ABSTRACT

This chapter describes recent aspects of advanced inorganic materials used in photovoltaics or solar cell applications. Specific materials examined will be high-efficiency silicon, gallium arsenide and related materials, and thin-film materials, particularly amorphous silicon and (polycrystalline) copper indium selenide. Some of the advanced concepts discussed include multijunction III–V (and thin-film) devices, utilization of nanotechnology, specifically quantum dots, low-temperature chemical processing, polymer substrates for lightweight and low-cost solar arrays, concentrator cells, and integrated power devices. While many of these technologies will eventually be used for utility and consumer applications, their genesis can be traced back to challenging problems related to power generation for aerospace and defense applications. Because this overview of inorganic materials is included in a monogram focused on organic photovoltaics, fundamental issues common to all solar cell devices (and arrays) will be addressed.