ABSTRACT
CCl4 Tetrachloromethane (Ref. 9) 1 9.33340·10-2 1.11363·103 –8.68453 2.80698·10-2 –4.22880·10-5 2.37923·10-8 273/413 51/388 0.040 349.9 1.074 1.209 3 1.58994 2.51946 –5.82313 6.96793 –2.51359 253/554 556.40 557.33 0.042 5 –7.07139 1.71497 –2.89930 –2.49466 250/556 556.40 4.551
CHBr3 Tribromomethane (Ref. 9) 1 1.03492·10-1 2.64208·102 –4.57399·10-1 323/368 150/343 0.058 422.3 0.809 0.907 2 3.55953·103 –1.96212 –1.08712·10-3 283/403 0.001
CHCl3 Trichloromethane (Ref. 9) 1 9.57210·10-2 4.79593·102 –1.84011 1.81340·10-3 273/348 100(r) 0.031 334.4 1.037 1.274 3 3.56339 –3.86051 3.35636 213/333 536.40 499.49 0.043 5 –6.95546 1.16625 –2.13970 –3.44421 215/536 536.40 5.366
CH2Cl2 Dichloromethane (Ref. 9) 1 9.76370·10-2 5.24365·102 –2.06633 2.09494·10-3 293/423 100(r) 0.091 313.4 1.032 1.428 3 3.00368 –2.19763 2.34269 178/383 510.00 440.07 0.014 5 –7.35739 2.17546 –4.07038 3.50701 233/510 510.00 6.300
CH3I Iodomethane (Ref. 9) 1 9.54770·10-2 5.36810·102 –2.25115 2.53188·10-3 253/313 160 0.038 315.6 1.052 1.255 2 3.48981·103 –7.47709 1.83592·10-2 –2.36742·10-5 213/313 0.011
CH4O Methanol (Ref. 3) 1a 1.15068·10-1 6.49718·102 –4.34583 1.30722·10-2 –2.00292·10-5 1.20566·10-8 183/483 104(r) 0.059 337.7 1.231 1.201 3 2.62781 –4.04742 1.58343·10 –2.25066·10 1.09160·10 3.04774·10-1 175/509 512.60 272.00 0.180 4 –8.63571 1.17982 –2.47900 –1.02400 175/513 512.64 8.092
C2Cl4 Tetrachloroethylene (Ref. 9) 1 1.01727·10-1 1.36610·102 298/298 101 0.007 394.5 0.744 1.012 3 1.10232 1.45142 298/313 620.20 571.84 0.019
C2HCl3 Trichloroethylene (Ref. 9) 1 1.00987·10-1 1.16005·102 298/298 101 0.010 360.4 0.870 1.142 3 1.30631 1.33512 291/315 571.00 513.24 0.008
C2H4Cl2 1,1-Dichloroethane (Ref. 9) 1 9.79930·10-2 4.40906·102 –1.67041 1.60492·10-3 298/398 101(r) 0.028 330.4 1.144 1.320 3 2.81773 –2.41755 2.40906 263/398 523.00 419.32 0.084 4 –9.51254 7.49332 –7.87028 6.32540·10-1 320/450 523.00 5.070
C2H4Cl2 1,2-Dichloroethane (Ref. 9) 1 9.60440·10-2 5.39476·102 –1.94358 1.79758·10-3 278/398 101(r) 0.027 356.7 0.801 1.158 3 2.77660 –2.33774 2.31530 263/398 561.60 439.82 0.063 5 –7.36864 1.76727 –3.34295 –1.43530 260/566 566.00 5.362
C2H4O2 Acetic acid (Ref. 5) 1 9.44550·10-2 7.22131·102 –3.33202 4.23588·10-3 293/328 25/253 0.040 391.1 0.897 1.085 3 4.74861 –1.76644·10 4.44807·10 –4.82535·10 1.98308·10 293/493 592.71 351.19 0.003
