ABSTRACT

Because of additional scattering of charge carriers on intergrain interfaces a reduction of electrical

conductivity is observed, while the thermoelectric power is affected only to a minor extent. Usually a

decrease of thermal conductivity is compensated by the decrease of electrical conductivity. Another

approach for improving the thermoelectric efficiency is by utilizing multiphase composite material,

which is also limited from theoretical point of view. Within the effective medium approximation which

is commonly used for theoretical analysis of composite materials, there is an upper bound for the

thermoelectric efficiency Z of a composite system, Z # maxðZ

Þ.