Thermodynamic Properties as a Function of Temperature

PHASE TRANSITION: ∆trs H = 18.980 kJ/mol, ∆trs S = 53.702 J/K.mol, cr-l 353.43 217.200 252.650 169.833 29.270 96.099 224.543 –33.186 400 241.577 280.916 181.124 39.917 96.067 241.475 –31.533 470 276.409 322.712 199.114 58.091 97.012 266.859 –29.658

20. NAPHTHALENE C10H8 (g) 298.15 131.920 333.150 333.150 0.000 150.580 224.100 –39.260 300 132.840 333.970 333.157 0.244 150.450 224.560 –39.098 400 180.070 378.800 338.950 15.940 144.190 250.270 –32.681 500 219.740 423.400 351.400 36.000 139.220 277.340 –28.973 600 251.530 466.380 367.007 59.624 135.350 305.330 –26.581 700 277.010 507.140 384.146 86.096 132.330 333.950 –24.919 800 297.730 545.520 401.935 114.868 130.050 362.920 –23.696 900 314.850 581.610 419.918 145.523 128.430 392.150 –22.759 1000 329.170 615.550 437.806 177.744 127.510 421.700 –22.027 1100 341.240 647.500 455.426 211.281 127.100 450.630 –21.398 1200 351.500 677.650 472.707 245.932 126.960 480.450 –20.913 1300 360.260 706.130 489.568 281.531 127.060 509.770 –20.482 1400 367.780 733.110 506.009 317.941 127.390 539.740 –20.137 1500 374.270 758.720 522.019 355.051 127.920 568.940 –19.812

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

21. FORMALDEHYDE H2CO (g) 298.15 35.387 218.760 218.760 0.000 –108.700 –102.667 17.987 300 35.443 218.979 218.761 0.066 –108.731 –102.630 17.869 400 39.240 229.665 220.192 3.789 –110.438 –100.340 13.103 500 43.736 238.900 223.028 7.936 –112.073 –97.623 10.198 600 48.181 247.270 226.381 12.534 –113.545 –94.592 8.235 700 52.280 255.011 229.924 17.560 –114.833 –91.328 6.815 800 55.941 262.236 233.517 22.975 –115.942 –87.893 5.739 900 59.156 269.014 237.088 28.734 –116.889 –84.328 4.894 1000 61.951 275.395 240.603 34.792 –117.696 –80.666 4.213 1100 64.368 281.416 244.042 41.111 –118.382 –76.929 3.653 1200 66.453 287.108 247.396 47.655 –118.966 –73.134 3.183 1300 68.251 292.500 250.660 54.392 –119.463 –69.294 2.784 1400 69.803 297.616 253.833 61.297 –119.887 –65.418 2.441 1500 71.146 302.479 256.915 68.346 –120.249 –61.514 2.142

22. METHANOL CH3OH (g) 298.15 44.101 239.865 239.865 0.000 –201.000 –162.298 28.434 300 44.219 240.139 239.866 0.082 –201.068 –162.057 28.216 400 51.713 253.845 241.685 4.864 –204.622 –148.509 19.393 500 59.800 266.257 245.374 10.442 –207.750 –134.109 14.010 600 67.294 277.835 249.830 16.803 –210.387 –119.125 10.371 700 73.958 288.719 254.616 23.873 –212.570 –103.737 7.741 800 79.838 298.987 259.526 31.569 –214.350 –88.063 5.750 900 85.025 308.696 264.455 39.817 –215.782 –72.188 4.190 1000 89.597 317.896 269.343 48.553 –216.916 –56.170 2.934 1100 93.624 326.629 274.158 57.718 –217.794 –40.050 1.902 1200 97.165 334.930 278.879 67.262 –218.457 –23.861 1.039 1300 100.277 342.833 283.497 77.137 –218.936 –7.624 0.306 1400 103.014 350.367 288.007 87.304 –219.261 8.644 –0.322 1500 105.422 357.558 292.405 97.729 –219.456 24.930 –0.868

23. ACETALDEHYDE C2H4O (g) 298.15 55.318 263.840 263.840 0.000 –166.190 –133.010 23.302 300 55.510 264.180 263.837 0.103 –166.250 –132.800 23.122 400 66.282 281.620 266.147 6.189 –169.530 –121.130 15.818 500 76.675 297.540 270.850 13.345 –172.420 –108.700 11.356 600 85.942 312.360 276.550 21.486 –174.870 –95.720 8.334 700 94.035 326.230 282.667 30.494 –176.910 –82.350 6.145 800 101.070 339.260 288.938 40.258 –178.570 –68.730 4.487 900 107.190 351.520 295.189 50.698 –179.880 –54.920 3.187 1000 112.490 363.100 301.431 61.669 –180.850 –40.930 2.138 1100 117.080 374.040 307.537 73.153 –181.560 –27.010 1.283 1200 121.060 384.400 313.512 85.065 –182.070 –12.860 0.560 1300 124.500 394.230 319.350 97.344 –182.420 1.240 –0.050 1400 127.490 403.570 325.031 109.954 –182.640 15.470 –0.577 1500 130.090 412.460 330.571 122.834 –182.750 29.580 –1.030

24. ETHANOL C2H5OH (g) 298.15 65.652 281.622 281.622 0.000 –234.800 –167.874 29.410 300 65.926 282.029 281.623 0.122 –234.897 –167.458 29.157 400 81.169 303.076 284.390 7.474 –239.826 –144.216 18.832 500 95.400 322.750 290.115 16.318 –243.940 –119.820 12.517 600 107.656 341.257 297.112 26.487 –247.260 –94.672 8.242 700 118.129 358.659 304.674 37.790 –249.895 –69.023 5.151 800 127.171 375.038 312.456 50.065 –251.951 –43.038 2.810 900 135.049 390.482 320.276 63.185 –253.515 –16.825 0.976 1000 141.934 405.075 328.033 77.042 –254.662 9.539 –0.498 1100 147.958 418.892 335.670 91.543 –255.454 36.000 –1.709 1200 153.232 431.997 343.156 106.609 –255.947 62.520 –2.721

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1300 157.849 444.448 350.473 122.168 –256.184 89.070 –3.579 1400 161.896 456.298 357.612 138.160 –256.206 115.630 –4.314 1500 165.447 467.591 364.571 154.531 –256.044 142.185 –4.951

25. ACETIC ACID C2H4O2 (g) 298.15 63.438 283.470 283.470 0.000 –432.249 –374.254 65.567 300 63.739 283.863 283.471 0.118 –432.324 –373.893 65.100 400 79.665 304.404 286.164 7.296 –436.006 –353.840 46.206 500 93.926 323.751 291.765 15.993 –438.875 –332.950 34.783 600 106.181 341.988 298.631 26.014 –440.993 –311.554 27.123 700 116.627 359.162 306.064 37.169 –442.466 –289.856 21.629 800 125.501 375.331 313.722 49.287 –443.395 –267.985 17.497 900 132.989 390.558 321.422 62.223 –443.873 –246.026 14.279 1000 139.257 404.904 329.060 75.844 –443.982 –224.034 11.702 1100 144.462 418.429 336.576 90.039 –443.798 –202.046 9.594 1200 148.760 431.189 343.933 104.707 –443.385 –180.086 7.839 1300 152.302 443.240 351.113 119.765 –442.795 –158.167 6.355 1400 155.220 454.637 358.105 135.146 –442.071 –136.299 5.085 1500 157.631 465.432 364.903 150.793 –441.247 –114.486 3.987

26. ACETONE C3H6O (g) 298.15 74.517 295.349 295.349 0.000 –217.150 –152.716 26.757 300 74.810 295.809 295.349 0.138 –217.233 –152.339 26.521 400 91.755 319.658 298.498 8.464 –222.212 –129.913 16.962 500 107.864 341.916 304.988 18.464 –226.522 –106.315 11.107 600 122.047 362.836 312.873 29.978 –230.120 –81.923 7.133 700 134.306 382.627 321.470 42.810 –233.049 –56.986 4.252 800 144.934 401.246 330.265 56.785 –235.350 –31.673 2.068 900 154.097 418.860 339.141 71.747 –237.149 –6.109 0.353 1000 162.046 435.513 347.950 87.563 –238.404 19.707 –1.030 1100 168.908 451.286 356.617 104.136 –239.283 45.396 –2.157 1200 174.891 466.265 365.155 121.332 –239.827 71.463 –3.110 1300 180.079 480.491 373.513 139.072 –240.120 97.362 –3.912 1400 184.556 493.963 381.596 157.314 –240.203 123.470 –4.607 1500 188.447 506.850 389.533 175.975 –240.120 149.369 –5.202

