ABSTRACT

Multiferroic transition metal oxides exhibit a wide variety of properties that are related to the delicate balance between lattice, charge, spin, and orbital degrees of freedom [1]. Modern thin-lm synthesis methods such as pulsed laser deposition (PLD), molecular beam epitaxy (MBE), and metal-organic chemical vapor deposition (MOCVD), among others, enable the engineering of interfaces between complex transition metal oxides with atomic-scale precision. Interfaces introduce a variety of local changes, for example, they break

Contents 12.1 Introduction..................................................................................................316 12.2 Multiferroic Domain Walls ....................................................................... 317

12.2.1 Local Structure Investigations of Multiferroic Domain Walls ....317 12.2.2 Conductivity at Multiferroic Domain Walls ............................. 317 12.2.3 Light Interaction with Multiferroic Domain Walls ................. 323 12.2.4 Magnetic Properties of Multiferroic Domain Walls ................ 324

12.3 Multiferroic Vortex Structures and Skyrmion Systems ........................ 324 12.4 Conclusions and Outlook .......................................................................... 327 References ............................................................................................................... 328

the symmetry of the material, induce stress, and lead to variation in the bonding between ions. ese in turn give rise to changes in electronic structure such as bandwidth, orbital interactions, and energy-level degeneracy. Charge transfer in these correlated systems can induce changes in carrier densities at interfaces that result in physical properties that may be completely dierent from those of the parent bulk phases [2-6].