The Selective Catalytic Alkylarens Oxidations To Hydro Peroxides With Dioxygen, Catalyzed With Nickel Complexes: The Formation Of Supramolecular Nanostructures On The Basis Of Catalytic Active Heteroligand Nickel Complexes

L. I. MATIENKO, L. A. MOSOLOVA, V. I. BINYUKOV, E. M. MIL, and G. E. ZAIKOV

1.1 Introduction ...................................................................................... 2 1.2 Materials and Methods ..................................................................... 8 1.3 Results and Discussion .................................................................... 9 1.3.1 Role of H-Bonding in Stabilization of Catalytic

Complexes, Nix(acac)Y(aco)Z(L 2)n(H2O)m (“A”) .............................. 9

1.4 Conclusion ..................................................................................... 19 Keywords ................................................................................................ 20 References ............................................................................................... 20

1.1 INTRODUCTION

Technical and technological development demands the creation of new materials, which are stronger, more reliable and more durable, that is, materials with new properties. Up-to-date projects in creation of new materials go along the way of nanotechnology.