27. PHENOL C6H6O (g) 298.15 103.220 314.810 314.810 0.000 –96.400 –32.630 5.720 300 103.860 315.450 314.810 0.192 –96.490 –32.230 5.610 400 135.790 349.820 319.278 12.217 –100.870 –10.180 1.330 500 161.910 383.040 328.736 27.152 –104.240 12.970 –1.360 600 182.480 414.450 340.430 44.412 –106.810 36.650 –3.190 700 198.840 443.860 353.134 63.508 –108.800 60.750 –4.530 800 212.140 471.310 366.211 84.079 –110.300 85.020 –5.550 900 223.190 496.950 379.327 105.861 –111.370 109.590 –6.360 1000 232.490 520.960 392.302 128.658 –111.990 134.280 –7.010 1100 240.410 543.500 405.033 152.314 –112.280 158.620 –7.530 1200 247.200 564.720 417.468 176.703 –112.390 183.350 –7.980 1300 253.060 584.740 429.568 201.723 –112.330 208.070 –8.360 1400 258.120 603.680 441.331 227.288 –112.120 233.050 –8.700 1500 262.520 621.650 452.767 253.325 –111.780 257.540 –8.970

28. CARBON TETRAFLUORIDE CF4 (g) 298.15 61.050 261.455 261.455 0.000 –933.200 –888.518 155.663 300 61.284 261.833 261.456 0.113 –933.219 –888.240 154.654 400 72.399 281.057 264.001 6.822 –933.986 –873.120 114.016 500 80.713 298.153 269.155 14.499 –934.372 –857.852 89.618 600 86.783 313.434 275.284 22.890 –934.490 –842.533 73.348 700 91.212 327.162 281.732 31.801 –934.431 –827.210 61.726 800 94.479 339.566 288.199 41.094 –934.261 –811.903 53.011 900 96.929 350.842 294.542 50.670 –934.024 –796.622 46.234

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1000 98.798 361.156 300.695 60.460 –933.745 –781.369 40.814 1100 100.250 370.643 306.629 70.416 –933.442 –766.146 36.381 1200 101.396 379.417 312.334 80.500 –933.125 –750.952 32.688 1300 102.314 387.571 317.811 90.687 –932.800 –735.784 29.564 1400 103.059 395.181 323.069 100.957 –932.470 –720.641 26.887 1500 103.671 402.313 328.116 111.295 –932.137 –705.522 24.568

29. TRIFLUOROMETHANE CHF3 (g) 298.15 51.069 259.675 259.675 0.000 –696.700 –662.237 116.020 300 51.258 259.991 259.676 0.095 –696.735 –662.023 115.267 400 61.148 276.113 261.807 5.722 –698.427 –650.186 84.905 500 69.631 290.700 266.149 12.275 –699.715 –637.969 66.647 600 76.453 304.022 271.368 19.593 –700.634 –625.528 54.456 700 81.868 316.230 276.917 27.519 –701.253 –612.957 45.739 800 86.201 327.455 282.542 35.930 –701.636 –600.315 39.196 900 89.719 337.818 288.116 44.732 –701.832 –587.636 34.105 1000 92.617 347.426 293.572 53.854 –701.879 –574.944 30.032 1100 95.038 356.370 298.879 63.240 –701.805 –562.253 26.699 1200 97.084 364.730 304.022 72.849 –701.629 –549.574 23.922 1300 98.833 372.571 308.997 82.647 –701.368 –536.913 21.573 1400 100.344 379.952 313.804 92.607 –701.033 –524.274 19.561 1500 101.660 386.921 318.449 102.709 –700.635 –511.662 17.817

30. CHLOROTRIFLUOROMETHANE CClF3 (g) 298.15 66.886 285.419 285.419 0.000 –707.800 –667.238 116.896 300 67.111 285.834 285.421 0.124 –707.810 –666.986 116.131 400 77.528 306.646 288.187 7.383 –708.153 –653.316 85.313 500 85.013 324.797 293.734 15.532 –708.170 –639.599 66.818 600 90.329 340.794 300.271 24.314 –707.975 –625.901 54.489 700 94.132 355.020 307.096 33.547 –707.654 –612.246 45.686 800 96.899 367.780 313.897 43.106 –707.264 –598.642 39.087 900 98.951 379.317 320.536 52.903 –706.837 –585.090 33.957 1000 100.507 389.827 326.947 62.880 –706.396 –571.586 29.856 1100 101.708 399.465 333.108 72.993 –705.950 –558.126 26.503 1200 102.651 408.357 339.013 83.213 –705.505 –544.707 23.710 1300 103.404 416.604 344.668 93.517 –705.064 –531.326 21.349 1400 104.012 424.290 350.084 103.889 –704.628 –517.977 19.326 1500 104.512 431.484 355.273 114.316 –704.196 –504.660 17.574

31. DICHLORODIFLUOROMETHANE CCl2F2 (g) 298.15 72.476 300.903 300.903 0.000 –486.000 –447.030 78.317 300 72.691 301.352 300.905 0.134 –486.002 –446.788 77.792 400 82.408 323.682 303.883 7.919 –485.945 –433.716 56.637 500 89.063 342.833 309.804 16.514 –485.618 –420.692 43.949 600 93.635 359.500 316.729 25.663 –485.136 –407.751 35.497 700 96.832 374.189 323.909 35.196 –484.576 –394.897 29.467 800 99.121 387.276 331.027 44.999 –483.984 –382.126 24.950 900 100.801 399.053 337.942 55.000 –483.388 –369.429 21.441 1000 102.062 409.742 344.596 65.146 –482.800 –356.799 18.637 1100 103.030 419.517 350.969 75.402 –482.226 –344.227 16.346 1200 103.786 428.515 357.061 85.745 –481.667 –331.706 14.439 1300 104.388 436.847 362.882 96.154 –481.121 –319.232 12.827 1400 104.874 444.602 368.445 106.618 –480.588 –306.799 11.447 1500 105.270 451.851 373.767 117.126 –480.065 –294.404 10.252

32. CHLORODIFLUOROMETHANE CHClF2 (g) 298.15 55.853 280.915 280.915 0.000 –475.000 –443.845 77.759 300 56.039 281.261 280.916 0.104 –475.028 –443.652 77.246 400 65.395 298.701 283.231 6.188 –476.390 –432.978 56.540 500 73.008 314.145 287.898 13.123 –477.398 –422.001 44.086 600 78.940 328.003 293.448 20.733 –478.103 –410.851 35.767

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

700 83.551 340.533 299.294 28.867 –478.574 –399.603 29.818 800 87.185 351.936 305.172 37.411 –478.870 –388.299 25.353 900 90.100 362.379 310.956 46.280 –479.031 –376.967 21.878 1000 92.475 371.999 316.586 55.413 –479.090 –365.622 19.098 1100 94.433 380.908 322.033 64.761 –479.068 –354.276 16.823 1200 96.066 389.196 327.289 74.289 –478.982 –342.935 14.927 1300 97.438 396.941 332.352 83.966 –478.843 –331.603 13.324 1400 98.601 404.206 337.228 93.769 –478.661 –320.283 11.950 1500 99.593 411.044 341.923 103.681 –478.443 –308.978 10.759

33. METHYLAMINE CH5N (g) 298.15 50.053 242.881 242.881 0.000 –22.529 32.734 –5.735 300 50.227 243.196 242.893 0.091 –22.614 33.077 –5.759 400 60.171 258.986 244.975 5.604 –26.846 52.294 –6.829 500 70.057 273.486 249.244 12.121 –30.431 72.510 –7.575 600 78.929 287.063 254.431 19.579 –33.364 93.382 –8.129 700 86.711 299.826 260.008 27.873 –35.712 114.702 –8.559 800 93.545 311.865 265.749 36.893 –37.548 136.316 –8.900 900 99.573 323.239 271.511 46.555 –38.949 158.138 –9.178 1000 104.886 334.006 277.220 56.786 –39.967 180.098 –9.407 1100 109.576 344.233 282.861 67.509 –40.681 201.822 –9.584 1200 113.708 353.944 288.374 78.685 –41.136 224.240 –9.761 1300 117.341 363.190 293.775 90.239 –41.376 246.364 –9.899 1400 120.542 372.012 299.061 102.131 –41.451 268.504 –10.018 1500 123.353 380.426 304.209 114.326 –41.381 290.639 –10.121

34. CHLORINE Cl (g) 298.15 21.838 165.190 165.190 0.000 121.302 105.306 –18.449 300 21.852 165.325 165.190 0.040 121.311 105.207 –18.318 400 22.467 171.703 166.055 2.259 121.795 99.766 –13.028 500 22.744 176.752 167.708 4.522 122.272 94.203 –9.841 600 22.781 180.905 169.571 6.800 122.734 88.546 –7.709 700 22.692 184.411 171.448 9.074 123.172 82.813 –6.179 800 22.549 187.432 173.261 11.337 123.585 77.019 –5.029 900 22.389 190.079 174.986 13.584 123.971 71.175 –4.131 1000 22.233 192.430 176.615 15.815 124.334 65.289 –3.410 1100 22.089 194.542 178.150 18.031 124.675 59.368 –2.819 1200 21.959 196.458 179.597 20.233 124.996 53.416 –2.325 1300 21.843 198.211 180.963 22.423 125.299 47.439 –1.906 1400 21.742 199.826 182.253 24.602 125.587 41.439 –1.546 1500 21.652 201.323 183.475 26.772 125.861 35.418 –1.233

