ABSTRACT

The starting point for the statistical thermodynamics justification of equations of state for pure compounds is Equation 24.13, namely, https://www.w3.org/1998/Math/MathML"> P = − ( ∂ A ∂ V ) T , n = k T ( ∂ ln ⁡ Q ∂ V ) T , n https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781315399065/5df30985-80c1-4e11-9533-10c20ed2604c/content/equ24_13a.tif" xmlns:xlink="https://www.w3.org/1999/xlink"/> with https://www.w3.org/1998/Math/MathML"> Q ≡ ∑ j e − E j k T https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781315399065/5df30985-80c1-4e11-9533-10c20ed2604c/content/equ24_05a.tif" xmlns:xlink="https://www.w3.org/1999/xlink"/>