ABSTRACT

aMetal chelating systems can be viewed as metal ion buffer systems.

MY = metal chelate complex; M is metal and Y is chelating agent. Metal ion are electron acceptors can be viewed as Lewis acids while chelating agents donate electrons and are Lewis bases. Also, chelating agents are polydentate

MYn–m = M+n + M–m

KMY = [MYn+m]/[M+n][Y–m]

pM = log KMY + log [Y–m]/[MYn–m]