35. DICHLORINE Cl2 (g) 298.15 33.949 223.079 223.079 0.000 0.000 0.000 0.000 300 33.981 223.290 223.080 0.063 0.000 0.000 0.000 400 35.296 233.263 224.431 3.533 0.000 0.000 0.000 500 36.064 241.229 227.021 7.104 0.000 0.000 0.000 600 36.547 247.850 229.956 10.736 0.000 0.000 0.000 700 36.874 253.510 232.926 14.408 0.000 0.000 0.000 800 37.111 258.450 235.815 18.108 0.000 0.000 0.000 900 37.294 262.832 238.578 21.829 0.000 0.000 0.000 1000 37.442 266.769 241.203 25.566 0.000 0.000 0.000 1100 37.567 270.343 243.692 29.316 0.000 0.000 0.000 1200 37.678 273.617 246.052 33.079 0.000 0.000 0.000 1300 37.778 276.637 248.290 36.851 0.000 0.000 0.000 1400 37.872 279.440 250.416 40.634 0.000 0.000 0.000 1500 37.961 282.056 252.439 44.426 0.000 0.000 0.000

36. HYDROGEN CHLORIDE HCl (g) 298.15 29.136 186.902 186.902 0.000 –92.310 –95.298 16.696 300 29.137 187.082 186.902 0.054 –92.314 –95.317 16.596

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

400 29.175 195.468 188.045 2.969 –92.587 –96.278 12.573 500 29.304 201.990 190.206 5.892 –92.911 –97.164 10.151 600 29.576 207.354 192.630 8.835 –93.249 –97.983 8.530 700 29.988 211.943 195.069 11.812 –93.577 –98.746 7.368 800 30.500 215.980 197.435 14.836 –93.879 –99.464 6.494 900 31.063 219.604 199.700 17.913 –94.149 –100.145 5.812 1000 31.639 222.907 201.858 21.049 –94.384 –100.798 5.265 1100 32.201 225.949 203.912 24.241 –94.587 –101.430 4.816 1200 32.734 228.774 205.867 27.488 –94.760 –102.044 4.442 1300 33.229 231.414 207.732 30.786 –94.908 –102.645 4.124 1400 33.684 233.893 209.513 34.132 –95.035 –103.235 3.852 1500 34.100 236.232 211.217 37.522 –95.146 –103.817 3.615

37. COPPER Cu (cr, l) 298.15 24.440 33.150 33.150 0.000 0.000 0.000 0.000 300 24.460 33.301 33.150 0.045 0.000 0.000 0.000 400 25.339 40.467 34.122 2.538 0.000 0.000 0.000 500 25.966 46.192 35.982 5.105 0.000 0.000 0.000 600 26.479 50.973 38.093 7.728 0.000 0.000 0.000 700 26.953 55.090 40.234 10.399 0.000 0.000 0.000 800 27.448 58.721 42.322 13.119 0.000 0.000 0.000 900 28.014 61.986 44.328 15.891 0.000 0.000 0.000 1000 28.700 64.971 46.245 18.726 0.000 0.000 0.000 1100 29.553 67.745 48.075 21.637 0.000 0.000 0.000 1200 30.617 70.361 49.824 24.644 0.000 0.000 0.000 1300 31.940 72.862 51.501 27.769 0.000 0.000 0.000 1358 32.844 74.275 52.443 29.647 0.000 0.000 0.000

PHASE TRANSITION: ∆trs H = 13.141 kJ/mol, ∆trs S = 9.676 J/K⋅mol, cr-l 1358 32.800 83.951 52.443 42.788 0.000 0.000 0.000 1400 32.800 84.950 53.403 44.166 0.000 0.000 0.000 1500 32.800 87.213 55.583 47.446 0.000 0.000 0.000

38. COPPER Cu (g) 298.15 20.786 166.397 166.397 0.000 337.600 297.873 –52.185 300 20.786 166.525 166.397 0.038 337.594 297.626 –51.821 400 20.786 172.505 167.213 2.117 337.179 284.364 –37.134 500 20.786 177.143 168.752 4.196 336.691 271.215 –28.333 600 20.786 180.933 170.476 6.274 336.147 258.170 –22.475 700 20.786 184.137 172.205 8.353 335.554 245.221 –18.298 800 20.786 186.913 173.874 10.431 334.913 232.359 –15.171 900 20.786 189.361 175.461 12.510 334.219 219.581 –12.744 1000 20.786 191.551 176.963 14.589 333.463 206.883 –10.806 1100 20.788 193.532 178.380 16.667 332.631 194.265 –9.225 1200 20.793 195.341 179.719 18.746 331.703 181.726 –7.910 1300 20.803 197.006 180.986 20.826 330.657 169.270 –6.801 1400 20.823 198.548 182.186 22.907 316.342 157.305 –5.869 1500 20.856 199.986 183.325 24.991 315.146 145.987 –5.084

39. COPPER OXIDE CuO (cr) 298.15 42.300 42.740 42.740 0.000 –162.000 –134.277 23.524 300 42.417 43.002 42.741 0.078 –161.994 –134.105 23.349 400 46.783 55.878 44.467 4.564 –161.487 –124.876 16.307 500 49.190 66.596 47.852 9.372 –160.775 –115.803 12.098 600 50.827 75.717 51.755 14.377 –159.973 –106.883 9.305 700 52.099 83.651 55.757 19.526 –159.124 –98.102 7.320 800 53.178 90.680 59.691 24.791 –158.247 –89.444 5.840 900 54.144 97.000 63.491 30.158 –157.356 –80.897 4.695 1000 55.040 102.751 67.134 35.617 –156.462 –72.450 3.784 1100 55.890 108.037 70.615 41.164 –155.582 –64.091 3.043 1200 56.709 112.936 73.941 46.794 –154.733 –55.812 2.429

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1300 57.507 117.507 77.118 52.505 –153.940 –47.601 1.913 1400 58.288 121.797 80.158 58.295 –166.354 –39.043 1.457 1500 59.057 125.845 83.070 64.163 –165.589 –29.975 1.044

40. DICOPPER OXIDE Cu2O (cr) 298.15 62.600 92.550 92.550 0.000 –173.100 –150.344 26.339 300 62.721 92.938 92.551 0.116 –173.102 –150.203 26.152 400 67.587 111.712 95.078 6.654 –173.036 –142.572 18.618 500 70.784 127.155 99.995 13.580 –172.772 –134.984 14.101 600 73.323 140.291 105.643 20.789 –172.389 –127.460 11.096 700 75.552 151.764 111.429 28.235 –171.914 –120.009 8.955 800 77.616 161.989 117.121 35.894 –171.363 –112.631 7.354 900 79.584 171.245 122.629 43.755 –170.750 –105.325 6.113 1000 81.492 179.729 127.920 51.809 –170.097 –98.091 5.124 1100 83.360 187.584 132.992 60.052 –169.431 –90.922 4.317 1200 85.202 194.917 137.850 68.480 –168.791 –83.814 3.648 1300 87.026 201.808 142.507 77.092 –168.223 –76.756 3.084 1400 88.836 208.324 146.978 85.885 –194.030 –68.926 2.572 1500 90.636 214.515 151.276 94.858 –193.438 –60.010 2.090

41. COPPER DICHLORIDE CuCl2 (cr, l) 298.15 71.880 108.070 108.070 0.000 –218.000 –173.826 30.453 300 71.998 108.515 108.071 0.133 –217.975 –173.552 30.218 400 76.338 129.899 110.957 7.577 –216.494 –158.962 20.758 500 78.654 147.204 116.532 15.336 –214.873 –144.765 15.123 600 80.175 161.687 122.884 23.282 –213.182 –130.901 11.396 675 81.056 171.183 127.732 29.329 –211.185 –120.693 9.340

PHASE TRANSITION: ∆trs H = 0.700 kJ/mol, ∆trs S = 1.037 J/K.mol, crII-crI 675 82.400 172.220 127.732 30.029 –211.185 –120.693 9.340 700 82.400 175.216 129.375 32.089 –210.719 –117.350 8.757 800 82.400 186.219 135.808 40.329 –208.898 –104.137 6.799 871 82.400 193.226 140.207 46.179 –192.649 –94.893 5.691

PHASE TRANSITION: ∆trs H = 15.001 kJ/mol, ∆trs S = 17.221 J/K.mol, crI-l 871 100.000 210.447 140.207 61.180 –192.649 –94.893 5.691 900 100.000 213.723 142.523 64.080 –191.640 –91.655 5.319 1000 100.000 224.259 150.179 74.080 –188.212 –80.730 4.217 1100 100.000 233.790 157.353 84.080 –184.873 –70.144 3.331 1130.75 100.000 236.547 159.470 87.155 –183.867 –66.951 3.093

42. COPPER DICHLORIDE CuCl2 (g) 298.15 56.814 278.418 278.418 0.000 –43.268 –49.883 8.739 300 56.869 278.769 278.419 0.105 –43.271 –49.924 8.692 400 58.992 295.456 280.679 5.911 –43.428 –52.119 6.806 500 60.111 308.752 285.010 11.871 –43.606 –54.271 5.670 600 60.761 319.774 289.911 17.918 –43.814 –56.385 4.909 700 61.168 329.173 294.865 24.015 –44.060 –58.462 4.362 800 61.439 337.360 299.677 30.147 –44.349 –60.500 3.950 900 61.630 344.608 304.274 36.301 –44.688 –62.499 3.627 1000 61.776 351.109 308.638 42.471 –45.088 –64.457 3.367 1100 61.900 357.003 312.771 48.655 –45.566 –66.372 3.152 1200 62.022 362.394 316.685 54.851 –46.139 –68.239 2.970 1300 62.159 367.364 320.395 61.060 –46.829 –70.053 2.815 1400 62.325 371.976 323.916 67.284 –60.784 –71.404 2.664 1500 62.531 376.283 327.265 73.526 –61.613 –72.133 2.512

