ABSTRACT

Three methods of immobilization of Pd(O) catalysts were tested for the TsujiTrost type reaction of C-C and C-N bond formation by allylic substitution of cinnamyl carbonates by active methylene compounds (ethyl acetoacetate and dimethyl malonate) and morpholine respectively. A comparison is made in terms of activity, selectivity and capacity of the catalytic systems to be recycled (stability, Pd leaching).