ABSTRACT

In this chapter, we will move from atoms and molecules to the

world of solids. Here, we are less concerned with large scale

extended solids, where “large scale” here refers to solids with all

dimensions larger than about 100 nm, where size-effects do not

play a significant role. Instead, we will concern ourselves with

“low dimensional” nanostructures, whereby at least one dimen-

sion of the solid is less than about 100 nm in length. In such

low dimensional systems and nanostructures, the physical prop-

erties differ dramatically from those of their corresponding bulk

materials because quantum effects become significant. As seen in

Chapter 3, confinement of quantummechanical wave functions in

regions of nanoscale dimensions induces a discretisation of energy

levels, and in this chapter we will introduce the effects of low

dimensionality on the electron density of states and related elec-

tronic properties.