C2H5Br Bromoethane (Ref. 9) 1 9.43490·10-2 7.70215·102 –4.06470 5.75736·10-3 253/313 157(r) 0.055 311.6 1.344 1.475 3 1.50516 1.35063 253/313 503.90 506.82 0.058 5 –9.14807 5.49831 –6.68657 6.27287 301/504 503.80 6.232
C2H6O Ethanol (Ref. 3) 1b 1.09012·10-1 5.22523·102 –2.99367 8.25136·10-3 –1.31014·10-5 8.74008·10-9 193/480 200(r) 0.055 351.4 1.117 1.097 3c –9.92640·10-1 3.80287·10 –1.81117·102 4.45905·102 –5.88518·102 3.93920·102 159/508 513.88 276.00 0.160 4 –8.68587 1.17831 –4.87620 1.58800 159/514 513.92 6.132
C2H6O2 Ethylene glycol (Ref. 6) 1 9.50140·10-2 6.74427·102 –1.77594 1.27583·10-3 298/378 100(r) 0.031 470.5 0.368 0.639 3 1.77482 1.11208 298/378 790.00 333.70 0.022
C3H6O Acetone (Ref. 5) 1 9.92390·10-2 6.22264·102 –2.94315 3.73329·10-3 278/323 392 0.032 329.2 1.293 1.457 3 1.83805 5.82830·10-1 –1.00291·10-1 5.70410·10-1 179/506 508.10 277.90 0.025
Eq. a1 a2 a3 a4 a5 a6
K MPa
MPa
%
C3H7Br 1-Bromopropane (Ref. 9) 1 8.88710·10-2 4.24716·102 –1.81352 2.55049·10-3 –1.23227·10-6 280/500 100 0.094 344.0 1.137 1.251 3 1.65835 1.17536 280/340 536.00 455.53 0.009 4 –9.68919 7.16793 –7.05282 1.00727 300/536 536.00 4.750
C3H7Cl 1-Chloropropane (Ref. 9) 1 1.07245·10-1 2.78606·102 –5.17553·10-2 –3.83546·10-3 5.85824·10-6 273/368 98(r) 0.078 319.6 1.382 1.462 3 4.15272 –5.73954 4.74431 253/343 503.00 309.22 0.015 5 –7.55764 2.60153 –5.06041 3.31163 248/503 503.00 4.580
C3H7I 1-Iodopropane (Ref. 9) 1 1.01044·10-1 3.01114·102 –6.61560·10-1 8.74342·10-5 273/368 1177 0.070 375.7 0.904 1.072 2 2.22323·103 –1.38867 –7.96985·10-4 288/361 0.196
C3H8O 1-Propanol (Ref. 3) 1d 9.60290·10-2 3.10861·102 –8.35531·10-1 4.27987·10-5 7.78234·10-7 170/524 49(r) 0.109 370.3 1.007 0.999 3 9.40534·10-1 1.29442·10 –5.39519·10 1.13639·102 –1.13866·102 4.33832·10 153/530 536.74 274.00 0.160 4 –8.53706 1.96214 –7.69180 2.94500 147/537 536.78 5.168
C3H8O 2-Propanol (Ref. 6) 1 8.90020·10-2 1.87411·102 –2.36391·10-1 –4.24787·10-4 273/400 50(r) 0.054 355.4 1.123 1.099 3 6.24542·10-1 6.18938 –6.79039 2.49009 243/430 508.30 273.16 0.093 5 –8.16927 –9.43213·10-2 –8.10040 7.85000 250/508 508.30 4.742
C3H8O2 1,2-Propanediol (Ref. 6) 1 8.38940·10-2 9.09931·102 –4.03075 5.24295·10-3 273/368 200 0.019 460.2 0.481 0.714 2 1.18071·103 –2.56645·10-1 –8.05917·10-4 283/363 0.017
C3H8O2 1,3-Propanediol (Ref. 6) 1 9.10310·10-2 5.95160·102 –1.64714 1.36994·10-3 273/368 200 0.067 487.6 0.403 0.593 3 3.64841 –2.06696 1.22738 283/363 685.70 318.39 0.002
