ABSTRACT

Acenaphthylene (ACN), which forms bright yellowish plates with a melting point of 93-94˚C, is one of the simplest nonalternant aromatic hydrocarbons.

Since its discovery by Dziewonski and Rapalski in 1912, the photochemical conversion of ACN into two isomeric dimers (

cisoid

-

and

transoid

-

) has been studied because of its unique photophysical properties and mechanistic interest.