ABSTRACT

I. INTRODUCTION Polyacetylene, a one-dimensional, conjugated polymer represented as (CH),, exhibits electrical conduction upon chemical doping with an electron acceptor or donor [1,2]. The chemical doping transforms the polyacetylene from insulator or semiconductor to conductor. Ordinary polyacetylene film is composed of fibrils that are bundles of polyene chains. Because the fibrils are randomly oriented, the inherent electrical conductivity of the polyacetylene chain is depressed owing to fibril contact resistance. This makes it difficult for polyacetylene to become a complete one-dimensional conductor at the macroscopic level. Today, the primary concern is how to align the fibrils of polyacetylene film in order to achieve higher electrical conductivity.