C3H8O3 Glycerol (Ref. 6) 1 1.14255·10-1 9.25959·102 –1.58140 4.48909·10-4 223/368 686 0.061 563.1 0.231 0.486 3 6.94960 –9.25236 5.43535 214/364 800.00 351.51 0.069
C4H8O2 Ethyl acetate (Ref. 5) 1 8.94090·10-2 1.05394·103 –7.58700 1.98689·10-2 –1.82587·10-5 253/343 49(r) 0.106 350.3 1.204 1.425 3 1.69043 2.64150 –4.70476 3.52368 253/473 523.20 308.06 0.015
C4H9Br 1-Bromobutane (Ref. 9) 1 9.76600·10-2 4.97301·102 –2.02541 2.24791·10-3 273/368 1177 0.074 374.8 1.046 1.119 3 1.59525 1.23746 293/323 572.00 421.60 0.003
C4H10O 1-Butanol (Ref. 3) 1e 1.01542·10-1 5.01888·102 –2.41576 5.35877·10-3 –7.31982·10-6 4.60628·10-9 195/524 49(r) 0.053 390.9 0.914 0.949 3 –3.57379 5.02450·10 –1.75934·102 3.08588·102 –2.65628·102 8.94997·10 186/559 563.01 271.00 0.352 4 –8.40615 2.23010 –8.24860 –7.11000·10-1 185/563 563.05 4.424
C4H10O Diethyl ether (Ref. 5) 1 9.70250·10-2 3.95413·102 –1.68339 1.82398·10-3 293/353 981 0.239 307.6 1.740 1.657 3 3.31808 –8.55179 2.09100·10 –2.10672·10 8.26525 140/430 466.74 264.72 0.027 5 –7.29916 1.24828 –2.91931 –3.36740 250/467 466.74 3.646
C5H10 Cyclopentane (Ref. 8) 1 8.85580·10-2 8.94968·102 –7.76576 3.01636·10-2 –5.82645·10-5 4.43996·10-8 193/353 48/196 0.050 322.4 1.308 1.325 3 1.68431 6.19856·10-1 4.90670·10-2 2.19121·10-1 179/508 511.70 275.04 0.031 5 –6.51809 3.84422·10-1 –1.11706 –4.50275 289/512 511.60 4.509
C5H11Br 1-Bromopentane (Ref. 9) 1 8.98660·10-2 5.28042·102 –2.41620 3.92466·10-3 –2.31231·10-6 283/523 98 0.061 402.7 0.943 1.076 2 1.60209·103 –1.30486 283/363 0.006 4 –8.59341 3.46288 –3.06661 –4.07997 294/606 605.90 3.900
C5H12 Pentane (Ref. 4) 1f 1.00620·10-1 6.52014·102 –4.94167 1.54854·10-2 –2.36811·10-5 1.44530·10-8 173/373 87/285 0.119 309.2 2.133 1.610 3 1.17756 3.89157 –5.50896 3.29181 143/444 469.80 232.00 0.154 4 –7.30698 1.75845 –2.16290 –2.91300 143/470 469.80 3.375
C5H12O 1-Pentanol (Ref. 3) 1 9.52000·10-2 3.00019·102 –5.62481·10-1 –5.98193·10-4 1.15744·10-6 233/550 59(r) 0.149 411.2 0.866 0.905 3 –2.61129 4.23375·10 –1.49640·102 2.62210·102 –2.23090·102 7.37879·10 195/585 588.11 270.00 0.353 4 –8.98005 3.91624 –9.90810 –2.19100 196/588 588.15 3.909
C6H5Br Bromobenzene (Ref. 9) 1 9.73880·10-2 4.87590·102 –1.49313 1.16283·10-3 278/358 100(r) 0.043 429.2 0.668 0.901 3 2.84948 –2.30055 2.31394 298/358 670.00 484.60 0.002
