ABSTRACT

A carbon nanotube can be viewed as a graphene sheet rolled up

into a seamless cylinder. This implies, conversely, that longitudinal

cutting (i.e., unzipping) of nanotubes leads to a set of one-atom-thick

graphene sheets having very narrowwidths and straight edges. Such

a thin strip of carbon sheet, termed a graphene nanoribbon, was

theoretically predicted to conduct electrons well,a being transparent

and mechanically strong. Hence, it has been touted as a promising

material for use in electronic devices such as field-effect transistors,

which form the basis of solar cells, displays, and microchips in

computers. To understand and fully make use of its interesting

properties, methods for large-scale production are indispensible.

Until recently, however, graphene nanoribbons have proved harder

to produce than nanotubes; early techniques based on lithographic

patterning [398-402], sonochemical methods [403, 404], chemical

vapor deposition (CVD) [405, 406], and nanocutting [407-409]

could not make nanoribbons in large amounts or with controlled

widths.