Electroorganic Synthesis | Festschrift for Manuel M. Baizer | R. Danie

Book

Electroorganic Synthesis

ABSTRACT

Baizer (1914-1988) was the foremost internationally recognized authority on organic electrosynthesis. In this festschrift , derived from a memorial symposium held in Montreal, May 1990, as part of the 177th meeting of the Electrochemical Society, and also marking the 25th anniversary of electroorgan

TABLE OF CONTENTS

part |51 pages

Mechanism

chapter |7 pages

Are Mechanistic Studies Relevant to Electroorganic Synthesis? An Example from the Reduction of 1,1-Dinitrocyclohexane

chapter |8 pages

Information Available from Formal Oxidation Potentials of R2NX Compounds

chapter |9 pages

Mechanism of Electrochemical Synthesis of Some Sterically Hindered Compounds

chapter |16 pages

Electrochemical Induction of SRN1 Nucleophilic Substitution

chapter |7 pages

Synthesis of Aromatic Chalcogeno Derivatives by Electrochemically Induced SRN1 Substitution in MeCN. Advantages and Limits of the Electrochemical Technique

part |90 pages

Reduction

chapter |6 pages

Electrohydrodimerization: Comparison of Acrylonitrile and Formaldehyde

chapter |5 pages

Electroreductive Hydrodimerization of Allylbenzene and Related Aromatic Olefins

chapter |8 pages

Electroreductive Coupling of Carbonyl-Type Groups with Unsaturated Systems

chapter |7 pages

The 5,6 vs the 6,5 Electroreductive Tandem Cyclization of Ketones

chapter |8 pages

Regiocontrolled Allylation of Carbonyl Compounds by Electrochemical Reduction of Allylic Halides

chapter |8 pages

Electrolytic Reductions of Heptanoyl Chloride, Phthaloyl Dichloride, and Benzoyl Chloride at Carbon and Mercury Cathodes in Acetonitrile

chapter |6 pages

Stereoselective Electrochemical and Sonochemical Reductive Silylation of Geminal Dihalides

chapter |6 pages

Reduction of Alkyl Chlorides at Lead Cathodes

chapter |9 pages

Electroreduction of 9,9′-Spirobifluorene in Dimethyiformamide: Preparation of Hydrogenated Products

chapter |7 pages

Electrochemical Reduction of Carbonyl Compounds Activated by a Nitrile Function. Application to 2-Cyanocycloalkanones. Some Examples of Carbon-Carbon Bond Cleavages

chapter |8 pages

The Efficient Electrochemical Reduction of Aliphatic Nitro Compounds to Amines in Neutral and Basic Media at Raney Nickel and Devarda Copper Electrodes

chapter |6 pages

Reduction of Aromatic Nitro Compounds: The Fate of Arylhydroxylamines

part |88 pages

Oxidation

chapter |7 pages

Anodic Methoxylation of Aromatic Compounds Occurring Via the EECrCp Mechanism

chapter |8 pages

Oxidative Organic Electrochemistry: Intramolecular Enol Ether Coupling Reactions

chapter |8 pages

Electro-Initiated Oxygenation

chapter |12 pages

Anodic Oxidation of CH-Bonds in Cyclic Hydrocarbons

chapter |6 pages

Photodetoxification Via Photoelectrochemical Oxidation on Irradiated TiO2 Particles

chapter |9 pages

Anodic Addition to the Ethylenic Double Bond: The Case of Inden-1-ones

chapter |7 pages

Viable One-Pot Procedures for Electrooxidative Coupling of 2,6-Di-tert-butylphenol to 2,2′6′6-Tetra-tert-butyl-1,1′-biphenol

chapter |11 pages

Direct and Indirect Anodic Oxidation of Vinyl and Allyl Arenes: Prospects for the Formation of Benzaldehydes and Arylketones by Double-Bond Cleavage

chapter |8 pages

Formation of Heterocyclic Compounds by Electrochemical Oxidation of Hetero-Allenes in Non-Aqueous Media

chapter |6 pages

Porous Carbon Anodes in the cave KF˙2HF Electrolyte

part |32 pages

Mediated Reduction and Oxidation

chapter |7 pages

Indirect Electroreduction of α,β-Epoxy and α,α-Dihalo Carbonyl Compounds with Diphenyl Diselenide or Ditelluride as a Recyclable Mediator

chapter |7 pages

Electroreductive Carbon-Carbon Bond-Making Reactions in Pb(O)/Pb(II) Redox Mediatory Systems. “Barbier Type” Allylation and Hydrocoupling of Imines in an Undivided Cell

chapter |6 pages

New Development of Indirect Electrooxidation of Alcohols by N-Oxoammonium Salts and Bromine Compounds as Mediators

chapter |8 pages

Indirect Electrolysis Involving Phase Transfer Catalysis

part |77 pages

Biochemical, Biomass, and Natural Products

chapter |7 pages

Bioelectrochemical and Biochemical Oxidation of Organics by Mammalian and Bacterial Cytochrome P450 Preparations

chapter |8 pages

The Direct Electrosynthesis of L-Cysteine Free Base

chapter |7 pages

Bioelectrocatalytic Regeneration of NADH at Enzyme Immobilized Electrodes

chapter |11 pages

New Insights into the Electrochemical Oxidation of 5-Hydroxytryptamine in Acidic Aqueous Solution

chapter |8 pages

Electrochemistry: Electrochemical Conversion of 2,3-Butanediol

chapter |7 pages

Natural Products Syntheses by Means of Electrochemical Methodology

chapter |6 pages

B12-Catalyzed Electrosynthesis of Natural Products

chapter |8 pages

Stereoselective Electroreductive Cyclization. Construction of a Corey Lactone Precursor

chapter |9 pages

Novel Synthesis of Some Specialty Chemicals by Electroorganic Reaction

part |34 pages

Modified Sacrificial/Consumable Electrodes

chapter |12 pages

Electroorganic Synthesis on Catalyst Coated Electrodes

chapter |6 pages

Electrochemical Carboxylation of Organic Halides in the Presence of Consumable Magnesium Anode and Modified Cathode

chapter |7 pages

Nickel-Catalyzed Electrochemical Coupling Reaction Between Alkyl Chlorides and Carbonyl Compounds in the Presence of Sacrificial Zinc Anode. Evidence for Ni-Zn Transmetalation

chapter |6 pages

Electroactive Polymers Based on Amino Acids

part |20 pages

Electrogenerated Bases (EGB)

chapter |10 pages

Electro-Organic Reactions. Part 36. The Mechanism of Asymmetric Protonation of Electrogenerated Bases

chapter |8 pages

Selective Organic Synthesis Using Electrogenerated Bases

part |11 pages

Film-Forming Electropolymerization

chapter |9 pages

Proton Balance and Catalysis for the Film-Forming Electropolymerization of Pyrrole in Wet Acetonitrile

part |9 pages

Ion Exchange

chapter |7 pages

Electrochemical Ion Exchange