ABSTRACT

A few months ago, through the generosity of the Academy of Sciences of Vienna, one of us was loaned a radium preparation containing about 250 mg. of radium. Observations were at once begun to purify the emanation produced by it, and to determine its volume. When the emanation was condensed in a side tube by means of liquid air, the great majority of the lines vanished at the moment of condensation, which was readily noted by the phosphorescence of the glass. The colour of the discharge then completely changed, and became of a pale rose colour. At the instant of volatilisation, the emanation lines flashed out again. The first determination of the spectrum of the emanation was made in 1904 by Ramsay and Collie, who determined the wave-lengths of about eleven lines by visual observations. The accuracy obtained is indicated by the agreement of the wavelengths of some of the hydrogen lines with their known values.