ABSTRACT

Origins of Colloid Stability . . . . . . . . . . . . . . . . . . . 249

Electrostatic Repulsion . . . . . . . . . . . . . . . . . . . . 249

van der Waals Attraction . . . . . . . . . . . . . . . . . . . 249

Steric Stabilization and “Anomalous” Stability . 250

Hydration Effects . . . . . . . . . . . . . . . . . . . . . . . . . 251

Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252

Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . 252

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252

The control of silica sol coagulation by pH and by addition of simple electrolytes is said to be “anomalous”

in that it is not simply predicted by conventional Derjaguin-Landau-Verwey-Overbeck (DLVO) theory.