43. FLUORINE F (g) 298.15 22.746 158.750 158.750 0.000 79.380 62.280 –10.911 300 22.742 158.891 158.750 0.042 79.393 62.173 –10.825 400 22.432 165.394 159.639 2.302 80.043 56.332 –7.356 500 22.100 170.363 161.307 4.528 80.587 50.340 –5.259

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

600 21.832 174.368 163.161 6.724 81.046 44.246 –3.852 700 21.629 177.717 165.008 8.897 81.442 38.081 –2.842 800 21.475 180.595 166.780 11.052 81.792 31.862 –2.080 900 21.357 183.117 168.458 13.193 82.106 25.601 –1.486 1000 21.266 185.362 170.039 15.324 82.391 19.308 –1.009 1100 21.194 187.386 171.525 17.447 82.654 12.986 –0.617 1200 21.137 189.227 172.925 19.563 82.897 6.642 –0.289 1300 21.091 190.917 174.245 21.675 83.123 0.278 –0.011 1400 21.054 192.479 175.492 23.782 83.335 –6.103 0.228 1500 21.022 193.930 176.673 25.886 83.533 –12.498 0.435

44. DIFLUORINE F2 (g) 298.15 31.304 202.790 202.790 0.000 0.000 0.000 0.000 300 31.337 202.984 202.790 0.058 0.000 0.000 0.000 400 32.995 212.233 204.040 3.277 0.000 0.000 0.000 500 34.258 219.739 206.453 6.643 0.000 0.000 0.000 600 35.171 226.070 209.208 10.117 0.000 0.000 0.000 700 35.839 231.545 212.017 13.669 0.000 0.000 0.000 800 36.343 236.365 214.765 17.279 0.000 0.000 0.000 900 36.740 240.669 217.409 20.934 0.000 0.000 0.000 1000 37.065 244.557 219.932 24.625 0.000 0.000 0.000 1100 37.342 248.103 222.334 28.346 0.000 0.000 0.000 1200 37.588 251.363 224.619 32.093 0.000 0.000 0.000 1300 37.811 254.381 226.794 35.863 0.000 0.000 0.000 1400 38.019 257.191 228.866 39.654 0.000 0.000 0.000 1500 38.214 259.820 230.843 43.466 0.000 0.000 0.000

45. HYDROGEN FLUORIDE HF (g) 298.15 29.137 173.776 173.776 0.000 –273.300 –275.399 48.248 300 29.137 173.956 173.776 0.054 –273.302 –275.412 47.953 400 29.149 182.340 174.919 2.968 –273.450 –276.096 36.054 500 29.172 188.846 177.078 5.884 –273.679 –276.733 28.910 600 29.230 194.169 179.496 8.804 –273.961 –277.318 24.142 700 29.350 198.683 181.923 11.732 –274.277 –277.852 20.733 800 29.549 202.614 184.269 14.676 –274.614 –278.340 18.174 900 29.827 206.110 186.505 17.645 –274.961 –278.785 16.180 1000 30.169 209.270 188.626 20.644 –275.309 –279.191 14.583 1100 30.558 212.163 190.636 23.680 –275.652 –279.563 13.275 1200 30.974 214.840 192.543 26.756 –275.988 –279.904 12.184 1300 31.403 217.336 194.355 29.875 –276.315 –280.217 11.259 1400 31.831 219.679 196.081 33.037 –276.631 –280.505 10.466 1500 32.250 221.889 197.729 36.241 –276.937 –280.771 9.777

46. GERMANIUM Ge (cr, l) 298.15 23.222 31.090 31.090 0.000 0.000 0.000 0.000 300 23.249 31.234 31.090 0.043 0.000 0.000 0.000 400 24.310 38.083 32.017 2.426 0.000 0.000 0.000 500 24.962 43.582 33.798 4.892 0.000 0.000 0.000 600 25.452 48.178 35.822 7.414 0.000 0.000 0.000 700 25.867 52.133 37.876 9.980 0.000 0.000 0.000 800 26.240 55.612 39.880 12.586 0.000 0.000 0.000 900 26.591 58.723 41.804 15.227 0.000 0.000 0.000 1000 26.926 61.542 43.639 17.903 0.000 0.000 0.000 1100 27.252 64.124 45.386 20.612 0.000 0.000 0.000 1200 27.571 66.509 47.048 23.353 0.000 0.000 0.000 1211.4 27.608 66.770 47.232 23.668 0.000 0.000 0.000

PHASE TRANSITION: ∆trs H = 37.030 kJ/mol, ∆trs S = 30.568 J/K.mol, cr-l 1211.4 27.600 97.338 47.232 60.698 0.000 0.000 0.000 1300 27.600 99.286 50.714 63.143 0.000 0.000 0.000 1400 27.600 101.331 54.258 65.903 0.000 0.000 0.000

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

47. GERMANIUM Ge (g) 298.15 30.733 167.903 167.903 0.000 367.800 327.009 –57.290 300 30.757 168.094 167.904 0.057 367.814 326.756 –56.893 400 31.071 177.025 169.119 3.162 368.536 312.959 –40.868 500 30.360 183.893 171.415 6.239 369.147 298.991 –31.235 600 29.265 189.334 173.965 9.222 369.608 284.914 –24.804 700 28.102 193.758 176.487 12.090 369.910 270.773 –20.205 800 27.029 197.439 178.882 14.845 370.060 256.598 –16.754 900 26.108 200.567 181.122 17.501 370.073 242.414 –14.069 1000 25.349 203.277 183.205 20.072 369.969 228.234 –11.922 1100 24.741 205.664 185.141 22.575 369.763 214.069 –10.165 1200 24.264 207.795 186.941 25.025 369.471 199.928 –8.703 1300 23.898 209.722 188.621 27.432 332.088 188.521 –7.575 1400 23.624 211.483 190.192 29.807 331.704 177.492 –6.622 1500 23.426 213.105 191.666 32.159 331.296 166.491 –5.798

48. GERMANIUM DIOXIDE GeO2 (cr, l) 298.15 50.166 39.710 39.710 0.000 –580.200 –521.605 91.382 300 50.475 40.021 39.711 0.093 –580.204 –521.242 90.755 400 61.281 56.248 41.850 5.759 –579.893 –501.610 65.503 500 66.273 70.519 46.191 12.164 –579.013 –482.134 50.368 600 69.089 82.872 51.299 18.943 –577.915 –462.859 40.295 700 70.974 93.671 56.597 25.952 –576.729 –443.776 33.115 800 72.449 103.247 61.841 33.125 –575.498 –424.866 27.741 900 73.764 111.857 66.928 40.436 –574.235 –406.113 23.570 1000 75.049 119.696 71.819 47.877 –572.934 –387.502 20.241 1100 76.378 126.910 76.504 55.447 –571.582 –369.024 17.523 1200 77.796 133.616 80.987 63.155 –570.166 –350.671 15.264 1300 79.332 139.903 85.279 71.010 –605.685 –329.732 13.249 1308 79.460 140.390 85.615 71.646 –584.059 –328.034 13.100

PHASE TRANSITION: ∆trs H = 21.500 kJ/mol, ∆trs S = 16.437 J/K.mol, crII-crI 1308 80.075 156.827 85.615 93.146 –584.059 –328.034 13.100 1388 81.297 161.617 89.858 99.601 –565.504 –312.415 11.757

PHASE TRANSITION: ∆trs H = 17.200 kJ/mol, ∆trs S = 12.392 J/K.mol, crI-l 1388 78.500 174.009 89.858 116.801 –565.504 –312.415 11.757 1400 78.500 174.685 90.582 117.743 –565.328 –310.228 11.575 1500 78.500 180.100 96.372 125.593 –563.882 –292.057 10.170

49. GERMANIUM TETRACHLORIDE GeCl4 (g) 298.15 95.918 348.393 348.393 0.000 –500.000 –461.582 80.866 300 96.041 348.987 348.395 0.178 –499.991 –461.343 80.326 400 100.750 377.342 352.229 10.045 –499.447 –448.540 58.573 500 103.206 400.114 359.604 20.255 –498.845 –435.882 45.536 600 104.624 419.067 367.980 30.652 –498.234 –423.347 36.855 700 105.509 435.266 376.463 41.162 –497.634 –410.914 30.662 800 106.096 449.396 384.715 51.744 –497.057 –398.565 26.023 900 106.504 461.917 392.611 62.375 –496.509 –386.287 22.419 1000 106.799 473.155 400.113 73.041 –495.993 –374.068 19.539 1100 107.020 483.344 407.224 83.733 –495.512 –361.899 17.185 1200 107.189 492.664 413.961 94.444 –495.067 –349.772 15.225 1300 107.320 501.249 420.349 105.169 –531.677 –334.973 13.459 1400 107.425 509.206 426.416 115.907 –531.265 –319.857 11.934 1500 107.509 516.621 432.185 126.654 –530.861 –304.771 10.613