C6H5Cl Chlorobenzene (Ref. 9) 1g 1.06896·10-1 5.95178·102 –2.52143 4.02563·10-3 –3.10524·10-6 1.06813·10-9 278/583 50(r) 0.057 404.9 0.752 0.969 3 1.17137·10-1 1.23712·10 –2.84464·10 2.94048·10 –1.07075·10 253/630 632.40 365.45 0.008 5 –7.58700 2.26551 –4.09118 1.70377·10-1 335/632 632.40 4.519
Eq. a1 a2 a3 a4 a5 a6
K MPa
MPa
%
C6H5NO2 Nitrobenzene (Ref. 10) 1 9.31940·10-2 6.10698·102 –1.89353 1.56305·10-3 293/358 100 0.005 484.0 0.503 0.826 3 4.47929 –5.72846 4.39478 273/373 718.00 362.09 0.027
C6H6 Benzene (Ref. 7) 1 9.36560·10-2 3.28066·102 2.79270·10-2 –6.54288·10-3 1.66249·10-5 –1.24527·10-8 283/499 58(r) 0.079 353.2 0.965 1.222 3 1.81679 –1.44828·10-1 3.65168 –5.85231 3.50125 279/561 562.16 301.60 0.024 4 –7.01433 1.55256 –1.84790 –3.71300 288/562 562.16 4.898
C6H7N Aniline (Ref. 10) 1 9.43630·10-2 7.27479·102 –2.43017 2.23750·10-3 298/358 100(r) 0.043 457.3 0.467 0.830 3 2.71043 –3.14236 1.48381·10 –3.89610·10 4.62777·10 –1.91216·10 263/699 699.00 332.60 0.093
C6H12 Cyclohexane (Ref. 8) 1 8.51590·10-2 6.06614·102 –3.64438 9.15077·10-3 –1.15323·10-5 5.95736·10-9 287/523 81(r) 0.087 353.9 1.135 1.207 3 1.62642 9.95043·10-1 –2.55766·10-1 –8.79980·10-2 4.74534·10-1 273/553 553.50 273.25 0.038 5 –6.96009 1.31328 –2.75683 –2.45491 293/554 553.64 4.075
C6H14 Hexane (Ref. 4) 1h 1.05863·10-1 4.87649·102 –2.71631 5.75951·10-3 –5.74075·10-6 2.33450·10-9 223/498 200(r) 0.112 341.9 1.645 1.387 3 1.59756 1.84266 –1.72631 4.94308·10-1 6.46314·10-1 183/507 507.90 234.00 0.124 4 –7.53998 1.83759 –2.54380 –3.16300 178/508 507.90 3.035
C6H14 2-Methylpentane (Ref. 8) 1 8.95370·10-2 3.60920·102 –1.70650 2.61411·10-3 –1.30788·10-6 273/473 32(r) 0.272 333.4 1.793 1.430 3 5.72227 –2.82931·10 7.80587·10 –9.08956·10 3.90010·10 273/473 497.50 234.82 0.090 5 –7.28750 1.29015 –2.97853 –2.17234 240/498 498.10 3.033
C6H14 3-Methylpentane (Ref. 8) 1 8.79150·10-2 2.68648·102 –1.00644 9.29350·10-4 293/473 32(r) 0.086 336.4 1.714 1.350 3 4.03149 –1.18248·10 2.42559·10 –1.83295·10 4.33405 293/473 504.50 234.82 0.143 5 –7.27084 1.26113 –2.81741 –2.17642 235/504 504.40 3.122
C6H14 2,3-Dimethylbutane (Ref. 8) 1i 6.09940·10-2 2.88312·102 –1.38880 2.23422·10-3 –1.24468·10-6 208/473 32(r) 0.072 331.2 1.831 1.364 3 4.23996 –1.47401·10 3.56742·10 –3.61641·10 1.37668·10 208/463 499.98 240.72 0.078 5 –7.27870 1.56349 –3.05387 –1.57752 235/500 500.30 3.146
