 1955ARN

168000 298.15 0.4 1955ARN in 0.05 M NaCl aqueous solution 505000 293.15 1.465 1964KAN

505000 308.15 0.8 1964KAN 505000 323.15 0.255 1964KAN 505000 333.15 0.0 1964KAN

in 0.5 M NaCl aqueous solution 510000 293.15 0.96 1964KAN 510000 303.15 0.49 1964KAN 510000 313.15 0.1 1964KAN

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Poly(3-methylacrylamido-3-methylbutanoic acid) sodium salt

2600000 298.15 3.5 1986MCC ____________________________________________________________________________________

Poly(sodium acrylate) 30000 298.15 0.27 1957TAK 60700 298.15 0.55 1957TAK

128800 298.15 0.95 1957TAK 211900 298.15 0.51 1957TAK 335000 298.15 0.97 1957TAK 644000 298.15 0.79 1957TAK

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Poly(sodium sulfodecyl methacrylate) in 0.1 M NaCl aqueous solution 349500 734000 298.15 1.91 1996PEI ____________________________________________________________________________________

Poly(sodium sulfoethyl methacrylate) in 0.1 M NaCl aqueous solution 170000 306000 298.15 6.41 1996PEI ____________________________________________________________________________________

Poly(sodium sulfohexyl methacrylate) in 0.1 M NaCl aqueous solution 247000 494000 298.15 5.61 1996PEI ____________________________________________________________________________________

Poly(sodium sulfooctyl methacrylate) in 0.1 M NaCl aqueous solution 467000 701000 298.15 2.03 1996PEI ____________________________________________________________________________________

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Poly(vinyl alcohol) 180000 303.15 3.9 1962MA1 196000 303.15 5.2 1962MA1 245000 346.65 1.119 1962MA2 195000 353.15 0.995 1962MA2 259000 353.15 0.930 1962MA2 352000 353.15 0.739 1962MA2 458000 353.15 0.775 1962MA2

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Poly(1-vinyl-2-pyrrolidinone) 4600 8900 293.15 2.62 2003KAN 4600 8900 333.15 1.68 2003KAN

11600 298.15 3.35 1952HEN 15000 298.15 3.7 1952HEN 21900 298.15 3.0 1952HEN 28500 298.15 3.5 1952HEN 28900 298.15 3.4 1952HEN 37700 298.15 3.1 1952HEN 40800 298.15 3.7 1952HEN 45700 298.15 3.75 1952HEN 48600 298.15 3.15 1952HEN 60200 298.15 3.45 1952HEN 75400 298.15 3.2 1952HEN

207000 310000 293.15 4.2 1993DES 207000 310000 293.15 4.2 1994TIN

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Poly(2-vinylpyridine) in 0.01 – 10.3 M H2SO4 aqueous solution ≈500000 298.15 11.0 – 3.0 1993YOS ____________________________________________________________________________________

Pullulan 300000 288.15 2.82 1993NOR 300000 298.15 2.76 1993NOR 300000 313.15 2.78 1993NOR 300000 323.15 2.64 1993NOR 300000 333.15 2.56 1993NOR 510000 288.15 2.66 1993NOR 510000 298.15 2.53 1993NOR 510000 313.15 2.51 1993NOR 510000 323.15 2.38 1993NOR 510000 333.15 2.43 1993NOR

1000000 288.15 2.47 1993NOR 1000000 298.15 2.25 1993NOR 1000000 313.15 2.20 1993NOR 1000000 323.15 2.16 1993NOR 1000000 333.15 2.07 1993NOR

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1952HEN Hengstenberg, J. and Schuch, E., Molekulargewichtsbestimmung von Polyvinylpyrrolidonen (PVP) mittels des osmotischen Drucks und der Lichtstreuung ihrer Lösungen, Makromol. Chem., 7, 236, 1952.