50. HYDROGEN H (g) 298.15 20.786 114.716 114.716 0.000 217.998 203.276 –35.613 300 20.786 114.845 114.716 0.038 218.010 203.185 –35.377 400 20.786 120.824 115.532 2.117 218.635 198.149 –25.875 500 20.786 125.463 117.071 4.196 219.253 192.956 –20.158

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

600 20.786 129.252 118.795 6.274 219.867 187.639 –16.335 700 20.786 132.457 120.524 8.353 220.476 182.219 –13.597 800 20.786 135.232 122.193 10.431 221.079 176.712 –11.538 900 20.786 137.680 123.780 12.510 221.670 171.131 –9.932 1000 20.786 139.870 125.282 14.589 222.247 165.485 –8.644 1100 20.786 141.852 126.700 16.667 222.806 159.781 –7.587 1200 20.786 143.660 128.039 18.746 223.345 154.028 –6.705 1300 20.786 145.324 129.305 20.824 223.864 148.230 –5.956 1400 20.786 146.864 130.505 22.903 224.360 142.393 –5.313 1500 20.786 148.298 131.644 24.982 224.835 136.522 –4.754

51. DIHYDROGEN H2 (g) 298.15 28.836 130.680 130.680 0.000 0.000 0.000 0.000 300 28.849 130.858 130.680 0.053 0.000 0.000 0.000 400 29.181 139.217 131.818 2.960 0.000 0.000 0.000 500 29.260 145.738 133.974 5.882 0.000 0.000 0.000 600 29.327 151.078 136.393 8.811 0.000 0.000 0.000 700 29.440 155.607 138.822 11.749 0.000 0.000 0.000 800 29.623 159.549 141.172 14.702 0.000 0.000 0.000 900 29.880 163.052 143.412 17.676 0.000 0.000 0.000 1000 30.204 166.217 145.537 20.680 0.000 0.000 0.000 1100 30.580 169.113 147.550 23.719 0.000 0.000 0.000 1200 30.991 171.791 149.460 26.797 0.000 0.000 0.000 1300 31.422 174.288 151.275 29.918 0.000 0.000 0.000 1400 31.860 176.633 153.003 33.082 0.000 0.000 0.000 1500 32.296 178.846 154.653 36.290 0.000 0.000 0.000

52. HYDROXYL OH (g) 298.15 29.886 183.737 183.737 0.000 39.349 34.631 –6.067 300 29.879 183.922 183.738 0.055 39.350 34.602 –6.025 400 29.604 192.476 184.906 3.028 39.384 33.012 –4.311 500 29.495 199.067 187.104 5.982 39.347 31.422 –3.283 600 29.513 204.445 189.560 8.931 39.252 29.845 –2.598 700 29.655 209.003 192.020 11.888 39.113 28.287 –2.111 800 29.914 212.979 194.396 14.866 38.945 26.752 –1.747 900 30.265 216.522 196.661 17.874 38.763 25.239 –1.465 1000 30.682 219.731 198.810 20.921 38.577 23.746 –1.240 1100 31.135 222.677 200.848 24.012 38.393 22.272 –1.058 1200 31.603 225.406 202.782 27.149 38.215 20.814 –0.906 1300 32.069 227.954 204.621 30.332 38.046 19.371 –0.778 1400 32.522 230.347 206.374 33.562 37.886 17.941 –0.669 1500 32.956 232.606 208.048 36.836 37.735 16.521 –0.575

53. WATER H2O (l) 298.15 75.300 69.950 69.950 0.000 –285.830 –237.141 41.546 300 75.281 70.416 69.951 0.139 –285.771 –236.839 41.237 373.21 76.079 86.896 71.715 5.666 –283.454 –225.160 31.513

54. WATER H2O (g) 298.15 33.598 188.832 188.832 0.000 –241.826 –228.582 40.046 300 33.606 189.040 188.833 0.062 –241.844 –228.500 39.785 400 34.283 198.791 190.158 3.453 –242.845 –223.900 29.238 500 35.259 206.542 192.685 6.929 –243.822 –219.050 22.884 600 36.371 213.067 195.552 10.509 –244.751 –214.008 18.631 700 37.557 218.762 198.469 14.205 –245.620 –208.814 15.582 800 38.800 223.858 201.329 18.023 –246.424 –203.501 13.287 900 40.084 228.501 204.094 21.966 –247.158 –198.091 11.497 1000 41.385 232.792 206.752 26.040 –247.820 –192.603 10.060 1100 42.675 236.797 209.303 30.243 –248.410 –187.052 8.882 1200 43.932 240.565 211.753 34.574 –248.933 –181.450 7.898 1300 45.138 244.129 214.108 39.028 –249.392 –175.807 7.064

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1400 46.281 247.516 216.374 43.599 –249.792 –170.132 6.348 1500 47.356 250.746 218.559 48.282 –250.139 –164.429 5.726

55. IODINE I (g) 298.15 20.786 180.787 180.787 0.000 106.760 70.172 –12.294 300 20.786 180.915 180.787 0.038 106.748 69.945 –12.178 400 20.786 186.895 181.602 2.117 97.974 58.060 –7.582 500 20.786 191.533 183.142 4.196 75.988 50.202 –5.244 600 20.786 195.323 184.866 6.274 76.190 45.025 –3.920 700 20.786 198.527 186.594 8.353 76.385 39.816 –2.971 800 20.787 201.303 188.263 10.432 76.574 34.579 –2.258 900 20.789 203.751 189.851 12.510 76.757 29.319 –1.702 1000 20.795 205.942 191.352 14.589 76.936 24.038 –1.256 1100 20.806 207.924 192.770 16.669 77.109 18.740 –0.890 1200 20.824 209.735 194.110 18.751 77.277 13.426 –0.584 1300 20.851 211.403 195.377 20.835 77.440 8.098 –0.325 1400 20.889 212.950 196.577 22.921 77.596 2.758 –0.103 1500 20.936 214.392 197.717 25.013 77.745 –2.592 0.090

56. DIIODINE I2 (cr, l) 298.15 54.440 116.139 116.139 0.000 0.000 0.000 0.000 300 54.518 116.476 116.140 0.101 0.000 0.000 0.000 386.75 61.531 131.039 117.884 5.088 0.000 0.000 0.000

PHASE TRANSITION: ∆trs H = 15.665 kJ/mol, ∆trs S = 40.504 J/K.mol, cr-l 386.75 79.555 171.543 117.884 20.753 0.000 0.000 0.000 400 79.555 174.223 119.706 21.807 0.000 0.000 0.000 457.67 79.555 184.938 127.266 26.395 0.000 0.000 0.000

57. DIIODINE I2 (g) 298.15 36.887 260.685 260.685 0.000 62.420 19.324 –3.385 300 36.897 260.913 260.685 0.068 62.387 19.056 –3.318 400 37.256 271.584 262.138 3.778 44.391 5.447 –0.711 457.67 37.385 276.610 263.652 5.931 pressure = 1 bar 500 37.464 279.921 264.891 7.515 0.000 0.000 0.000 600 37.613 286.765 267.983 11.269 0.000 0.000 0.000 700 37.735 292.573 271.092 15.037 0.000 0.000 0.000 800 37.847 297.619 274.099 18.816 0.000 0.000 0.000 900 37.956 302.083 276.965 22.606 0.000 0.000 0.000 1000 38.070 306.088 279.681 26.407 0.000 0.000 0.000 1100 38.196 309.722 282.249 30.220 0.000 0.000 0.000 1200 38.341 313.052 284.679 34.047 0.000 0.000 0.000 1300 38.514 316.127 286.981 37.890 0.000 0.000 0.000 1400 38.719 318.989 289.166 41.751 0.000 0.000 0.000 1500 38.959 321.668 291.245 45.635 0.000 0.000 0.000

58. HYDROGEN IODIDE HI (g) 298.15 29.157 206.589 206.589 0.000 26.500 1.700 –0.298 300 29.158 206.769 206.589 0.054 26.477 1.546 –0.269 400 29.329 215.176 207.734 2.977 17.093 –6.289 0.821 500 29.738 221.760 209.904 5.928 –5.481 –9.946 1.039 600 30.351 227.233 212.348 8.931 –5.819 –10.806 0.941 700 31.070 231.965 214.820 12.002 –6.101 –11.614 0.867 800 31.807 236.162 217.230 15.145 –6.323 –12.386 0.809 900 32.511 239.950 219.548 18.362 –6.489 –13.133 0.762 1000 33.156 243.409 221.763 21.646 –6.608 –13.865 0.724 1100 33.735 246.597 223.878 24.991 –6.689 –14.586 0.693 1200 34.249 249.555 225.896 28.391 –6.741 –15.302 0.666 1300 34.703 252.314 227.823 31.839 –6.775 –16.014 0.643 1400 35.106 254.901 229.666 35.330 –6.797 –16.723 0.624 1500 35.463 257.336 231.430 38.858 –6.814 –17.432 0.607

J/Kmol kJ/mol T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

59. POTASSIUM K (cr, l) 298.15 29.600 64.680 64.680 0.000 0.000 0.000 0.000 300 29.671 64.863 64.681 0.055 0.000 0.000 0.000 336.86 32.130 68.422 64.896 1.188 0.000 0.000 0.000

