ABSTRACT
Values of PMPs of the Other ......................................................... 210
8.3 Relationships Among Partial Molal Properties........................................... 212
8.4 Chemical Potential in Multicomponent Systems........................................ 215
8.5 Fugacities, Activities, and Activity Coefficients ........................................ 219
8.5.1 Properties of Ideal Gas Mixtures ................................................... 220
8.5.2 Mixtures of Real Gases: Fugacity.................................................. 224
8.5.3 Activity and the Behavior of Real Solutions ................................. 226
8.5.4 Use of the Activity Coefficient to Describe the Behavior
of Real Solutions ............................................................................ 227
8.6 The Behavior of Dilute Solutions ............................................................... 230
8.7 Solution Models........................................................................................... 232
8.7.1 Regular Solution Models................................................................ 232
8.7.2 Modeling Real Solutions ................................................................ 235
8.7.3 Atomistic Models for Solution Behavior ....................................... 236
8.8 Summary...................................................................................................... 244
References............................................................................................................. 248
Application of the thermodynamics displayed in Figure 1.4 to yield equilibrium
maps for systems that contain more than one independent chemical component
begins with the development of a formalism for describing thermodynamic
properties of such multicomponent systems. This chapter lays out that
development.
