ABSTRACT

The hydrogen atom can be considered a two-particle system, an electron and a proton, with the Coulomb potential acting between them. This chapter shows how to solve the Schrodinger equation for the wave function of the two-particle system. It introduces the coordinates of the center of mass, which will allow us to split the Schrodinger equation into two independent equations, one for the center of mass motion and another for the relative motion of the electron and proton. The left- hand side of the Schrodinger equation depends solely on the spatial variables, whereas the right-hand side depends solely on time. The wave function can be written as a product of the spatial and time-dependent parts. It is very similar in form to the Schrodinger equation for the hydrogen atom except it involves two Laplacians. Since the Laplacians act on separate variables, the chapter helps to solve the Schrodinger equation using the method of separate variables.