PHASE TRANSITION: ∆trs H = 2.321 kJ/mol, ∆trs S = 6.891 J/K.mol, cr-l 336.86 32.129 75.313 64.896 3.509 0.000 0.000 0.000 400 31.552 80.784 66.986 5.519 0.000 0.000 0.000 500 30.741 87.734 70.469 8.632 0.000 0.000 0.000 600 30.158 93.283 73.824 11.675 0.000 0.000 0.000 700 29.851 97.905 76.943 14.673 0.000 0.000 0.000 800 29.838 101.887 79.818 17.655 0.000 0.000 0.000 900 30.130 105.415 82.470 20.651 0.000 0.000 0.000 1000 30.730 108.618 84.927 23.691 0.000 0.000 0.000 1039.4 31.053 109.812 85.847 24.908 0.000 0.000 0.000

60. POTASSIUM K (g) 298.15 20.786 160.340 160.340 0.000 89.000 60.479 –10.596 300 20.786 160.468 160.340 0.038 88.984 60.302 –10.499 400 20.786 166.448 161.155 2.117 85.598 51.332 –6.703 500 20.786 171.086 162.695 4.196 84.563 42.887 –4.480 600 20.786 174.876 164.419 6.274 83.599 34.643 –3.016 700 20.786 178.080 166.148 8.353 82.680 26.557 –1.982 800 20.786 180.856 167.817 10.431 81.776 18.601 –1.215 900 20.786 183.304 169.404 12.510 80.859 10.759 –0.624 1000 20.786 185.494 170.905 14.589 79.897 3.021 –0.158 1039.4 20.786 186.297 171.474 15.408 pressure = 1 bar 1100 20.786 187.475 172.323 16.667 0.000 0.000 0.000 1200 20.786 189.284 173.662 18.746 0.000 0.000 0.000 1300 20.789 190.948 174.929 20.825 0.000 0.000 0.000 1400 20.793 192.489 176.129 22.904 0.000 0.000 0.000 1500 20.801 193.923 177.268 24.983 0.000 0.000 0.000

61. DIPOTASSIUM OXIDE K2O (cr, l) 298.15 72.000 96.000 96.000 0.000 –361.700 –321.171 56.267 300 72.130 96.446 96.001 0.133 –361.704 –320.920 55.876 400 79.154 118.158 98.914 7.698 –366.554 –306.416 40.013 500 86.178 136.575 104.647 15.964 –366.043 –291.423 30.444 590 92.500 151.348 110.662 24.005 –364.204 –278.079 24.619

PHASE TRANSITION: ∆trs H = 0.700 kJ/mol, ∆trs S = 1.186 J/K.mol, crIII-crII 590 100.000 152.534 110.662 24.705 –364.204 –278.079 24.619 600 100.000 154.215 111.374 25.705 –363.968 –276.621 24.082 645 100.000 161.447 114.618 30.205 –358.901 –270.109 21.874

PHASE TRANSITION: ∆trs H = 4.000 kJ/mol, ∆trs S = 6.202 J/K.mol, crII-crI 645 100.000 167.649 114.618 34.205 –358.901 –270.109 21.874 700 100.000 175.832 119.111 39.705 –357.592 –262.592 19.595 800 100.000 189.185 127.054 49.705 –355.224 –249.183 16.270 900 100.000 200.963 134.625 59.705 –352.919 –236.067 13.701 1000 100.000 211.499 141.794 69.705 –350.732 –223.202 11.659 1013 100.000 212.791 142.697 71.005 –323.459 –221.546 11.424

PHASE TRANSITION: ∆trs H = 27.000 kJ/mol, ∆trs S =26.654 J/K.mol, crI-l 1013 100.000 239.444 142.697 98.005 –323.459 –221.546 11.424 1100 100.000 247.684 150.679 106.705 –479.439 –203.633 9.670 1200 100.000 256.385 159.131 116.705 –475.371 –178.740 7.780 1300 100.000 264.389 166.924 126.705 –471.321 –154.185 6.195 1400 100.000 271.800 174.154 136.705 –467.287 –129.941 4.848 1500 100.000 278.699 180.896 146.705 –463.268 –105.986 3.691

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

62. POTASSIUM HYDROXIDE KOH (cr, l) 298.15 64.900 78.870 78.870 0.000 –424.580 –378.747 66.354 300 65.038 79.272 78.871 0.120 –424.569 –378.463 65.895 400 72.519 99.007 81.512 6.998 –426.094 –362.765 47.372 500 80.000 115.993 86.745 14.624 –424.572 –347.093 36.260 520 81.496 119.159 87.931 16.239 –417.725 –344.002 34.555

PHASE TRANSITION: ∆trs H = 6.450 kJ/mol, ∆trs S = 12.404 J/K.mol, crII-crI 520 79.000 131.563 87.931 22.689 –417.725 –344.002 34.555 600 79.000 142.868 94.520 29.009 –416.274 –332.766 28.969 678 79.000 152.523 100.649 35.171 –405.464 –321.998 24.807

PHASE TRANSITION: ∆trs H = 9.400 kJ/mol, ∆trs S = 13.865 J/K.mol, crI-l 678 83.000 166.388 100.649 44.571 –405.464 –321.998 24.807 700 83.000 169.038 102.757 46.397 –404.981 –319.297 23.826 800 83.000 180.121 111.750 54.697 –402.808 –307.206 20.058 900 83.000 189.897 119.901 62.997 –400.694 –295.383 17.143 1000 83.000 198.642 127.345 71.297 –398.668 –283.791 14.824 1100 83.000 206.553 134.192 79.597 –475.618 –267.780 12.716 1200 83.000 213.775 140.527 87.897 –472.711 –249.014 10.839 1300 83.000 220.418 146.421 96.197 –469.843 –230.490 9.261 1400 83.000 226.569 151.929 104.497 –467.011 –212.184 7.917 1500 83.000 232.296 157.098 112.797 –464.217 –194.080 6.758

63. POTASSIUM HYDROXIDE KOH (g) 298.15 49.184 238.283 238.283 0.000 –227.989 –229.685 40.239 300 49.236 238.588 238.284 0.091 –228.007 –229.696 39.993 400 51.178 253.053 240.243 5.124 –231.377 –229.667 29.991 500 52.178 264.591 243.998 10.296 –232.309 –229.129 23.937 600 52.804 274.163 248.251 15.547 –233.145 –228.413 19.885 700 53.296 282.340 252.551 20.853 –233.934 –227.562 16.981 800 53.758 289.487 256.730 26.206 –234.708 –226.599 14.795 900 54.229 295.846 260.730 31.605 –235.495 –225.538 13.090 1000 54.713 301.585 264.533 37.052 –236.322 –224.388 11.721 1100 55.203 306.823 268.143 42.548 –316.077 –218.535 10.377 1200 55.686 311.647 271.570 48.092 –315.925 –209.674 9.127 1300 56.153 316.122 274.827 53.684 –315.764 –200.826 8.069 1400 56.598 320.300 277.927 59.322 –315.595 –191.991 7.163 1500 57.016 324.220 280.884 65.003 –315.420 –183.169 6.378

64. POTASSIUM CHLORIDE KCl (cr, l) 298.15 51.300 82.570 82.570 0.000 –436.490 –408.568 71.579 300 51.333 82.887 82.571 0.095 –436.481 –408.395 71.107 400 52.977 97.886 84.605 5.312 –438.463 –398.651 52.058 500 54.448 109.867 88.498 10.685 –437.990 –388.749 40.612 600 55.885 119.921 92.919 16.201 –437.332 –378.960 32.991 700 57.425 128.649 97.413 21.865 –436.502 –369.295 27.557 800 59.205 136.430 101.812 27.694 –435.505 –359.760 23.490 900 61.361 143.523 106.058 33.719 –434.337 –350.360 20.334 1000 64.032 150.121 110.138 39.983 –432.981 –341.100 17.817 1044 65.405 152.908 111.882 42.830 –485.450 –336.720 16.847

PHASE TRANSITION: ∆trs H = 26.320 kJ/mol, ∆trs S = 25.210 J/K.mol, cr-l 1044 72.000 178.118 111.882 69.150 –485.450 –336.720 16.847 1100 72.000 181.880 115.351 73.182 –483.633 –328.790 15.613 1200 72.000 188.145 121.160 80.382 –480.393 –314.856 13.705 1300 72.000 193.908 126.537 87.582 –477.158 –301.192 12.102 1400 72.000 199.244 131.542 94.782 –473.928 –287.778 10.737 1500 72.000 204.211 136.223 101.982 –470.704 –274.594 9.562