C6H14O 1-Hexanol (Ref. 3) 1 9.45430·10-2 3.56654·102 –9.63938·10-1 3.19317·10-4 7.27932·10-7 –3.68450·10-10 298/503 400 0.045 430.5 0.828 0.878 3 –1.55309·10-1 1.77262·10 –5.76007·10 9.99026·10 –8.65883·10 2.96281·10 223/607 610.70 268.00 0.191 4 –9.49034 5.13288 –1.05817·10 –5.15400 226/611 610.70 3.470
C7H8 Toluene (Ref. 7) 1j 1.08655·10-1 6.58594·102 –3.36063 6.79417·10-3 –6.73894·10-6 2.80015·10-9 179/583 50(r) 0.052 383.8 0.900 1.080 3 2.33057 –3.10784 1.04839·10 –1.28168·10 6.29458 –2.64550·10-1 178/588 591.79 291.59 0.041 5 –7.28607 1.38091 –2.83433 –2.79168 309/592 591.72 4.106
C7H8O Anisole (Ref. 5) 1 9.57370·10-2 3.76997·102 –7.76199·10-1 298/353 196 0.032 426.9 0.657 0.949 3 2.32023 –1.28589 1.68888 273/353 645.60 335.84 0.031
C7H14 Cycloheptane (Ref. 8) 1 9.09350·10-2 3.25145·102 –8.81409·10-1 4.29576·10-4 294/393 40(r) 0.041 391.6 0.904 1.062 2 1.06207·103 –8.56800·10-1 298/353 0.003
C7H16 Heptane (Ref. 4) 1k 8.14360·10-2 5.31891·102 –3.38490 9.42976·10-3 –1.36183·10-5 8.10257·10-9 198/511 150(r) 0.153 371.6 1.429 1.251 3 1.33159 3.30092 –4.50961 2.76549 183/538 540.11 236.00 0.377 4 –7.77404 1.85614 –2.82980 –3.50700 183/540 540.15 2.735
C8H10 o-Xylene (Ref. 7) 1 8.02720·10-2 4.52200·102 –1.81150 2.45174·10-3 –1.15349·10-6 257/598 51(r) 0.082 417.6 0.806 0.944 3 1.93903 6.93214·10-1 –5.52518·10-1 7.42481·10-1 248/628 630.30 287.72 0.006 5 –7.53357 1.40968 –3.10985 –2.85992 337/630 630.25 3.733
C8H10 m-Xylene (Ref. 7) 1 8.13550·10-2 5.95204·102 –3.17132 6.99286·10-3 –7.69418·10-6 3.47267·10-9 230/598 20(r) 0.054 412.3 0.857 0.987 3 1.96653 7.70424·10-1 –8.14622·10-1 9.44937·10-1 225/613 617.05 282.36 0.007 5 –7.59222 1.39441 –3.22746 –2.40376 332/617 616.97 3.537
C8H10 p-Xylene (Ref. 7) 1 8.45420·10-2 4.38870·102 –1.77395 2.41453·10-3 –1.13719·10-6 288/598 51(r) 0.076 411.5 0.894 1.003 3 2.01680 6.60504·10-1 –7.70676·10-1 9.97453·10-1 286/603 616.20 280.13 0.005 5 –7.63495 1.50724 –3.19678 –2.78710 331/616 616.15 3.513
C8H16 Cyclooctane (Ref. 8) 1 8.66040·10-2 3.85135·102 –1.19668 9.00890·10-4 314/394 40 0.026 422.2 0.798 0.960 3 1.25843 1.53566 293/394 647.20 273.70 0.040
Eq. a1 a2 a3 a4 a5 a6
K MPa
MPa
%
C8H18 Octane (Ref. 4) 1l 1.09943·10-1 1.17639·103 –1.02441·10 3.73444·10-2 –6.42362·10-5 4.23381·10-8 248/393 108(r) 0.069 398.8 1.255 1.158 3 1.96977 –1.10062 6.36417 –8.69348 4.42005 216/563 568.91 237.00 0.221 4 –8.04937 2.03865 –3.31200 –3.64800 216/569 568.95 2.490