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

65. POTASSIUM CHLORIDE KCl (g) 298.15 36.505 239.091 239.091 0.000 –214.575 –233.320 40.876 300 36.518 239.317 239.092 0.068 –214.594 –233.436 40.644 400 37.066 249.904 240.532 3.749 –218.112 –239.107 31.224 500 37.384 258.212 243.267 7.473 –219.287 –244.219 25.513 600 37.597 265.048 246.344 11.222 –220.396 –249.100 21.686 700 37.769 270.857 249.441 14.991 –221.461 –253.799 18.938 800 37.907 275.910 252.441 18.775 –222.509 –258.347 16.868 900 38.041 280.382 255.302 22.572 –223.568 –262.764 15.250 1000 38.162 284.397 258.014 26.383 –224.667 –267.061 13.950 1100 38.279 288.039 260.581 30.205 –304.696 –266.627 12.661 1200 38.401 291.375 263.010 34.039 –304.821 –263.161 11.455 1300 38.518 294.454 265.312 37.885 –304.941 –259.684 10.434 1400 38.639 297.313 267.496 41.743 –305.053 –256.199 9.559 1500 38.761 299.983 269.574 45.613 –305.159 –252.706 8.800

66. DINITROGEN N2 (g) 298.15 29.124 191.608 191.608 0.000 0.000 0.000 0.000 300 29.125 191.788 191.608 0.054 0.000 0.000 0.000 400 29.249 200.180 192.752 2.971 0.000 0.000 0.000 500 29.580 206.738 194.916 5.911 0.000 0.000 0.000 600 30.109 212.175 197.352 8.894 0.000 0.000 0.000 700 30.754 216.864 199.812 11.936 0.000 0.000 0.000 800 31.433 221.015 202.208 15.046 0.000 0.000 0.000 900 32.090 224.756 204.509 18.222 0.000 0.000 0.000 1000 32.696 228.169 206.706 21.462 0.000 0.000 0.000 1100 33.241 231.311 208.802 24.759 0.000 0.000 0.000 1200 33.723 234.224 210.801 28.108 0.000 0.000 0.000 1300 34.147 236.941 212.708 31.502 0.000 0.000 0.000 1400 34.517 239.485 214.531 34.936 0.000 0.000 0.000 1500 34.842 241.878 216.275 38.404 0.000 0.000 0.000

67. NITRIC OXIDE NO (g) 298.15 29.862 210.745 210.745 0.000 91.277 87.590 –15.345 300 29.858 210.930 210.746 0.055 91.278 87.567 –15.247 400 29.954 219.519 211.916 3.041 91.320 86.323 –11.272 500 30.493 226.255 214.133 6.061 91.340 85.071 –8.887 600 31.243 231.879 216.635 9.147 91.354 83.816 –7.297 700 32.031 236.754 219.168 12.310 91.369 82.558 –6.160 800 32.770 241.081 221.642 15.551 91.386 81.298 –5.308 900 33.425 244.979 224.022 18.862 91.405 80.036 –4.645 1000 33.990 248.531 226.298 22.233 91.426 78.772 –4.115 1100 34.473 251.794 228.469 25.657 91.445 77.505 –3.680 1200 34.883 254.811 230.540 29.125 91.464 76.237 –3.318 1300 35.234 257.618 232.516 32.632 91.481 74.967 –3.012 1400 35.533 260.240 234.404 36.170 91.495 73.697 –2.750 1500 35.792 262.700 236.209 39.737 91.506 72.425 –2.522

68. NITROGEN DIOXIDE NO2 (g) 298.15 37.178 240.166 240.166 0.000 34.193 52.316 –9.165 300 37.236 240.397 240.167 0.069 34.181 52.429 –9.129 400 40.513 251.554 241.666 3.955 33.637 58.600 –7.652 500 43.664 260.939 244.605 8.167 33.319 64.882 –6.778 600 46.383 269.147 248.026 12.673 33.174 71.211 –6.199 700 48.612 276.471 251.575 17.427 33.151 77.553 –5.787 800 50.405 283.083 255.107 22.381 33.213 83.893 –5.478 900 51.844 289.106 258.555 27.496 33.334 90.221 –5.236 1000 53.007 294.631 261.891 32.741 33.495 96.534 –5.042 1100 53.956 299.729 265.102 38.090 33.686 102.828 –4.883 1200 54.741 304.459 268.187 43.526 33.898 109.105 –4.749

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1300 55.399 308.867 271.148 49.034 34.124 115.363 –4.635 1400 55.960 312.994 273.992 54.603 34.360 121.603 –4.537 1500 56.446 316.871 276.722 60.224 34.604 127.827 –4.451

69. AMMONIA NH3 (g) 298.15 35.630 192.768 192.768 0.000 –45.940 –16.407 2.874 300 35.678 192.989 192.769 0.066 –45.981 –16.223 2.825 400 38.674 203.647 194.202 3.778 –48.087 –5.980 0.781 500 41.994 212.633 197.011 7.811 –49.908 4.764 –0.498 600 45.229 220.578 200.289 12.174 –51.430 15.846 –1.379 700 48.269 227.781 203.709 16.850 –52.682 27.161 –2.027 800 51.112 234.414 207.138 21.821 –53.695 38.639 –2.523 900 53.769 240.589 210.516 27.066 –54.499 50.231 –2.915 1000 56.244 246.384 213.816 32.569 –55.122 61.903 –3.233 1100 58.535 251.854 217.027 38.309 –55.589 73.629 –3.496 1200 60.644 257.039 220.147 44.270 –55.920 85.392 –3.717 1300 62.576 261.970 223.176 50.432 –56.136 97.177 –3.905 1400 64.339 266.673 226.117 56.779 –56.251 108.975 –4.066 1500 65.945 271.168 228.971 63.295 –56.282 120.779 –4.206

70. OXYGEN O (g) 298.15 21.911 161.058 161.058 0.000 249.180 231.743 –40.600 300 21.901 161.194 161.059 0.041 249.193 231.635 –40.331 400 21.482 167.430 161.912 2.207 249.874 225.677 –29.470 500 21.257 172.197 163.511 4.343 250.481 219.556 –22.937 600 21.124 176.060 165.290 6.462 251.019 213.319 –18.571 700 21.040 179.310 167.067 8.570 251.500 206.997 –15.446 800 20.984 182.115 168.777 10.671 251.932 200.610 –13.098 900 20.944 184.584 170.399 12.767 252.325 194.171 –11.269 1000 20.915 186.789 171.930 14.860 252.686 187.689 –9.804 1100 20.893 188.782 173.372 16.950 253.022 181.173 –8.603 1200 20.877 190.599 174.733 19.039 253.335 174.628 –7.601 1300 20.864 192.270 176.019 21.126 253.630 168.057 –6.753 1400 20.853 193.815 177.236 23.212 253.908 161.463 –6.024 1500 20.845 195.254 178.389 25.296 254.171 154.851 –5.392

71. DIOXYGEN O2 (g) 298.15 29.378 205.148 205.148 0.000 0.000 0.000 0.000 300 29.387 205.330 205.148 0.054 0.000 0.000 0.000 400 30.109 213.873 206.308 3.026 0.000 0.000 0.000 500 31.094 220.695 208.525 6.085 0.000 0.000 0.000 600 32.095 226.454 211.045 9.245 0.000 0.000 0.000 700 32.987 231.470 213.612 12.500 0.000 0.000 0.000 800 33.741 235.925 216.128 15.838 0.000 0.000 0.000 900 34.365 239.937 218.554 19.244 0.000 0.000 0.000 1000 34.881 243.585 220.878 22.707 0.000 0.000 0.000 1100 35.314 246.930 223.096 26.217 0.000 0.000 0.000 1200 35.683 250.019 225.213 29.768 0.000 0.000 0.000 1300 36.006 252.888 227.233 33.352 0.000 0.000 0.000 1400 36.297 255.568 229.162 36.968 0.000 0.000 0.000 1500 36.567 258.081 231.007 40.611 0.000 0.000 0.000

72. SULFUR S (cr, l) 298.15 22.690 32.070 32.070 0.000 0.000 0.000 0.000 300 22.737 32.210 32.070 0.042 0.000 0.000 0.000 368.3 24.237 37.030 32.554 1.649 0.000 0.000 0.000

PHASE TRANSITION: ∆trs H = 0.401 kJ/mol, ∆trs S = 1.089 J/K.mol, crII-crI 368.3 24.773 38.119 32.553 2.050 0.000 0.000 0.000 388.36 25.180 39.444 32.875 2.551 0.000 0.000 0.000

PHASE TRANSITION: ∆ H = 1.722 kJ/mol, ∆ S = 4.431 J/K.mol, crI-l

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

388.36 31.710 43.875 32.872 4.273 0.000 0.000 0.000 400 32.369 44.824 33.206 4.647 0.000 0.000 0.000 500 38.026 53.578 36.411 8.584 0.000 0.000 0.000 600 34.371 60.116 39.842 12.164 0.000 0.000 0.000 700 32.451 65.278 43.120 15.511 0.000 0.000 0.000 800 32.000 69.557 46.163 18.715 0.000 0.000 0.000 882.38 32.000 72.693 48.496 21.351 0.000 0.000 0.000