C8H18O 1-Octanol (Ref. 3) 1 9.39730·10-2 5.22871·102 –1.99322 2.56178·10-3 –1.13255·10-6 283/623 79(r) 0.177 468.3 0.743 0.844 3 –3.53373 5.48581·10 –1.99653·102 3.45797·102 –2.85030·102 9.05445·10 258/643 652.50 266.00 0.262 4 –1.00144·10 5.90629 –1.04026·10 –9.04800 258/653 652.50 2.860
C9H12 Mesitylene (Ref. 7) 1 8.84360·10-2 4.00368·102 –1.18616 7.38886·10-4 238/362 200 0.056 437.9 0.786 0.944 3 1.23001·10 –3.23171·10 3.37700·10 –1.06994·10 238/353 637.25 277.59 0.012
C9H20 Nonane (Ref. 4) 1m 1.04176·10-1 6.60874·102 –3.94793 9.86964·10-3 –1.23014·10-5 6.27200·10-9 248/511 65(r) 0.064 424.0 1.125 1.088 3 1.92778 9.30219·10-1 –1.33413 1.39282 223/511 594.90 238.00 0.078 4 –8.32886 2.25707 –3.82570 –3.73200 220/595 594.90 2.290
C10H22 Decane (Ref. 4) 1n 7.76110·10-2 5.12895·102 –2.98749 7.58178·10-3 –9.71758·10-6 5.01670·10-9 248/503 200(r) 0.079 447.3 1.096 1.042 3 3.29139·10-1 7.36434 –9.98510 5.28361 243/511 617.61 239.00 0.108 4 –8.60643 2.44659 –4.29250 –3.90800 244/618 617.65 2.105
C11H24 Undecane (Ref. 4) 1o 9.36240·10-2 9.78153·103 –1.13416·102 4.97036·10-1 –9.65143·10-4 6.97765·10-7 258/423 50/500 0.044 469.1 1.078 0.998 3 –2.75532·10-1 9.28503 –1.19923·10 5.96957 258/473 638.81 240.00 0.069
C12H26 Dodecane (Ref. 4) 1 9.0545010-2 9.00366·103 –1.03134·102 4.49084·10-1 –8.70464·10-4 6.31007·10-7 268/393 20/442 0.083 489.5 0.998 0.977 3 –3.04946·10-2 8.32535 –1.08268·10 5.55178 263/483 658.60 240.00 0.055
C13H28 Tridecane (Ref. 4) 1 8.79880·10-2 3.53129·102 –1.17372 1.00334·10-3 303/473 500 0.080 508.6 0.951 0.947 3 2.52779 –1.64864 2.10099 265/473 676.00 240.00 0.139
C14H30 Tetradecane (Ref. 4) 1 9.01310·10-2 2.44902·102 –4.92510·10-1 293/358 50/367 0.040 526.7 0.918 0.924 3 3.50992 –4.09768 3.61064 279/372 693.00 241.00 0.050
C`15H32 Pentadecane (Ref. 4) 1 8.85030·10-2 4.04942·102 –1.37693 1.25370·10-3 311/408 69/655 0.048 543.8 0.835 0.882 3 1.08801 1.82524 288/408 708.00 241.00 0.038
C16H34 Hexadecane (Ref. 4) 1 9.05120·10-2 –6.87292·102 8.07128 –2.59370·10-2 2.60661·10-5 293/393 10/451 0.047 560.0 0.866 0.889 3 2.61306 –1.99964 2.40011 293/490 722.00 241.00 0.035 a b1 = –5.322·10
c Additional term a7(1 – Tr) (7/3) is included in Eq. 3 with a7 = –1.04344 10
k b1 = 7.924·10 –5, c1 = –1.513·10