73. SULFUR S (g) 298.15 23.673 167.828 167.828 0.000 277.180 236.704 –41.469 300 23.669 167.974 167.828 0.044 277.182 236.453 –41.170 400 23.233 174.730 168.752 2.391 274.924 222.962 –29.115 500 22.741 179.860 170.482 4.689 273.286 210.145 –21.953 600 22.338 183.969 172.398 6.942 271.958 197.646 –17.206 700 22.031 187.388 174.302 9.160 270.829 185.352 –13.831 800 21.800 190.314 176.125 11.351 269.816 173.210 –11.309 900 21.624 192.871 177.847 13.522 215.723 162.258 –9.417 1000 21.489 195.142 179.465 15.677 216.018 156.301 –8.164 1100 21.386 197.185 180.985 17.821 216.284 150.317 –7.138 1200 21.307 199.043 182.413 19.955 216.525 144.309 –6.282 1300 21.249 200.746 183.759 22.083 216.743 138.282 –5.556 1400 21.209 202.319 185.029 24.206 216.940 132.239 –4.934 1500 21.186 203.781 186.231 26.325 217.119 126.182 –4.394

74. DISULFUR S2 (g) 298.15 32.505 228.165 228.165 0.000 128.600 79.696 –13.962 300 32.540 228.366 228.165 0.060 128.576 79.393 –13.823 400 34.108 237.956 229.462 3.398 122.703 63.380 –8.276 500 35.133 245.686 231.959 6.863 118.296 49.031 –5.122 600 35.815 252.156 234.800 10.413 114.685 35.530 –3.093 700 36.305 257.715 237.686 14.020 111.599 22.588 –1.685 800 36.697 262.589 240.501 17.671 108.841 10.060 –0.657 882.38 36.985 266.200 242.734 20.706 pressure = 1 bar 900 37.045 266.932 243.201 21.358 0.000 0.000 0.000 1000 37.377 270.852 245.773 25.079 0.000 0.000 0.000 1100 37.704 274.430 248.218 28.833 0.000 0.000 0.000 1200 38.030 277.725 250.541 32.620 0.000 0.000 0.000 1300 38.353 280.781 252.751 36.439 0.000 0.000 0.000 1400 38.669 283.635 254.856 40.290 0.000 0.000 0.000 1500 38.976 286.314 256.865 44.173 0.000 0.000 0.000

75. OCTASULFUR S8 (g) 298.15 156.500 432.536 432.536 0.000 101.277 48.810 –8.551 300 156.768 433.505 432.539 0.290 101.231 48.484 –8.442 400 167.125 480.190 438.834 16.542 80.642 32.003 –4.179 500 173.181 518.176 451.022 33.577 66.185 21.409 –2.237 600 177.936 550.180 464.951 51.137 55.101 13.549 –1.180 700 182.441 577.948 479.152 69.157 46.349 7.343 –0.548 800 186.764 602.596 493.071 87.620 39.177 2.263 –0.148 900 190.595 624.821 506.495 106.494 –392.062 6.554 –0.380 1000 193.618 645.067 519.355 125.712 –387.728 50.614 –2.644 1100 195.684 663.625 531.639 145.185 –383.272 94.233 –4.475 1200 196.825 680.707 543.359 164.817 –378.786 137.444 –5.983 1300 197.195 696.480 554.539 184.524 –374.356 180.283 –7.244 1400 196.988 711.089 565.206 204.237 –370.048 222.785 –8.312 1500 196.396 724.662 575.389 223.909 –365.905 264.984 –9.227

76. SULFUR DIOXIDE SO2 (g) 298.15 39.842 248.219 248.219 0.000 –296.810 –300.090 52.574 300 39.909 248.466 248.220 0.074 –296.833 –300.110 52.253 400 43.427 260.435 249.828 4.243 –300.240 –300.935 39.298

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

500 46.490 270.465 252.978 8.744 –302.735 –300.831 31.427 600 48.938 279.167 256.634 13.520 –304.699 –300.258 26.139 700 50.829 286.859 260.413 18.513 –306.308 –299.386 22.340 800 52.282 293.746 264.157 23.671 –307.691 –298.302 19.477 900 53.407 299.971 267.796 28.958 –362.075 –295.987 17.178 1000 54.290 305.646 271.301 34.345 –362.012 –288.647 15.077 1100 54.993 310.855 274.664 39.810 –361.934 –281.314 13.358 1200 55.564 315.665 277.882 45.339 –361.849 –273.989 11.926 1300 56.033 320.131 280.963 50.920 –361.763 –266.671 10.715 1400 56.426 324.299 283.911 56.543 –361.680 –259.359 9.677 1500 56.759 328.203 286.735 62.203 –361.605 –252.053 8.777

77. SILICON Si (cr) 298.15 19.789 18.810 18.810 0.000 0.000 0.000 0.000 300 19.855 18.933 18.810 0.037 0.000 0.000 0.000 400 22.301 25.023 19.624 2.160 0.000 0.000 0.000 500 23.610 30.152 21.231 4.461 0.000 0.000 0.000 600 24.472 34.537 23.092 6.867 0.000 0.000 0.000 700 25.124 38.361 25.006 9.348 0.000 0.000 0.000 800 25.662 41.752 26.891 11.888 0.000 0.000 0.000 900 26.135 44.802 28.715 14.478 0.000 0.000 0.000 1000 26.568 47.578 30.464 17.114 0.000 0.000 0.000 1100 26.974 50.130 32.138 19.791 0.000 0.000 0.000 1200 27.362 52.493 33.737 22.508 0.000 0.000 0.000 1300 27.737 54.698 35.265 25.263 0.000 0.000 0.000 1400 28.103 56.767 36.728 28.055 0.000 0.000 0.000 1500 28.462 58.719 38.130 30.883 0.000 0.000 0.000

78. SILICON Si (g) 298.15 22.251 167.980 167.980 0.000 450.000 405.525 –71.045 300 22.234 168.117 167.980 0.041 450.004 405.249 –70.559 400 21.613 174.416 168.843 2.229 450.070 390.312 –50.969 500 21.316 179.204 170.456 4.374 449.913 375.388 –39.216 600 21.153 183.074 172.246 6.497 449.630 360.508 –31.385 700 21.057 186.327 174.032 8.607 449.259 345.682 –25.795 800 21.000 189.135 175.748 10.709 448.821 330.915 –21.606 900 20.971 191.606 177.375 12.808 448.329 316.205 –18.352 1000 20.968 193.815 178.911 14.904 447.791 301.553 –15.751 1100 20.989 195.815 180.358 17.002 447.211 286.957 –13.626 1200 21.033 197.643 181.723 19.103 446.595 272.416 –11.858 1300 21.099 199.329 183.014 21.209 445.946 257.927 –10.364 1400 21.183 200.895 184.236 23.323 445.268 243.489 –9.085 1500 21.282 202.360 185.396 25.446 444.563 229.101 –7.978

79. SILICON DIOXIDE SiO2 (cr) 298.15 44.602 41.460 41.460 0.000 –910.700 –856.288 150.016 300 44.712 41.736 41.461 0.083 –910.708 –855.951 149.032 400 53.477 55.744 43.311 4.973 –910.912 –837.651 109.385 500 60.533 68.505 47.094 10.705 –910.540 –819.369 85.598 600 64.452 79.919 51.633 16.971 –909.841 –801.197 69.749 700 68.234 90.114 56.414 23.590 –908.958 –783.157 58.439 800 76.224 99.674 61.226 30.758 –907.668 –765.265 49.966 848 82.967 104.298 63.533 34.569 –906.310 –756.747 46.613

PHASE TRANSITION: ∆trs H = 0.411 kJ/mol, ∆trs S = 0.484 J/K.mol, crII-crII′ 848 67.446 104.782 63.532 34.980 –906.310 –756.747 46.613 900 67.953 108.811 66.033 38.500 –905.922 –747.587 43.388 1000 68.941 116.021 70.676 45.345 –905.176 –730.034 38.133 1100 69.940 122.639 75.104 52.289 –904.420 –712.557 33.836 1200 70.947 128.768 79.323 59.333 –901.382 –695.148 30.259

T/K C°p S° –(G°–H° (Tr))/T H°–H° (Tr) ∆fH° ∆fG° Log Kf

1200 71.199 130.651 79.323 61.594 –901.382 –695.148 30.259 1300 71.743 136.372 83.494 68.742 –900.574 –677.994 27.242 1400 72.249 141.707 87.463 75.941 –899.782 –660.903 24.658 1500 72.739 146.709 91.248 83.191 –899.004 –643.867 22.421

80. SILICON TETRACHLORIDE SiCl4 (g) 298.15 90.404 331.446 331.446 0.000 –662.200 –622.390 109.039 300 90.562 332.006 331.448 0.167 –662.195 –622.143 108.323 400 96.893 359.019 335.088 9.572 –661.853 –608.841 79.505 500 100.449 381.058 342.147 19.456 –661.413 –595.637 62.225 600 102.587 399.576 350.216 29.616 –660.924 –582.527 50.713 700 103.954 415.500 358.432 39.948 –660.417 –569.501 42.496 800 104.875 429.445 366.455 50.392 –659.912 –556.548 36.338 900 105.523 441.837 374.155 60.914 –659.422 –543.657 31.553 1000 105.995 452.981 381.490 71.491 –658.954 –530.819 27.727 1100 106.349 463.101 388.456 82.109 –658.515 –518.027 24.599 1200 106.620 472.366 395.068 92.758 –658.107 –505.274 21.994 1300 106.834 480.909 401.347 103.431 –657.735 –492.553 19.791 1400 107.003 488.833 407.316 114.123 –657.400 –479.860 17.904 1500 107.141 496.220 413.000 124.830 –657.104 –467.189 16.269